一种新型高强奥氏体低密度钢的强塑性机理
收稿日期: 2024-03-12
修回日期: 2024-04-28
网络出版日期: 2024-04-28
基金资助
云南省重点研发计划项目(202403AA080013);国家自然科学基金项目(52233018);国家自然科学基金项目(51831002);北京市自然科学基金项目(2242048)
Strengthening and Plastifying Mechanisms of a Novel High-Strength Low-Density Austenitic Steel
Received date: 2024-03-12
Revised date: 2024-04-28
Online published: 2024-04-28
Supported by
Yunnan Key Research and Development Program(202403AA080013);National Natural Science Foundation of China(52233018);National Natural Science Foundation of China(51831002);Beijing Municipal Natural Science Foundation(2242048)
高强低密度钢能在保证结构安全性的前提下降低重量,减少CO2排放,因此在汽车等交通运输工业中占有重要的地位。本工作设计并制备出一种密度为6.50 g/cm³的含Cr奥氏体钢。经35%压下率冷轧+时效 (35CR-T)和75%压下率冷轧+退火+时效(75CR-AT) 2种工艺路径所得到的样品均表现出优异的综合力学性能,2者的比屈服强度和总延伸率分别达到211.5 MPa·cm3/g、15.6%和210.0 MPa·cm3/g、21.5%。其中,35CR-T样品的显微组织由具有高密度位错的奥氏体和粗大的κ-碳化物组成;75CR-AT样品的显微组织由细小的再结晶奥氏体和更多、更细小的晶内κ-碳化物组成。因此,前者位错强化贡献值更高,而后者晶界强化和析出强化增量更高,这导致2种样品屈服强度相当。75CR-AT样品中再结晶奥氏体变形时依次形成平面滑移位错、Taylor晶格、高密度位错墙和微带等位错亚结构,而35CR-T样品中奥氏体内的微带结构限制了其变形时位错增殖和位错亚结构的形成,因此后者的塑性较前者差。
李夫顺 , 刘志鹏 , 丁灿灿 , 胡斌 , 罗海文 . 一种新型高强奥氏体低密度钢的强塑性机理[J]. 金属学报, 2025 , 61(6) : 909 -916 . DOI: 10.11900/0412.1961.2024.00077
High-strength low-density steels are strongly recommended in the automotive industry because they can reduce weight and CO2 emissions without affecting structural safety. In this study, a novel Cr-alloyed austenitic steel with a low density of 6.50 g/cm3 was designed. It was subjected to two types of processing routes. One includes cold rolling with a thickness reduction of 35% followed by aging at 450 oC for 1.5 h (known as 35CR-T). The other route includes cold rolling by 75%, short annealing at 925 oC for 10 s, and final aging at 450 oC for 1.5 h (known as 75CR-AT). Both resultant specimens exhibited excellent tensile properties; the specific yield strength and total elongation of the 35CR-T and 75CR-AT specimens reached 211.5 MPa·cm3/g, 15.6% and 210.0 MPa·cm3/g3, 21.5%, respectively. The microstructure of the former comprises relatively coarse austenite grains with high-density dislocations as the matrix and coarse κ-carbides, whereas that of the latter comprises fine recrystallized austenite grains and more extensive intragranular κ-carbides with a finer size. Consequently, greater dislocation strengthening contributes to the yield strength (YS) of the former, whereas more significant grain refinement and precipitation strengthening contribute to the YS of the latter. Therefore, both specimens have the same YS after considering all strengthening contributors. Moreover, the recrystallized austenite grains in 75CR-AT allow the sequential evolution of the dislocation substructure from planar-slip dislocations, Taylor lattice, and high-density dislocation wall to the microband during tensile deformation. By contrast, the dislocation microbands formed in the austenite grains of 35CR-T specimen suppress the dislocation multiplication and sequential evolution of dislocation substructures, resulting in poorer ductility compared with that of 75CR-AT specimen.
| 1 | Moon J, Ha H Y, Park S J, et al. Effect of Mo and Cr additions on the microstructure, mechanical properties and pitting corrosion resistance of austenitic Fe-30Mn-10.5Al-1.1C lightweight steels [J]. J. Alloys Compd., 2019, 775: 1136 |
| 2 | Liu C Q, Peng Q C, Xue Z L, et al. Research situation of Fe-Mn-Al-C system low-density high-strength steel [J]. Mater. Rep., 2019, 33: 2572 |
| 刘春泉, 彭其春, 薛正良 等. Fe-Mn-Al-C系列低密度高强钢的研究现状 [J]. 材料导报, 2019, 33: 2572 | |
| 3 | Chen S P, Rana R, Haldar A, et al. Current state of Fe-Mn-Al-C low density steels [J]. Prog. Mater. Sci., 2017, 89: 345 |
| 4 | Huang Z Y, Hou A L, Jiang Y S, et al. Rietveld refinement, microstructure, mechanical properties and oxidation characteristics of Fe-28Mn-xAl-1C (x = 10 and 12 wt. %) low-density steels [J]. J. Iron Steel Res. Int., 2017, 24: 1190 |
| 5 | Sutou Y, Kamiya N, Umino R, et al. High-strength Fe-20Mn-Al-C-based alloys with low density [J]. ISIJ Int., 2010, 50: 893 |
| 6 | Chen X P, Xu Y P, Ren P, et al. Aging hardening response and β-Mn transformation behavior of high carbon high manganese austenitic low-density Fe-30Mn-10Al-2C steel [J]. Mater. Sci. Eng., 2017, A703: 167 |
| 7 | Kim S H, Kim H, Kim N J. Brittle intermetallic compound makes ultrastrong low-density steel with large ductility [J]. Nature, 2015, 518: 77 |
| 8 | Yoo J D, Hwang S W, Park K T. Factors influencing the tensile behavior of a Fe-28Mn-9Al-0.8C steel [J]. Mater. Sci. Eng., 2009, A508: 234 |
| 9 | Frommeyer G, Brüx U. Microstructures and mechanical properties of high-strength Fe-Mn-Al-C light-weight TRIPLEX steels [J]. Steel Res. Int., 2006, 77: 627 |
| 10 | Raabe D, Springer H, Gutierrez-Urrutia I, et al. Alloy design, combinatorial synthesis, and microstructure-property relations for low-density Fe-Mn-Al-C austenitic steels [J]. JOM, 2014, 66: 1845 |
| 11 | Yang F Q, Song R B, Li Y P, et al. Tensile deformation of low density duplex Fe-Mn-Al-C steel [J]. Mater. Des., 2015, 76: 32 |
| 12 | Hwang S W, Ji J H, Lee E G, et al. Tensile deformation of a duplex Fe-20Mn-9Al-0.6C steel having the reduced specific weight [J]. Mater. Sci. Eng., 2011, A528: 5196 |
| 13 | Ha M C, Koo J M, Lee J K, et al. Tensile deformation of a low density Fe-27Mn-12Al-0.8C duplex steel in association with ordered phases at ambient temperature [J]. Mater. Sci. Eng., 2013, A586: 276 |
| 14 | Ren P, Chen X P, Cao Z X, et al. Synergistic strengthening effect induced ultrahigh yield strength in lightweight Fe-30Mn-11Al-1.2C steel [J]. Mater. Sci. Eng., 2019, A752: 160 |
| 15 | Yoo J D, Park K T. Microband-induced plasticity in a high Mn-Al-C light steel [J]. Mater. Sci. Eng., 2008, A496: 417 |
| 16 | Gutierrez-Urrutia I, Raabe D. Influence of Al content and precipitation state on the mechanical behavior of austenitic high-Mn low-density steels [J]. Scr. Mater., 2013, 68: 343 |
| 17 | Lee J, Park S, Kim H, et al. Simulation of κ-carbide precipitation kinetics in aged low-density Fe-Mn-Al-C steels and its effects on strengthening [J]. Met. Mater. Int., 2018, 24: 702 |
| 18 | Wu Z Q, Ding H, An X H, et al. Influence of Al content on the strain-hardening behavior of aged low density Fe-Mn-Al-C steels with high Al content [J]. Mater. Sci. Eng., 2015, A639: 187 |
| 19 | Jiang Z H, Jin J J, Wang X Z, et al. Microstructure and properties of a low-density steel with high strength of 1350 MPa [J]. J. Aeronaut. Mater., 2018, 38(5): 67 |
| 江志华, 金建军, 王晓震 等. 一种1350 MPa级低密度高强度钢的组织性能 [J]. 航空材料学报, 2018, 38(5): 67 | |
| 20 | Seward G G E, Celotto S, Prior D J, et al. In situ SEM-EBSD observations of the hcp to bcc phase transformation in commercially pure titanium [J]. Acta Mater., 2004, 52: 821 |
| 21 | Humphreys F J. Review Grain and subgrain characterisation by electron backscatter diffraction [J]. J. Mater. Sci., 2001, 36: 3833 |
| 22 | Wang Y J, Sun J J, Jiang T, et al. A low-alloy high-carbon martensite steel with 2.6?GPa tensile strength and good ductility [J]. Acta Mater., 2018, 158: 247 |
| 23 | He B B, Hu B, Yen H W, et al. High dislocation density-induced large ductility in deformed and partitioned steels [J]. Science, 2017, 357: 1029 |
| 24 | Wang Z W, Lu W J, Zhao H, et al. Ultrastrong lightweight compositionally complex steels via dual-nanoprecipitation [J]. Sci. Adv., 2020, 6: eaba9543 |
| 25 | Ardell A J. Precipitation hardening [J]. Metall. Trans., 1985, 16A: 2131 |
| 26 | Zhao Y L, Li Y R, Yeli G M, et al. Anomalous precipitate-size-dependent ductility in multicomponent high-entropy alloys with dense nanoscale precipitates [J]. Acta Mater., 2022, 223: 117480 |
| 27 | Yang T, Zhao Y L, Tong Y, et al. Multicomponent intermetallic nanoparticles and superb mechanical behaviors of complex alloys [J]. Science, 2018, 362: 933 |
| 28 | Wang Z W, Lu W J, Zhao H, et al. Formation mechanism of κ- carbides and deformation behavior in Si-alloyed FeMnAlC lightweight steels [J]. Acta Mater., 2020, 198: 258 |
| 29 | Zhang J L, Raabe D, Tasan C C. Designing duplex, ultrafine-grained Fe-Mn-Al-C steels by tuning phase transformation and recrystallization kinetics [J]. Acta Mater., 2017, 141: 374 |
| 30 | Yoo J D, Hwang S W, Park K T. Origin of extended tensile ductility of a Fe-28Mn-10Al-1C steel [J]. Metall. Mater. Trans., 2009, 40A: 1520 |
/
| 〈 |
|
〉 |