CHEMICAL VAPOUR GROWTH OF CARBON WHISKERS ON CARBON FIBRE
SUN Shoujin;WEI Yongliang;LIU Min;LI Minjun Institute of Metal Research Academia Sinica; Shenyang research associate;Institute of Metal Research;Academia Sinica;Shenyang 110015
Cite this article:
SUN Shoujin;WEI Yongliang;LIU Min;LI Minjun Institute of Metal Research Academia Sinica; Shenyang research associate;Institute of Metal Research;Academia Sinica;Shenyang 110015. CHEMICAL VAPOUR GROWTH OF CARBON WHISKERS ON CARBON FIBRE. Acta Metall Sin, 1993, 29(4): 62-67.
Abstract The secondary reinforcement, carbon whiskers, may grow on the surface ofparent reinforcement, carbon fibres, by chemical vapour growth from acetylene using Fe saltsolution as catalyzer. The optimal growing temperature is about 1000℃, and while the con-centration of catalytic solution is appropriate, the carbon whiskers may deposite uniformlyand link each other on the parent carbon fibre surface. If the temperature or concentration istoo high, the coarse cluster of carbon may deposite on the fibre surface. The mechanism ofcarbon whisker growth is believed that the carbon atoms in vapour phase dissolve first in theFe salt drops over fibres, then the solid carbon grains precipitate on the film surface.
1 Ko F K. Am Ceram Soc Bull, 1989: 68: 401 2 Bahl O P, Mathur R B. Polym Eng Sci, 1984; 24: 455 3 Fitzer E, Geigl K-H, Huttner W, Weiss R. Carbon, 1980; 18: 389 4 张志谦,张德庆、魏月贞、宇航材料工艺,1991;(2) :41 5 Jones C, Sammann E. Proceedings of the American Society for Composites. 14th Technical Conference. Lancaster, USA: Technomic, 1989: 387 6 Tibbetts G G. In: Figueiredo J L, Bernardo C A, Baker R T K, Huttinger K J eds., Carbon Fibers Filaments and Composites. Dordrecht: Kluwer Academic, 1989: 147>
WANG Yuqing;ZHENG Jiuhong;WANG Zuoming(Institute of Metal Research; Chinese Academy of Sciences;Shenyang);ZHOU Benlian(Institute of Metal Research;Chinese Academy of Sciences;Shenyang;International Centre for Meterials Physics;Chinese Academy of Sciences;Shenyang);ZHOU Longjiang;ZHANG Fengqiu(Institute of Corrosion and Protection of Metals;Chinese Academy of Sciences;Shenyang)(Manuscript received 16 August; 1993;in revised form 27 September;1993). SiC COATED CARBON FIBRES BY SOLUTION COATING AND THEIR APPLLICATION TO PREPARING CF/Al COMPOSITES[J]. 金属学报, 1994, 30(16): 194-198.