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Acta Metall Sin  1987, Vol. 23 Issue (1): 33-41    DOI:
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THERMODYNAMICS OF BAINITIC TRANSFORMATION IN Fe-C ALLOYS(LFG MODEL)
XU Zuyao (T.Y.Hsu)MOU Yiwen (Shanghai Jiaotong University)
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XU Zuyao (T.Y.Hsu)MOU Yiwen (Shanghai Jiaotong University). THERMODYNAMICS OF BAINITIC TRANSFORMATION IN Fe-C ALLOYS(LFG MODEL). Acta Metall Sin, 1987, 23(1): 33-41.

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Abstract  The calculated results obtained from the refined LFG model is similar to that from KRC,but there exists divergency between them in alloys with higher C contents.It seems that for treating interstitial solid solution,LFG model is more suitable over the KRC.Both the results from the two models show that △G~(γ→α+Fe_3c) is the largest,followed by △G~(γ→α+γ_1) and △G~(α-γ′) is the smallest and △G_N~(γ→α′)is far less than △G_N~(γ→α+γ_1′).At B_s,from LFG,for x_γ=0.001-0.002,△G_N~(γ→α+γ_1)△G_N~(γ→α+γ_1)- -196--237 J.mol~(-1);for x_γ=0.035,the sum of △G~(γ→α′) and △G~(α′→α″+Fe_3)is only—181 J.mol~(-1).The present work verifies again that at least at upper tem- perature range,the formation of bainite with shear mechanism is thermodynam- ically impossible.Calculation of the driving force for nucleaction(growth)gives an evidencs that the leading phase of the eutectoid reaction in hypoeutectoid steels is ferrite while that in hypereutectoid steels is cementite.
Received:  18 January 1987     
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