Acta Metall Sin  2007, Vol. 43 Issue (3): 273-280     DOI:

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ELECTROPOLYMERIZATION AND RADIATION CROSSLINKING OF ANTICORROSION POLYANILINE FILMS ON ZINC-ELECTROPLATED STEEL

YIN Renhe; JI Xuebin; WANG Huijuan; ZHANG Lei; SHI Xinhong

Department of Chemistry; College of Science; Shanghai University; Shanghai 200444

YIN Renhe; JI Xuebin; WANG Huijuan; ZHANG Lei; SHI Xinhong. ELECTROPOLYMERIZATION AND RADIATION CROSSLINKING OF ANTICORROSION POLYANILINE FILMS ON ZINC-ELECTROPLATED STEEL. Acta Metall Sin, 2007, 43(3): 273-280 .

Abstract References Related Articles Recommended Metrics Download:  PDF(1134KB)  Export:  BibTeX | EndNote (RIS)       Abstract  Polyaniline films were synthesized on zinc－electroplated steel sheets in sodium salicylate aqueous medium．From the FTIR and XPS values, conclusions can be as follows: (1) Pani layers is doped with some salicylate anions; (2) The doping level is nearly 12~24% for the Pani films.A research is made on the effect of the radialization of electron beam on electropolymerized film of aniline film on zinc-electroplated steel. The obtained results show that the gel content and crosslinking density increase with the dose, get to a maximum at 960kGy, and are independent of dosage quotiety. The corrosion protection capability are improved to a great extent. At the same dose, the corrosion protection capability becomes better with the dosage quotiety becomes lower. Key words:  polyaniline      electropolymerized      radiation crosslinking       Received:  27 June 2006      ZTFLH:  O631   Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors YIN Renhe JI Xuebin WANG Huijuan ZHANG Lei SHI Xinhong URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y2007/V43/I3/273 [1]Zhao Y P,Yin R H,Cao W M,Yuan A B.Acta Metall Sin(Engl Lett),2004;17:849 [2]Zhang D H,Wang Y Y,Qiang J F.New Chem Mater, 2003;31(6):30 (张东华,王杨勇,强军锋．化工新型材料．2003;31(6):30) [3]Zhang H L.Guangxi Chem Ind,1998;27(3):37 (郑海林．广西化工,1998;27(3):37) [4]Nguyen Thile H,Carcia B,Deslouis C,Le X Q.Elec- trochem Acta,2001;46:4259 [5]Ha H F,Wu J L.Radialization Chemistry of Macromolecule-Principle and Application.Beijing: ??Peking University Press,2002:75 (哈鸿飞,吴季兰．高分子辐射化学——原理与应用．北京:北京大学出版社,2002:75) [6]Zhang Z C,Ge X W,Zhang M W.Radialization Chem- istry of Macromolecule.Hefei:University of Science and Technology of China Press,2002:106 (张志成,葛学武,张曼维．高分子辐射化学．合肥:中国科学技术大学出版社,2000:106) [7]Jing X L,Zhao W B,Zheng M S.Petrochem Technol Appl, 2001;19:225 (井新利,赵卫兵,郑茂盛．石化技术与应用,2001;19:225) [8]Sun J P,Li B M,Wu H C.Fine Chem,2002;19:578 (孙建平,李宝铭,吴洪才．精细化工,2002;19:578) [9]Zhang B Y,Gao Z,Su X M.Petrochem Technol Appl, 2005;23:11 (张柏宇,高治,苏小明．石化技术与应用．2005;23:11) [10]Camalet J L,Lacroix J C,Nguyen T D,Aeiyach S,Pham M C,Petitjean J,Lacaze P C.J Electroanal Chem,2000; 485(1):13 [11]Liu C M,Qiu J J,Tian D T.J Microwaves,2002;18:83 (刘承美,邱进俊,田大听．微波学报,2002;18:83) [12]Yuan A B,Xu N X.Battery,2002;32:323 (袁安保,徐乃欣．电池,2002;32:323)w [1] SANG Xiaoguang, ZENG Fanwu, LIU Xiaoxia. ELECTROCHEMICAL PREPARATION OF PANI/CeO2 COMPOSITE WITH SPECIAL MORPHOLOGY[J]. 金属学报, 2012, 48(4): 508-512. [2] ZHANG Xia WANG Jing CHEN Li. STRUCTURE AND PERFORMANCE OF Fe2O3-PANI COMPOSITE NANOPARTICLES SYNTHESIZED BY ELECTROSTATIC SELF-ASSEMBLY[J]. 金属学报, 2009, 45(9): 1135-1140. [3] . Electromaganic Wave Absorbing Property of Polyaniline / Polystylene Blends[J]. 金属学报, 2007, 43(4): 409-412 . [4] . STUDY ON THE FORMATION OF POLYANILINE COATINGS AND ITS CORROSION BEHAVIOR FROM SILANE SOLUTIONS[J]. 金属学报, 2007, 43(4): 404-408 . No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed