高容量镁基储氢合金材料研究与应用进展
收稿日期: 2024-10-12
修回日期: 2024-11-28
网络出版日期: 2025-01-09
基金资助
国家自然科学基金项目(52201266);国家自然科学基金项目(52171186);国家重点研发计划项目(2023YFB3809103);博士后研究人员计划项目(GZC20231546)
Progress in the Research and Application of High-Capacity Mg-Based Hydrogen Storage Alloy Materials
Received date: 2024-10-12
Revised date: 2024-11-28
Online published: 2025-01-09
Supported by
National Natural Science Foundation of China(52201266);National Natural Science Foundation of China(52171186);National Key Research and Development Program of China(2023YFB3809103);Postdoctoral Fellowship Program of CPSF(GZC20231546)
随着近年来氢能产业的迅速发展，镁基固态储氢材料及其储运氢系统得到了全球的广泛关注，出现了许多突破性研究和进展。在新材料体系设计方面，高性能纳米镁基储氢材料和改性镁基铸造合金的研发有效改善了Mg及其氢化物的热力学稳定性和动力学性能，实现了材料在中低温条件下的快速吸脱氢和低成本应用。在系统开发方面，借助先进的模拟方法和设计策略对镁基固态储氢系统的结构与操作参数进行优化，实现了镁基固态储氢系统的有效热管理。在工程应用方面，世界首台吨级镁基固态储运氢车落地，多个镁基固态储运氢示范应用和加氢站也陆续问世。本文从纳米镁基储氢材料、改性镁基储氢合金、镁基储氢系统开发和示范应用4方面讨论了镁基储氢材料的重要研究进展，总结了其在氢能储运领域的相关工程示范及应用，并对未来的研究趋势进行了展望。
邹建新 , 张嘉祺 , 赵颖燕 , 林羲 , 丁文江 . 高容量镁基储氢合金材料研究与应用进展[J]. 金属学报, 2025 , 61(3) : 420 -436 . DOI: 10.11900/0412.1961.2024.00344
With the rapid advancement of the hydrogen energy industry in recent years, Mg-based solid hydrogen storage materials and their associated storage and transportation systems have garnered significant global attention, leading to numerous groundbreaking studies and remarkable progresses. In the field of material design, high-performance nano Mg-based hydrogen storage materials and modified Mg-based hydrogen storage alloys have significantly enhanced the thermodynamic stability and kinetic properties of Mg and its hydrides. These advancements enable rapid hydrogen absorption and desorption at moderate or even room temperatures, paving the way for cost-effective applications. In terms of system development, the structural design and operational parameters of Mg-based solid hydrogen storage systems have been optimized through advanced simulation techniques and innovative design strategies, thus efficient thermal management of the storage system is achieved. In terms of engineering applications, the world's first ton-level Mg-based solid-state hydrogen storage and transportation trailer has been successfully launched. Additionally, multiple demonstration projects, including Mg-based solid-state hydrogen storage systems and hydrogen refueling stations, have been initiated worldwide. This paper reviews the significant research advancements in Mg-based hydrogen storage materials, focusing on four key areas: nanocrystallization, alloying, system development, and demonstration applications. It also summarizes relevant engineering demonstrations and applications in hydrogen energy storage and transportation, providing suggestions for the future research directions and potential applications.
| 1 | Schlapbach L, Züttel A. Hydrogen-storage materials for mobile applications [J]. Nature, 2001, 414: 353 |
| 2 | Guan D Q, Wang B W, Zhang J G, et al. Hydrogen society: From present to future [J]. Energy Environ. Sci., 2023, 16: 4926 |
| 3 | M?ller K T, Jensen T R, Akiba E, et al. Hydrogen—A sustainable energy carrier [J]. Prog. Nat. Sci.: Mater. Int., 2017, 27: 34 |
| 4 | Yue M L, Lambert H, Pahon E, et al. Hydrogen energy systems: A critical review of technologies, applications, trends and challenges [J]. Renew. Sustain. Energy Rev., 2021, 146: 111180 |
| 5 | Hassan I A, Ramadan H S, Saleh M A, et al. Hydrogen storage technologies for stationary and mobile applications: Review, analysis and perspectives [J]. Renew. Sustain. Energy Rev., 2021, 149: 111311 |
| 6 | Han G, Lu Y F, Jia H X, et al. Magnesium-based energy materials: Progress, challenges, and perspectives [J]. J. Magnes. Alloy., 2023, 11: 3896 |
| 7 | Ren L, Li Y H, Zhang N, et al. Nanostructuring of Mg-based hydrogen storage materials: Recent advances for promoting key applications [J]. Nano-Micro Lett., 2023, 15: 93 |
| 8 | Zhao Y Y, Wang B L, Ren L, et al. Nanostructured MXene-based materials for boosting hydrogen sorption properties of Mg/MgH2 [J]. Mater. Rep.: Energy, 2024, 4: 100255 |
| 9 | Yang Y X, Zhang X, Zhang L C, et al. Recent advances in catalyst-modified Mg-based hydrogen storage materials [J]. J. Mater. Sci. Technol., 2023, 163: 182 |
| 10 | Zhang X L, Liu Y F, Zhang X, et al. Empowering hydrogen storage performance of MgH2 by nanoengineering and nanocatalysis [J]. Mater. Today Nano, 2020, 9: 100064 |
| 11 | Zhang J Q, Hou Q H, Guo X T, et al. Achieve high-efficiency hydrogen storage of MgH2 catalyzed by nanosheets CoMoO4 and rGO [J]. J. Alloys Compd., 2022, 911: 165153 |
| 12 | Hou Q H, Zhang J Q, Guo X T, et al. Improved MgH2 kinetics and cyclic stability by fibrous spherical NiMoO4 and rGO [J]. J. Taiwan Inst. Chem. Eng., 2022, 134: 104311 |
| 13 | Zhao Y Y, Zhu Y F, Shi R, et al. Structural inhomogeneity: A potential strategy to improve the hydrogen storage performance of metal hydrides [J]. J. Mater. Chem., 2023, 11A: 13255 |
| 14 | Li Q, Lu Y F, Luo Q, et al. Thermodynamics and kinetics of hydriding and dehydriding reactions in Mg-based hydrogen storage materials [J]. J. Magnes. Alloy., 2021, 9: 1922 |
| 15 | Aguey-Zinsou K F, Ares-Fernández J R. Hydrogen in magnesium: New perspectives toward functional stores [J]. Energy Environ. Sci., 2010, 3: 526 |
| 16 | Wagemans R W P, van Lenthe J H, de Jongh P E, et al. Hydrogen storage in magnesium clusters: Quantum chemical study [J]. J. Am. Chem. Soc., 2005, 127: 16675 |
| 17 | Varin R A, Czujko T, Wronski Z. Particle size, grain size and γ-MgH2 effects on the desorption properties of nanocrystalline commercial magnesium hydride processed by controlled mechanical milling [J]. Nanotechnology, 2006, 17: 3856 |
| 18 | Huang S J, Mose M P. High-energy ball milling-induced crystallographic structure changes of AZ61-Mg alloy for improved hydrogen storage [J]. J. Energy Storage, 2023, 68: 107773 |
| 19 | Lang C G, Ouyang L Z, Yang L L, et al. Enhanced hydrogen storage kinetics in Mg@FLG composite synthesized by plasma assisted milling [J]. Int. J. Hydrogen Energy, 2018, 43: 17346 |
| 20 | Zou R, Zhang W J, Dai M, et al. One-step synthesis of light metal nanoparticle from metastable complex [J]. Small, 2023, 19: 2206518 |
| 21 | Wang Y, Ding Z M, Li X J, et al. Improved hydrogen storage properties of MgH2 by nickel@nitrogen-doped carbon spheres [J]. Dalton Trans., 2020, 49: 3495 |
| 22 | Ren L, Zhu W, Li Y H, et al. Oxygen vacancy-rich 2D TiO2 nanosheets: A bridge toward high stability and rapid hydrogen storage kinetics of nano-confined MgH2 [J]. Nano-Micro Lett., 2022, 14: 144 |
| 23 | Ren L, Li Y H, Li Z, et al. Boosting hydrogen storage performance of MgH2 by oxygen vacancy-rich H-V2O5 nanosheet as an excited H-pump [J]. Nano-Micro Lett., 2024, 16: 160 |
| 24 | Zhao Y Y, Liu Z B, Liu J C, et al. Improvement effect of reversible solid solutions Mg2Ni(Cu)/Mg2Ni(Cu)H4 on hydrogen storage performance of MgH2 [J]. J. Magnes. Alloy., 2024, 12: 197 |
| 25 | Zhu C Y, Hosokai S, Akiyama T. Growth mechanism for the controlled synthesis of MgH2/Mg crystals via a vapor-solid process [J]. Cryst. Growth Des., 2011, 11: 4166 |
| 26 | Zhao Y Y, Zhu Y F, Shi R, et al. Magnesium nickel hydride monocrystalline nanoparticles for reversible hydrogen storage [J]. Mater. Rep.: Energy, 2024, 4: 100246 |
| 27 | Panti? T, Mamula B P, Soder?nik K ?, et al. The influence of defects on hydrogen sorption from Mg-V thin films [J]. Int. J. Hydrogen Energy, 2024, 54: 457 |
| 28 | Li W Y, Li C S, Ma H, et al. Magnesium nanowires: Enhanced kinetics for hydrogen absorption and desorption [J]. J. Am. Chem. Soc., 2007, 129: 6710 |
| 29 | Norberg N S, Arthur T S, Fredrick S J, et al. Size-dependent hydrogen storage properties of Mg nanocrystals prepared from solution [J]. J. Am. Chem. Soc., 2011, 133: 10679 |
| 30 | Liu W, Aguey-Zinsou K F. Hydrogen storage properties of in-situ stabilised magnesium nanoparticles generated by electroless reduction with alkali metals [J]. Int. J. Hydrogen Energy, 2015, 40: 16948 |
| 31 | Lu C, Ma Y L, Li F, et al. Visualization of fast “hydrogen pump” in core-shell nanostructured Mg@Pt through hydrogen-stabilized Mg3Pt [J]. J. Mater. Chem., 2019, 7A: 14629 |
| 32 | Ren L, Zhu W, Zhang Q Y, et al. MgH2 confinement in MOF-derived N-doped porous carbon nanofibers for enhanced hydrogen storage [J]. Chem. Eng. J., 2022, 434: 134701 |
| 33 | Zhang X, Liu Y F, Ren Z H, et al. Realizing 6.7 wt% reversible storage of hydrogen at ambient temperature with non-confined ultrafine magnesium hydrides [J]. Energy Environ. Sci., 2021, 14: 2302 |
| 34 | Liang C X, Wang Z B, Zhang M J, et al. Research progress on magnesium-based solid hydrogen storage nanomaterials [J]. Energy Storage Sci. Technol., 2024, 13: 788 |
| 梁宸曦, 王振斌, 张明锦 等. 镁基固态储氢材料的研究进展 [J]. 储能科学与技术, 2024, 13: 788 | |
| 35 | Reilly J J, Wiswall R H. Reaction of hydrogen with alloys of magnesium and copper [J]. Inorg. Chem., 1967, 6: 2220 |
| 36 | Reilly J J, Wiswall R H. Reaction of hydrogen with alloys of magnesium and nickel and the formation of Mg2NiH4 [J]. Inorg. Chem., 1968, 7: 2254 |
| 37 | Zou J X, Ding W J. Review of research hotspots in magnesium-based hydrogen storage materials in 2023 [J]. Sci. Technol. Rev., 2024, 42(1): 204 |
| 邹建新, 丁文江. 2023年镁基储氢材料研究热点回眸 [J]. 科技导报, 2024, 42(1): 204 | |
| 38 | Zhang B W, Zeng Z Q, Li J C, et al. Microstructure and hydrogen storage properties of magnesium-gallium binary alloys [J]. J. Phys. Chem. Solids, 2024, 190: 112028 |
| 39 | Zhang J X, Ding X, Chen R R, et al. Effective attempt towards enhancing hydrogen storage performance of LPSO phase contained high-capacity Mg-based alloy by Indium [J]. Int. J. Hydrogen Energy, 2024, 50: 431 |
| 40 | Lu Y S, Wang H, Liu J W, et al. Reversible de/hydriding reactions between two new Mg-In-Ni compounds with improved thermodynamics and kinetics [J]. J. Phys. Chem., 2015, 119C: 26858 |
| 41 | Zhang J X, Ding X, Chen R R, et al. Precursor H-induced pyrolysis towards hydrogen storage properties enhancement of Mg-Y-Zn alloys with diverse Y level [J]. J. Power Sources, 2023, 560: 232695 |
| 42 | Tan X F, Kim M, Gu Q F, et al. Na-modified cast hypo-eutectic Mg-Mg2Si alloys for solid-state hydrogen storage [J]. J. Power Sources, 2022, 538: 231538 |
| 43 | Yao H, Zeng G, Tan X F, et al. Hydrogen storage performance and phase transformations in as-cast and extruded Mg-Ni-Gd-Y-Zn-Cu alloys [J]. J. Mater. Sci. Technol., 2023, 151: 162 |
| 44 | Zhang J X, Ding X, Chen R R, et al. Diversification of interfaces triggered hydrogen storage properties enhancement [J]. Rare Met., 2024, 43: 2324 |
| 45 | Ma Z W, Huang Z Y, Li Z, et al. Insights into thermodynamic destabilization in Mg-In-D hydrogen storage system: A combined synchrotron X-ray and neutron diffraction study [J]. Energy Storage Mater., 2023, 56: 432 |
| 46 | de Brito Ferraz M, Botta W J, Zepon G. Synthesis, characterization and first hydrogen absorption/desorption of the Mg35Al15Ti25-V10Zn15 high entropy alloy [J]. Int. J. Hydrogen Energy, 2022, 47: 22881 |
| 47 | El Osery I A. Theory of the computer code RET 1 for the calculation of space-time dependent temperature and composition properties of metal hydride hydrogen storage beds [J]. Int. J. Hydrogen Energy, 1983, 8: 191 |
| 48 | Lucas G, Richards W. Mathematical modelling of hydrogen storage systems [J]. Int. J. Hydrogen Energy, 1984, 9: 225 |
| 49 | Nasako K, Ito Y, Hiro N, et al. Stress on a reaction vessel by the swelling of a hydrogen absorbing alloy [J]. J. Alloys Compd., 1998, 264: 271 |
| 50 | Jemni A, Nasrallah S B. Study of two-dimensional heat and mass transfer during desorption in a metal-hydrogen reactor [J]. Int. J. Hydrogen Energy, 1995, 20: 881 |
| 51 | Mat M D, Kaplan Y, Aldas K. Investigation of three‐dimensional heat and mass transfer in a metal hydride reactor [J]. Int. J. Energy Res., 2002, 26: 973 |
| 52 | Lin X, Yin C L, Ren L, et al. A one- and three-dimensional coupled model and simulation investigation for the large-scale oil-heating type Mg-based hydrogen storage tank [J]. Chem. Eng. J., 2023, 472: 144943 |
| 53 | Shao L F, Lin X, Bian L S, et al. Engineering control strategy of hydrogen gas direct-heating type Mg-based solid state hydrogen storage tanks: A simulation investigation [J]. Appl. Energy, 2024, 375: 124134 |
| 54 | Wu Z, Yang F S, Zhang Z X, et al. Magnesium based metal hydride reactor incorporating helical coil heat exchanger: Simulation study and optimal design [J]. Appl. Energy, 2014, 130: 712 |
| 55 | Wu Z, Yang F S, Zhu L Y, et al. Improvement in hydrogen desorption performances of magnesium based metal hydride reactor by incorporating helical coil heat exchanger [J]. Int. J. Hydrogen Energy, 2016, 41: 16108 |
| 56 | Nyamsi N S, Wu Z, Zhang Z X, et al. Dehydrogenation performance of metal hydride container utilising MgH2-based composite [J]. Appl. Therm. Eng., 2022, 209: 118314 |
| 57 | Ye Y, Lu J F, Ding J, et al. Performance improvement of metal hydride hydrogen storage tanks by using phase change materials [J]. Appl. Energy, 2022, 320: 119290 |
| 58 | Lutz M, Bhouri M, Linder M, et al. Adiabatic magnesium hydride system for hydrogen storage based on thermochemical heat storage: Numerical analysis of the dehydrogenation [J]. Appl. Energy, 2019, 236: 1034 |
| 59 | Chang H, Tao Y B, Ye H. Numerical study on hydrogen and thermal storage performance of a sandwich reaction bed filled with metal hydride and thermochemical material [J]. Int. J. Hydrogen Energy, 2023, 48: 20006 |
| 60 | Jehan M, Fruchart D. McPhy-Energy's proposal for solid state hydrogen storage materials and systems [J]. J. Alloys Compd., 2013, 580: S343 |
| 61 | Ren L, Li Y H, Lin X, et al. Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems [J]. Front. Energy, 2023, 17: 320 |
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