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Acta Metall Sin  2009, Vol. 45 Issue (6): 673-679    DOI:
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DETERMINATION OF SPACE GROUP OF INCOMMENSURATE MODULATION STRUCTURE PHASES IN Bi HIGH TEMPERATURE SUPERCONDUCTORS
BIAN Weimin1; ZHU Yimei2; ZHOU Lian3
1.Research Institute; Northeastern University; Shenyang 110004
2.Brookhaven National Laboratory; Upton NY 11973; USA
3.Northwest Institute for Nonferrous Metal Research; Xi'an 710016
Cite this article: 

BIAN Weimin ZHU Yimei ZHOU Lian. DETERMINATION OF SPACE GROUP OF INCOMMENSURATE MODULATION STRUCTURE PHASES IN Bi HIGH TEMPERATURE SUPERCONDUCTORS. Acta Metall Sin, 2009, 45(6): 673-679.

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Abstract  

The investigation of microstructures of the Bi--2212 and Bi--2223 phases in Bi high temperature superconductors is very significant for improving technology of production and researching superconducting properties and mechanisms. The determination of space groups for the Bi--2212 and Bi--2223 phases is a key problem, which is very complicated because of their incommensurate modulation structures. The supercell structures of the Bi--2212 and Bi--2223 phases with incommensurate modulation structures were determined by convergent beam electron diffraction (CBED). The point group of the supercell of the Bi--2212 phase with type A modulation structure is 2mm, its space group is I2mm. The point group of the supercell of the Bi--2223 phase with type B modulation structure is mmm, its space group is Ibmm. The effects of the rocking curve for the symmetries of CBED patterns were discussed according to experimental results. The simulation results of CBED patterns for the Bi--2212 phase confirmed the symmetries of CBED patterns to be the symmetries of the supercell with modulation structure, but not to be the symmetries of the subcell structure.

Key words:  Bi high temperature superconductor      convergent beam electron diffraction (CBED)      Bi--2212 phase      Bi--2223 phase      incommensurate modulation structure      space group     
Received:  19 November 2008     
ZTFLH: 

TG111

 
  TG132.26

 
Fund: 

Supported by US Department of Energy, Division of Materials Science, Office of Basic Energy Science (No. DE--AC02--76CH00016)

URL: 

https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2009/V45/I6/673

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