研究论文

堆垛层错能对CrMnFeCoNi系高熵合金动态力学性能与变形机制的影响

  • 尹仕攀 ,
  • 孟泽宇 ,
  • 贺竞瑶 ,
  • 李泽洲 ,
  • 张帆 ,
  • 程兴旺
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  • 1 北京理工大学 材料学院 北京 100081
    2 北京理工大学 冲击环境材料技术国家级重点实验室 北京 100081
    3 北京理工大学 唐山研究院 唐山 063000
尹仕攀,男,1993年生,博士生
张帆,fanzhang@bit.edu.cn,主要从事极端加载条件下先进金属材料的设计、变形机制及应用研究; 程兴旺,chengxw@bit.edu.cn,主要从事新型毁伤与防护材料、材料动态力学行为和微结构演化机制研究

收稿日期: 2024-05-07

  修回日期: 2024-06-03

  网络出版日期: 2024-08-15

基金资助

国家自然科学基金项目(52271141);冲击环境材料技术国家级重点实验室基金项目(DZC2022-1)

Effect of Stacking Fault Energy on the Dynamic Mechanical Properties and Deformation Mechanisms of CrMnFeCoNi High-Entropy Alloys

  • YIN Shipan ,
  • MENG Zeyu ,
  • HE Jingyao ,
  • LI Zezhou ,
  • ZHANG Fan ,
  • CHENG Xingwang
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  • 1 School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
    2 National Key Laboratory of Science and Technology on Materials Under Shock and Impact, Beijing Institute of Technology, Beijing 100081, China
    3 Tangshan Research Institute, Beijing Institute of Technology, Tangshan 063000, China
ZHANG Fan, professor, Tel: 13581586228, E-mail: fanzhang@bit.edu.cn; CHENG Xingwang, professor, Tel: (010)68913951, E-mail: chengxw@bit.edu.cn

Received date: 2024-05-07

  Revised date: 2024-06-03

  Online published: 2024-08-15

Supported by

National Natural Science Foundation of China(52271141);National Key Laboratory Foundation of Science and Technology on Materials Under Shock and Impact(DZC2022-1)

摘要

为了探明堆垛层错能对CrMnFeCoNi系高熵合金动态力学响应行为的影响,本工作以具有不同堆垛层错能的等比例CrMnFeCoNi (35 mJ/m2)和非等比例Cr26Mn20Fe20Co20Ni14 (23 mJ/m2)高熵合金为研究对象,通过准静态和动态压缩性能测试,对比研究了不同堆垛层错能CrMnFeCoNi系高熵合金的动态力学性能特点;利用EBSD和TEM技术观察分析了变形组织,研究了不同堆垛层错能高熵合金的变形机制。结果表明,动态压缩条件下,CrMnFeCoNi和Cr26Mn20Fe20Co20Ni14高熵合金均表现出显著的应变率强化效应;准静态、动态压缩条件下,合金的流变应力、加工硬化指数和吸能能力均随着堆垛层错能的降低而增加。准静态变形时,CrMnFeCoNi高熵合金变形以位错滑移为主;Cr26Mn20Fe20Co20Ni14高熵合金以位错滑移和孪生为主。动态压缩变形时,孪生行为对变形的贡献增加,CrMnFeCoNi高熵合金的变形模式主要为位错滑移和孪生;堆垛层错能更低的Cr26Mn20Fe20Co20Ni14高熵合金在动态变形过程中除了位错滑移和孪生,还发生了孪晶交互作用与fcc-hcp相变以协调变形,该合金表现出更高的流变应力、加工硬化指数和吸能能力。可见,堆垛层错能的变化通过影响变形模式实现高熵合金动态力学性能的提升。

本文引用格式

尹仕攀 , 孟泽宇 , 贺竞瑶 , 李泽洲 , 张帆 , 程兴旺 . 堆垛层错能对CrMnFeCoNi系高熵合金动态力学性能与变形机制的影响[J]. 金属学报, 2025 , 61(12) : 1817 -1828 . DOI: 10.11900/0412.1961.2024.00133

Abstract

CrMnFeCoNi high-entropy alloys (HEAs) have attracted considerable attention because of their excellent mechanical properties. Furthermore, these alloys exhibit high energy absorption characteristics under high-strain rate deformation for various deformation modes. The stacking fault energy (SFE) plays a crucial role in improving the deformation modes and mechanical properties. Only few studies have investigated the effect of SFE on the dynamic mechanical properties and deformation mode of CrMnFeCoNi series HEAs. In this work, the effect of SFE on the dynamic mechanical properties and deformation mechanism of CrMnFeCoNi HEAs were investigated through quasi-static and dynamic mechanical tests and microstructural analysis using CrMnFeCoNi (SFE of 35 mJ/m2) and Cr26Mn20Fe20Co20Ni14 (SFE of 23 mJ/m2) HEAs. Results indicate that CrMnFeCoNi and Cr26Mn20Fe20Co20Ni14 HEAs exhibit a strain-rate hardening effect under dynamic deformation. Furthermore, the flow stress, energy absorption ability, and work hardening index increase under static and dynamic conditions with the decrease in SFE. Under quasi-static compression, deformation occurs via dislocation gliding in CrMnFeCoNi, whereas deformation twinning is profound in Cr26Mn20Fe20Co20Ni14 HEA with low SFE; therefore, deformation is dominated by dislocation slip and twinning. The contribution of deformation twinning to the deformation strain increases with the increase in strain rates. In particular, deformation occurs via dislocation gliding and twinning in CrMnFeCoNi HEA. Apart from dislocation slip and twinning, the interaction of twins and the transition from fcc to hcp structures provide additional deformation modes to accommodate the plastic deformation of Cr26Mn20Fe20Co20Ni14 HEA and improve the mechanical properties and energy absorption of these alloys. This work demonstrates that the change in SFE will lead to different deformation modes for accommodating plastic strain, thereby improving the mechanical properties of HEAs.

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