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ON THE STABILITY OF BINARY COMPLEX OXIDES |
Chen Nianyi;Wen Yuankai Shanghai Institute of Metallurgy; Academia Sinica University of Science and Technology of china |
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Cite this article:
Chen Nianyi;Wen Yuankai Shanghai Institute of Metallurgy; Academia Sinica University of Science and Technology of china. ON THE STABILITY OF BINARY COMPLEX OXIDES. Acta Metall Sin, 1979, 15(1): 85-93.
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Abstract Factors concerning with the stability of binary complex oxides has been stu-died. For complex oxides with ionic bonds,the main factors determining the heatof formation of such oxides appear to be the relevant ionic radius and the va-lency of the component elements. For oxides with partial covalency, however, thescreening parameter proposed in this paper may also be important in addition tothe factors mentioned above.
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Received: 18 January 1979
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[1] Erdos, E., Collect. Czech. Chem. Commun., 27 (1962) , 1428. [2] Schwitzgebel, K. et al., J. Chem. Eng. Data, 16 (1971) , 418. [3] Капустниский:络合物热化学(中译本),科学出版社,北京,1963. [4] Thilo, E. et al., Z. Anorg. Allg. Chem., 303 (1960) , 90. [5] 陈念贻,中国科学,(1974) ,№6,580;(1975) ,№ 4,399. [6] 陈念贻,金属学报,11(1974) ,№ 2,154. [7] 1963. [8] 陈念贻,键参数函数及其应用,科学出版社,北京,1976.W |
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