|
|
|
| CALCULATION OF THERMODYNAMIC PROPERTIES AND PHASE DIAGRAM OF TERNARY MOLTEN SALT SYSTEM NaCl-CaCl_2-SrCl_2 BY USE OF COMPUTOR |
| Qiao Zhiyu;Mats Hillert Beijing University of Iron and Steel Technology Honourary Professor of Beijing University of Iron and Steel Technology; Royal Institute of Technology; Stockholm; Sweden |
|
Cite this article:
Qiao Zhiyu;Mats Hillert Beijing University of Iron and Steel Technology Honourary Professor of Beijing University of Iron and Steel Technology; Royal Institute of Technology; Stockholm; Sweden. CALCULATION OF THERMODYNAMIC PROPERTIES AND PHASE DIAGRAM OF TERNARY MOLTEN SALT SYSTEM NaCl-CaCl_2-SrCl_2 BY USE OF COMPUTOR. Acta Metall Sin, 1982, 18(2): 245-254.
|
|
|
Abstract The Gibbs energies of the liquid and solid phases in the CaCl_2-SrCl_2 system have been calculated using the information available on the phase diagram.The Gibbs energy of the liquid phase in the ternary system NaCl-CaCl_2-SrCl_2 has been predicted from the binary properties by applying a modified version of Toop's method.The partial Gibbs energies and the activity coefficients were then calcula- ted by using computer.On the basis of above calculated results and the principle of phase equilibrium the NaCl-CaCl_2-SrCl_2 phase diagram have also been compu- ted using a program.All these calculations are important for the practice of sodium electrolysis and utilization of salt lake resources.The subregular solution model and the modified version of Toop's method are expected to be suitable for calculating a series of assymetric ternary molten salt systems of potential interests, such as NaCl-CaCl_2-BaCl_2,NaCl-SrCl_2-BaCl_2,NaCl-CaCl_2-MgCl_2,KCl-CaCl_2- MgCl_2,KCl-NaCl-CeCl_3 and so on.
|
|
Received: 18 February 1982
|
1 Levin,E.M.,Phase Diagrams for Ceramists,Second Edition(1969) ,Supplement(1973) ,(1975) ,Am.Ceram.Soc.,Columbus,Ohio,Fig.1428,3304,3316．
2 Lin,P.L.;Pelton,A.D.;Bale,C.W.,J.Am.Ceram.Soc.,62(1980) ,416．
3 Hillert,M.,CALPHAD(Calculation of Phase Diagram),4(1980) ,1．
4 Mo,W.G.;Wu,S.M,;Qiao,Z.;Zhu,Y.K.,Unpublished Work.
5 Lumsden,J.,Thermodynamics of Molten Salt Mixtures,Academic Press,London,1966,p.212,215．
6 Levin,E.M.,Phase Diagrams for Ceramists,Second Edition(1969) ,Am.Ceram.Soc.,Columbus,Ohio,Fig.1364．
7 Toop,G.W.,Trans.Metall.Soc.AIME,233(1965) ,850．
8 Pelton,A.D.;Thompson,W.T.,Progr.Solid State Chem.,10(1975) ,119．
9 Sadoway,D.R.;Flengas,S.N.,J.Electrochem.Soc.,122(1975) ,515．
10 Pelton,A.D.;Thompson,W.T.,Can J.Chem.,48(1970) ,1585．
11 Pelton,A.D.,Can.J.Chem.,49(1971) ,3919．
12 Muggianu,Y.-M;Gambino,M.;Bros,J.-P.,J.Chim.Phys.Phys-Chim.Biol.,72(1975) ,83．
13 Hillert,M.,Thermodynamic of Alloys,in Beijing University of Iron and Steel Technology,(1980) .x |
| No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
| |
Shared |
|
|
|
|
| |
Discussed |
|
|
|
|
