Acta Metall Sin  1991, Vol. 27 Issue (4): 84-87    DOI:

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MECHANISM OF EXTRACTION AND STRIPPING OF Fe(Ⅲ) WITH PRIMARY AMINE N1923 AS EXTRACTANT AND n-OCTANE AS DILUENT

LIU Huizhou;YU Shuqiu;CHEN Jiayong Institute of Chemical Metallurgy; Academia Sinica; Beijing

LIU Huizhou;YU Shuqiu;CHEN Jiayong Institute of Chemical Metallurgy; Academia Sinica; Beijing. MECHANISM OF EXTRACTION AND STRIPPING OF Fe(Ⅲ) WITH PRIMARY AMINE N1923 AS EXTRACTANT AND n-OCTANE AS DILUENT. Acta Metall Sin, 1991, 27(4): 84-87.

Abstract References Related Articles Recommended Metrics Download:  PDF(394KB)  Export:  BibTeX | EndNote (RIS)       Abstract  Mechanism of extraction of Fe(Ⅲ) from sulphate solution by primaryamine N1923 and stripping of Fe loaded organic phase with dilute H_2SO_4 was inves-tigated. The organic phase was characterized by FT-IR and photon correlation spec-troseopy. The composition of extracted species as well as the content of H_2O inorganic phase were determined. The dependency of both the rate of extraction andstripping on the formation of reverse micelle in primary amine (N1923) system hasbeen confirmed. It is shown that the extraction of Fe(Ⅲ) by primary amine sulpha-te may be related to the adduct formation or cation exchange reaction under differ-ent concentrations of H_2SO_4 in aqueous solution. Key words:  Fe(III)      primary amine (N1923)      extraction      stripping      Received:  18 April 1991      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1991/V27/I4/84 1 Seeley F G, McDowell W J. J Inorg Nucl Chem, 1981; 43: 375 2 Alguacil F J, Amer S. Hydrometallurgy, 1986: 15: 337 3 孟锡泉.中国科学院化工冶金研究所博士学位论文.1988 4 Meng Xiquan, Yu Shuqiu, Chen Jiayong, Proc 2nd Int Conf on Separations Science and Technology, Vol. Ⅱ Hamilton, Ontario, Canada, 1989: 594 5 Zulauf M, Eicke H F. J Phys Chem, 1979; 83: 48 [1] Yun XUE,Xue YANG,Yongde YAN,Milin ZHANG,Debin JI,Enyu LI,Wei HAN. ELECTROLYSIS EXTRACTION OF NEODYMIUM FROM LiCl-KCl-AlCl3-Nd2O3 MELTS WITHTHE ASSISTANCE OF AlCl3[J]. 金属学报, 2016, 52(7): 883-889. [2] YANG Chuanfang; CHEN Jiayong(Institute of Chemical Metallurgy; Chinese Academy of Sciences; Beijing). PREPARATION OF HIGH QUALITY ULTRAFINE ZrO_2 POWDER WITH REVERSED MICELLAR SOLUTION FROM SOLVENT EXTRACTION[J]. 金属学报, 1994, 30(24): 527-531. [3] LIU Difei Department of Chemical Engineering; Tsinghua University; BeijingYU Jingfen;professor;Department of Chemical Engieering.Tsinghua University;Beijing 100084. EXTRACTION KINETICS AND INTERFACIAL CHEMISTRY FOR SYNERGISTIC EXTRACTION SYSTEMD_2EHPA-MPA-Fe~(3+)[J]. 金属学报, 1993, 29(5): 56-62. [4] HUANG Kelong;SHU Wanyin;DING Dunhuang;LIU Guogen;DONG Ping Central South University of Technology; Changsha. COMPLEX FORMED IN EXTRACTION OF DIVALENT Mn BY ALKYLPHOSPHONIC ACID MONOESTER[J]. 金属学报, 1991, 27(4): 88-92. [5] LIN Daozhi;SUN Wanming Changchun Institute of Applied Chemistry; Academia Sinica. EXTRACTION OF Tb AND Tm BY EXTRACTANT P_(229)[J]. 金属学报, 1991, 27(2): 89-93. [6] HAN Shumin;MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica. SYNERGISTIC AND ANTAGONISTIC EFFECTS OF Zn(Ⅱ) EXTRACTION WITHHEH/EHP AND PRIMARY AMINE N_(1923)[J]. 金属学报, 1991, 27(2): 83-88. [7] YU Jingfen;JI Chen;PAN Xiaomei;XIONG Yigang Tsinghua University; Beijing. EXTRACTION KINETICS, MICELLIZATION AND INTERFACIAL CHARACTERISTICS OF A NEW MIXED EXTRACTANT SYSTEM[J]. 金属学报, 1990, 26(6): 84-89. [8] LIU Jincai;LU Jiufang Department of Chemical Engineering; Tsinghua University; Beijing Department of Chemical Engineering; Tsinghua University;Beijing 100084. KINETICS OF COPPER EXTRACTION BY N530-HEPTANE[J]. 金属学报, 1990, 26(4): 93-97. [9] JIANG Tao;SU Yuanfu East China University of Chemical Technology; Shanghai. EXTRACTION OF Zn AND Cd FROM CHLORIDE SOLUTIONS BY TRI-n-BUTYL PHOSPHATE[J]. 金属学报, 1990, 26(4): 87-92. [10] WU Zhichun;YU Shuqiu;CHEN Jiayong (Chen Chia-yung) Institute of Chemical Metallurgy; Academia Sinica; Beijing. SOLVENT EXTRACTION OF Fe (Ⅲ) FROM SULFATE SOLUTIONS WITH TERTIARY AMINES[J]. 金属学报, 1990, 26(3): 106-112. [11] MA Genxiang;LI Deqian Changchun Institute of Applied Chemistry; Academia Sinica. SYNERGISTIC EXTRACTION OF Cd(II) WITH PRIMARY AMINE N-1923 AND NEUTRAL ORGANOPHOSPHORUS REAGENTS[J]. 金属学报, 1989, 25(1): 104-110. [12] HUANG Qianyao;SHI Yanyu Central Iron and Steel Research Institute; Ministry of Metallurgical Industry; Beijing. DYNAMICS OF PRECIPITATION AND TRANSFORMATION OF CARBIDES IN A Ni-BASE SUPERALLOY[J]. 金属学报, 1988, 24(6): 399-403. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed