Acta Metall Sin  1988, Vol. 24 Issue (1): 119-122    DOI:

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KINETICS OF INTERACTION OF PbO, xPbO·SiO_2 WITH PbS AND ACTIVITY OF PbO

LIU Chunpeng Kunming College of Engineering LU Yuehua Post Graduate Student for Ph.D.;Department of Metallurgicel;Kunming Institute of Technology

LIU Chunpeng Kunming College of Engineering LU Yuehua Post Graduate Student for Ph.D.;Department of Metallurgicel;Kunming Institute of Technology. KINETICS OF INTERACTION OF PbO, xPbO·SiO_2 WITH PbS AND ACTIVITY OF PbO. Acta Metall Sin, 1988, 24(1): 119-122.

Abstract References Related Articles Recommended Metrics Download:  PDF(330KB)  Export:  BibTeX | EndNote (RIS)       Abstract  The rate equation for the reaction of PbO with PbS in liquidstate at 850--1000℃ has been determined as dα/dt=4.73×10~6 exp (-190/RT)in which the activation en ergy E=190kJ/mol. In the solid-liquid reaction system of xPbO. SiO_2-PbS, the rate equation maybe formulated as following: dF(α)/dt=k′(t<20min)+k"(t>20min) (1000℃)where F(α)=α-(N°_(SiO_2/N°_(PbO))ln(1-α) The activities of PbO and SiO_2 in the silicate calculated from the rate dataare in good agreement with those measured thermodynamically. Key words:  solid-liquid interfacial reaction      chemical control      diffusion control      activity of PbO      Received:  18 January 1988      Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors URL:  https://www.ams.org.cn/EN/     OR     https://www.ams.org.cn/EN/Y1988/V24/I1/119 1 #12 2 Shohu H Y,Wodsworth M E.郑蒂基译. 提取冶金速过程,北京:冶金工业出版社,1984:153 3 李振家,芦爱春,孙萼庭.全国第一届冶金过程物理化学学术论文集,上海科学技术出版社,1962:380 4 Liou Chunpen, Feng Ganming, Yan Chuanyi, Ho Aiping, First China-USA Bilateral Mctallurgical Conference, Beijing, 1981: 137 5 Richardson F D. WebbL E. Bull Inst Met. 1955; 64: 529 6 Kozuka Z, Samis C S. Met Trans, 1970; 1: 8717 [1] Lei WANG,Di TANG,Yong SONG. AUSTENITE TRANSFORMING IN CONTINUOUS COOLING PROCESS UNDER DIFFUSION CONTROL MODEL[J]. 金属学报, 2015, 51(11): 1341-1348. [2] Wang Kuangfei. Numerical simulaton of cellular/dendritic transition and its growth during unidirectional solidificationin of Ti–Al alloy[J]. 金属学报, 2007, 43(2): 211-216 . [3] LI Cheng Beijing Central Engineering and Reseorch Institute for Non-Ferrous Metallurgical Industry; LIU Chunpeng Kunming Institute of Technology. KINETICS OF INTERACTION BETWEEN PbS AND PbO·SiO_2[J]. 金属学报, 1991, 27(1): 145-147. No Suggested Reading articles found! Viewed Full text Abstract Cited   Shared      Discussed