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ACTIVITY OF Ce_2O_3 IN LIQUID SLAGS OF Ce_2O_3-CaO-CaF_2 SYSTEM |
by WANG Changzhen; YE Shuqing (Northeast Institute of Technology; Shenyang); HU Yingnian; DU Qisheng (Nei Monggol Institute of Metallic Materials) |
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Cite this article:
by WANG Changzhen; YE Shuqing (Northeast Institute of Technology; Shenyang); HU Yingnian; DU Qisheng (Nei Monggol Institute of Metallic Materials). ACTIVITY OF Ce_2O_3 IN LIQUID SLAGS OF Ce_2O_3-CaO-CaF_2 SYSTEM. Acta Metall Sin, 1986, 22(4): 77-79.
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Abstract The liquid boundary of the slags of Ce_2O_3-CaO-CaF_2 system and the iso-activity lines for Ce_2O_3 and CeO_2 are given from experimental determination of the activity of Ce_2O_3 by equilibrating the slag with Sn in a graphite crucible under an atmosphere of CO at 1600℃. The activity of Ce_2O_3 in the slags containing certain CeO_2 or CaO, increases with the increase of concentration of CaO or CeO_2 respectively. The transition of CeO_2 to Ce_2O_3 under the condition of high temperature and low oxygen partial pressure was also discussed by thermodynamical analysis.
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Received: 18 April 1986
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1 邹元燨;赵彭年;曹兆民,金属学报,6(1963) ,121. 2 Chou Yuan-hsi(邹元燨),Chow Ji-cheng(周继程);Chao Peng-nian(赵彭年),Sci.Sinica,12 (1963) .1249. 3 王常珍,邹元燨,金属学报,16(1980) ,190. 4 王常珍,杨代银,金属学报,15(1979) .433. 5 Iwasaki, B.; Katsura, T., Bull. Chem. Soc. Jpn., 44 (1971) , 1297. 6 Bevan, D.J.; Kordis, J., J.Inorg. Nucl. Chem., 26 (1964) , 1509. 7 Fruehan, R.J., Metall, Trans., 10B (1979) , 143. 8 #1 |
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