脉冲电流对AZ91镁合金温挤压过程中动态析出和微观组织的影响
收稿日期: 2024-08-14
修回日期: 2024-10-28
网络出版日期: 2024-11-15
基金资助
山西省自然科学基金项目(20210302123134);山西省自然科学基金项目(202203021221071);山西省自然科学基金项目(202203021211157);山西省留学委员会项目(2022-045);山西浙大研究院新材料与化工研究院基础研究项目(2021SX-FR005)
Effect of Electropulse on Dynamic Precipitation and Microstructure of AZ91 Magnesium Alloy During Warm Extrusion
Received date: 2024-08-14
Revised date: 2024-10-28
Online published: 2024-11-15
Supported by
Natural Science Foundation of Shanxi Province(20210302123134);Natural Science Foundation of Shanxi Province(202203021221071);Natural Science Foundation of Shanxi Province(202203021211157);Shanxi Scholarship Council of China(2022-045);Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering(2021SX-FR005)
脉冲电流辅助成形工艺具有提高成型能力及细化微观组织等优点,被广泛用到各种塑性变形过程中。然而,关于脉冲电流在动态挤压变形过程中的作用尚不明确。本工作利用脉冲电流辅助挤压(EPAE)技术,研究了脉冲电流对于AZ91镁合金挤压过程中动态析出和微观组织的影响。结果表明,在能够完全动态再结晶(DRX)的临界变形条件下,EPAE工艺可以降低AZ91镁合金挤压过程中β-Mg17Al12相的体积分数并促使其发生球化,同时能够促进平均晶粒尺寸和最大基面织构强度的增加,且峰值电流密度越高,效果越明显。与常规热挤压相比,峰值电流密度为6.4 × 107 A/m2的EPAE工艺促使AZ91镁合金中β-Mg17Al12相的体积分数从76.9%降低至16.5%,平均晶粒尺寸从1.07 μm增加至3.54 μm,最大织构强度从3.39增加至5.92。在不均匀分布的β-Mg17Al12相的钉扎作用下,最终EPAE态AZ91镁合金内部形成双峰组织。实验及理论分析表明,脉冲电流中热效应和非热效应的共同作用所导致的AZ91镁合金挤压过程中的Gibbs自由能变化量和原子扩散通量的提高是上述实验现象发生的主要原因,在促进了β-Mg17Al12相的溶解及其附近Al溶质原子均匀分布的同时提高了晶界迁移速率。同时,脉冲电流可以通过其漂移电子对基面<a>滑移的加速作用促进β-Mg17Al12相颗粒贫乏区中晶粒的旋转。
关键词: AZ91镁合金; 脉冲电流辅助挤压; β-Mg17Al12相; 动态析出; 晶粒长大
王彬杉 , 徐光 , 任睿 , 张强 , 单召辉 , 樊建锋 . 脉冲电流对AZ91镁合金温挤压过程中动态析出和微观组织的影响[J]. 金属学报, 2025 , 61(1) : 129 -142 . DOI: 10.11900/0412.1961.2024.00256
The electropulse-assisted forming process has been widely used in various plastic deformation applications owing to its advantages in improving formability and refining microstructure. However, the influence of electropulse on the dynamic extrusion deformation process remains unclear. In this study, the effects of electropulse on dynamic precipitation and microstructure evolution of AZ91 magnesium alloy during extrusion were investigated using electropulse-assisted extrusion (EPAE) technology. The results demonstrate that under critical deformation conditions for complete dynamic recrystallization, the EPAE process reduces the volume fraction of the β-Mg17Al12 phase, promotes its spheroidization, and enhances both the average grain size and the maximum basal texture intensity. These effects become more pronounced with increasing peak current density. Specifically, with a peak current density of 6.4 × 107 A/m2 during the EPAE process, the volume fraction of the β-Mg17Al12 phase decreased from 76.9% to 16.5%, the average grain size increased from 1.07 μm to 3.54 μm, and the maximum basal texture intensity increased from 3.39 to 5.92, compared to conventional hot extrusion. The bimodal structure observed in the EPAE-processed AZ91 alloy was attributed to the pinning effect caused by the inhomogeneous distribution of the β-Mg17Al12 phase. Experimental and theoretical analyses indicated that the increase of Gibbs free energy variation and atomic diffusion flux during extrusion of AZ91 alloy caused by the combined thermal and athermal effects of the pulsed current was the main reason for the experimental phenomena, which promoting the solution of β-Mg17Al12 phase and uniform distribution of Al solute atoms nearby while also increasing the grain boundary migration rate. Moreover, the electropulse strengthened the basal texture in β-Mg17Al12 particle-depleted regions by accelerating basal <a> slip.
| 1 | Aghion E, Bronfin B. Magnesium alloys development towards the 21st century[J]. Mater. Sci. Forum, 2000, 350-351: 19 |
| 2 | Mordike B L, Ebert T. Magnesium: Properties-applications-potential[J]. Mater. Sci. Eng., 2001, A302: 37 |
| 3 | Chen X H, Pan F S, Mao J J, et al. Effect of heat treatment on strain hardening of ZK60 Mg alloy[J]. Mater. Des., 2011, 32: 1526 |
| 4 | Xu Q, Tang G Y, Jiang Y B. Thermal and electromigration effects of electropulsing on dynamic recrystallization in Mg-3Al-1Zn alloy[J]. Mater. Sci. Eng., 2011, A528: 4431 |
| 5 | Wang S N. Effect of electric pulses on drawability and corrosion property of AZ31 magnesium alloy[D]. Beijing: Tsinghua University, 2009 |
| 王少楠. 电脉冲对AZ31镁合金冲压性能和腐蚀性能的影响[D]. 北京: 清华大学, 2009 | |
| 6 | Shan Z H, Yang J, Fan J F, et al. Extraordinary mechanical properties of AZ61 alloy processed by ECAP with 160° channel angle and EPT[J]. J. Magnes. Alloy., 2021, 9: 548 |
| 7 | Jiang L Y, Zhang D F, Fan X W, et al. Microstructure and mechanical properties of as-extruded AZ80-xSn magnesium alloys[J]. Mater. Sci. Technol., 2016, 32: 1838 |
| 8 | Stanford N, Atwell D. The effect of Mn-rich precipitates on the strength of AZ31 extrudates[J]. Metall. Mater. Trans., 2013, 44A: 4830 |
| 9 | Moreau G, Cornet J A, Calais D. Acceleration de la diffusion chimique sous irradiation dans le systeme aluminium-magnesium[J]. J. Nucl. Mater., 1971, 38: 197 |
| 10 | Zhu T P, Chen Z W, Gao W. Dissolution of eutectic β-Mg17Al12 phase in magnesium AZ91 cast alloy at temperatures close to eutectic temperature[J]. J. Mater. Eng. Perform., 2010, 19: 860 |
| 11 | Shan Z H, Yang J, Fan J F, et al. Microstructure evolution and mechanical properties of an AZ61 alloy processed with TS-ECAP and EPT[J]. Mater. Sci. Eng., 2020, A780: 139195 |
| 12 | Godfrey A, Cao W Q, Liu Q, et al. Stored energy, microstructure, and flow stress of deformed metals[J]. Metall. Mater. Trans., 2005, 36A: 2371 |
| 13 | Lin B Y, Zhang H, Meng Y P, et al. Deformation behavior, microstructure evolution, and dynamic recrystallization mechanism of an AZ31 Mg alloy under high-throughput gradient thermal compression[J]. Mater. Sci. Eng., 2022, A847: 143338 |
| 14 | Xu H, Liu M, Wang Y P, et al. Refined microstructure and dispersed precipitates in a gradient rolled AZ91 alloy under pulsed current[J]. Materialia, 2021, 20: 101245 |
| 15 | Jeong H J, Kim M J, Park J W, et al. Effect of pulsed electric current on dissolution of Mg17Al12 phases in as-extruded AZ91 magnesium alloy[J]. Mater. Sci. Eng., 2017, A684: 668 |
| 16 | Shan Z H, Zhang Y X, Wang B S, et al. Microstructural evolution and precipitate behavior of an AZ61 alloy plate processed with ECAP and electropulsing treatment[J]. J. Mater. Res. Technol., 2022, 19: 382 |
| 17 | Qin R S, Samuel E I, Bhowmik A. Electropulse-induced cementite nanoparticle formation in deformed pearlitic steels[J]. J. Mater. Sci., 2011, 46: 2838 |
| 18 | Conrad H. Influence of an electric or magnetic field on the liquid-solid transformation in materials and on the microstructure of the solid[J]. Mater. Sci. Eng., 2000, A287: 205 |
| 19 | Qin R S, Zhou B L. Effect of electric current pulses on grain size in castings[J]. Int. J. Non-Equilib. Process., 1998, 11: 77 |
| 20 | Wang X L, Guo J D, Wang Y M, et al. Segregation of lead in Cu-Zn alloy under electric current pulses[J]. Appl. Phys. Lett., 2006, 89: 061910 |
| 21 | Jiang Y B, Tang G Y, Shek C, et al. Effect of electropulsing treatment on microstructure and tensile fracture behavior of aged Mg-9Al-1Zn alloy strip[J]. Appl. Phys., 2009, 97A: 607 |
| 22 | Onodera Y, Hirano K. The effect of a.c. frequency on precipitation in Al-5.6 at % Zn[J]. J. Mater. Sci., 1984, 19: 3935 |
| 23 | Sprecher A F, Mannan S L, Conrad H. On the temperature rise associated with the electroplastic effect in titanium[J]. Scr. Metall., 1983, 17: 769 |
| 24 | Porter D A, Easterling K E, Sherif M Y. Phase Transformations in Metals and Alloys (Revised Reprint)[M]. 3rd Ed., Boca Raton: CRC Press, 2009: 312 |
| 25 | Nabarro F R N. Dislocations in Solids[M]. Amsterdam: Elsevier, 1989: 499 |
| 26 | Sprecher A F, Mannan S L, Conrad H. Overview no. 49: On the mechanisms for the electroplastic effect in metals[J]. Acta Metall., 1986, 34: 1145 |
| 27 | Kim S H, You B S, Park S H. Effect of billet diameter on hot extrusion behavior of Mg-Al-Zn alloys and its influence on microstructure and mechanical properties[J]. J. Alloys Compd., 2017, 690: 417 |
| 28 | Braszczyńska-Malik K N. Spherical shape of γ-Mg17Al12 precipitates in AZ91 magnesium alloy processed by equal-channel angular pressing[J]. J. Alloys Compd., 2009, 487: 263 |
| 29 | Lee S W, Han G, Jun T S, et al. Effects of initial texture on deformation behavior during cold rolling and static recrystallization during subsequent annealing of AZ31 alloy[J]. J. Mater. Sci. Technol., 2021, 66: 139 |
| 30 | Di H S, Zhang X M, Wang G D, et al. Spheroidizing kinetics of eutectic carbide in the twin roll-casting of M2 high-speed steel[J]. J. Mater. Process. Technol., 2005, 166: 359 |
| 31 | Huang K, Marthinsen K, Zhao Q L, et al. The double-edge effect of second-phase particles on the recrystallization behaviour and associated mechanical properties of metallic materials[J]. Prog. Mater. Sci., 2018, 92: 284 |
| 32 | Shi D K. Fundamentals of Materials Science[M]. 2nd Ed., Beijing: China Machine Press, 2003: 363 |
| 石德珂. 材料科学基础[M]. 第2版, 北京: 机械工业出版社, 2003: 363 | |
| 33 | Guo F, Zhang D F, Yang X S, et al. Strain-induced dynamic precipitation of Mg17Al12 phases in Mg-8Al alloys sheets rolled at 748 K[J]. Mater. Sci. Eng., 2015, A636: 516 |
| 34 | Yan T L, Pei D, Cheng M H, et al. Development of Mg-6Al-4Sn-1Zn alloy sheets with ultra-high strength by combining extrusion and high-speed rolling[J]. J. Mater. Res. Technol., 2024, 29: 1487 |
| 35 | Zhang Q, Li Q A, Chen X Y, et al. Dynamic precipitation and recrystallization mechanism during hot compression of Mg-Gd-Y-Zr alloy[J]. J. Mater. Res. Technol., 2021, 15: 37 |
| 36 | Okazaki K, Kagawa M, Conrad H. A study of the electroplastic effect in metals[J]. Scr. Metall., 1978, 12: 1063 |
| 37 | Okazaki K, Kagawa M, Conrad H. Additional results on the electroplastic effect in metals[J]. Scr. Metall., 1979, 13: 277 |
| 38 | Xiang S Q, Zhang X F. Dislocation structure evolution under electroplastic effect[J]. Mater. Sci. Eng., 2019, A761: 138026 |
| 39 | Bhattacharyya J J, Agnew S R, Muralidharan G. Texture enhancement during grain growth of magnesium alloy AZ31B[J]. Acta Mater., 2015, 86: 80 |
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