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Acta Metall Sin  1993, Vol. 29 Issue (2): 49-53    DOI:
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REACTION BETWEEN Ca_2SiO_4 AND NaFeO_2 AND OPTIMIZATION OF COMPOSITION OF SINTER IN ALUMINA PRODUCTION
ZHAN Qianbao;LI Ming;ZHOU Jicheng;CHEN Nianyi;QI Likuan;CHEN Jiantang Shanghai Institute of Metallurgy; Academia Sinica; Research Institute of Shandong Aluminium Factory
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ZHAN Qianbao;LI Ming;ZHOU Jicheng;CHEN Nianyi;QI Likuan;CHEN Jiantang Shanghai Institute of Metallurgy; Academia Sinica; Research Institute of Shandong Aluminium Factory. REACTION BETWEEN Ca_2SiO_4 AND NaFeO_2 AND OPTIMIZATION OF COMPOSITION OF SINTER IN ALUMINA PRODUCTION. Acta Metall Sin, 1993, 29(2): 49-53.

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Abstract  The reaction product of Ca_2SiO_4-NaFeO_2 system has been investigated byX-ray diffraction and IR spectroscopy. The product contains CaFe_2O_4 and Na_4Ca_8(SiO_4)_5.Thermodynamical estimation also confirms that Ca_2SiO_4+NaFeO_2 is not the stable pair ofthe reciprocal salt pairs of Ca, NaSiO_4, FeO_2 system. In the reactions betweenNa_4Ca_8(SiO_4)_5 and sodium aluminate solution there forms Ca_3[Al(OH)_6]_2 (or its solid solu-tion) which will decrease the recovery of alumina. Based on the abovementioned facts, themathematical model for the optimization of the composition of sinters in alumina productionhas been explained.
Key words:  Ca_2SiO_4      NaFeO_2      chemical reaction     
Received:  18 February 1993     
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1 Chen Nianyi, Zhang Weiming, Cheng Zhaonian. In: Danzer K ed., Wissensche-ftliche Seitrage der Friedrich-Schiller Universitate, Jeaa: Friedrich-Schiller Universitate Jena, 1989: 59
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