研究论文

固溶时效对激光沉积修复ZM6合金组织及力学性能的影响

  • 钦兰云 ,
  • 张健 ,
  • 伊俊振 ,
  • 崔岩峰 ,
  • 杨光 ,
  • 王超
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  • 1 沈阳航空航天大学 机电工程学院 沈阳 110136
    2 沈阳航空航天大学 材料科学与工程学院 沈阳 110136
    3 沈阳航空航天大学 航空制造工艺数字化国防重点学科实验室 沈阳 110136
    4 中国航发哈尔滨东安发动机有限公司 哈尔滨 150066
钦兰云,女,1977年生,教授,博士
伊俊振,jzyi@sau.edu.cn,主要从事激光沉积制造、激光沉积修复方面的研究;
杨 光,yangguang@sau.edu.cn,主要从事金属激光沉积制造方面的研究

收稿日期: 2023-08-10

  修回日期: 2023-12-07

  网络出版日期: 2024-02-27

基金资助

国家重点研发计划项目(2022YFE0122600);中国航空发动机集团产学研合作项目(HFZL2021CXY025-1);辽宁省教育厅基金项目(JYT2020061);沈阳航空航天大学航空制造工艺数字化国防重点学科实验室开放基金项目(SHSYS202001)

Effects of Solution Aging on Microstructural Evolution and Mechanical Properties of Laser Deposition Repairing ZM6 Alloy

  • QIN Lanyun ,
  • ZHANG Jian ,
  • YI Junzhen ,
  • CUI Yanfeng ,
  • YANG Guang ,
  • WANG Chao
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  • 1 School of Mechatronics Engineering, Shenyang Aerospace University, Shenyang 110136, China
    2 School of Materials Science and Engineering, Shenyang Aerospace University, Shenyang 110136, China
    3 Key Laboratory of Fundamental Science for National Defense of Aeronautical Digital Manufacturing Process, Shenyang Aerospace University, Shenyang 110136, China
    4 AECC Harbin Dongan Engine Co. Ltd., Harbin 150066, China
YI Junzhen, associate professor, Tel: 18004024448, E-mail: jzyi@sau.edu.cn;
YANG Guang, professor, Tel: 18040037100, E-mail: yangguang@sau.edu.cn

Received date: 2023-08-10

  Revised date: 2023-12-07

  Online published: 2024-02-27

Supported by

National Key Research and Development Program of China(2022YFE0122600);China Aero Engine Group Industry University Research Cooperation Project(HFZL2021CXY025-1);Liaoning Province Department of Education Fund(JYT2020061);Open Fund of Key Laboratory of Fundamental Science for National Defense of Aeronautical Digital Manufacturing Process of Shenyang Aerospace University(SHSYS202001)

摘要

为了提高镁合金航空构件修复质量、延长服役寿命,本工作针对航空镁合金构件的冶金缺陷及服役损伤开展了ZM6合金激光沉积修复研究,对比分析了固溶时效(T6:520 ℃、8 h + 220 ℃、14 h)处理前后修复试样微观组织及力学性能的变化。结果表明,沉积态试样修复区组织由细小的α-Mg相和第二相组成,第二相主要以连续网状分布在晶界处,少量以点状及棒状分布在晶粒内部。修复区平均硬度为(60 ± 2) HV0.1,修复试样的抗拉强度、屈服强度和延伸率分别为137.47 MPa、111.61 MPa和5.57%,其断裂位置在基材部分,断裂模式为沿晶-穿晶混合的脆性断裂;经T6处理后,修复区组织由细小的α-Mg晶粒和异常粗大晶粒组成,且晶粒内部析出了β′相。T6处理后试样修复区的平均硬度提高17.5%,异常粗大晶粒和细小晶粒导致硬度波动范围较大,抗拉强度和屈服强度分别提升了49.8%和75.6%,但延伸率有所下降。拉伸试样断裂位置在修复区,异常粗大晶粒是引起断裂的主要原因。

本文引用格式

钦兰云 , 张健 , 伊俊振 , 崔岩峰 , 杨光 , 王超 . 固溶时效对激光沉积修复ZM6合金组织及力学性能的影响[J]. 金属学报, 2025 , 61(6) : 875 -886 . DOI: 10.11900/0412.1961.2023.00330

Abstract

ZM6 (Mg-Nd-Zn-Zr) alloy is a typical casting magnesium alloy with low density, high specific strength and stiffness, good vibration damping performance, good machinability, and good heat resistance. It is widely used in aerospace and aviation fields. However, metallurgical or machining defects are inevitable while processing due to the complicated shapes and large scales of aviation components. Failure to repair them may lead to significant economic loss. Laser deposition repair can be applied to aerospace components because of the advantages of small heat input and high molding accuracy. This work focuses on repairing the aerospace ZM6 magnesium alloy components using laser deposition, addressing the metallurgical defects and service damage to the components. The changes in the microstructure and mechanical properties of the repaired ZM6 samples before and after solution aging (T6: 520 oC, 8 h + 220 oC, 14 h) treatment were compared. The results show that the microstructure of the repaired zone of the as-deposited sample consists of fine α-Mg grains. The secondary phases distributed mainly at grain boundaries showed a continuous network, and a small number of the dot- and rod-shaped secondary phases were distributed inside Mg grains. The average hardness of the repaired zone is (60 ± 2) HV0.1, and the tensile strength, yield strength, and elongation were 137.47 MPa, 111.61 MPa, and 5.57%, respectively. The fracture occurred in the base metal, and the tensile fracture mode comprised transgranular and intergranular brittle fractures. After T6 treatment, the microstructure of the repaired zone comprised fine α-Mg grains and abnormally coarse grains, and β′ phase was precipitated inside the grains. The average hardness of the repaired zone increased by 17.5% compared to that of the as-deposited samples, and the abnormally coarse and fine grains led to various hardness fluctuations. The tensile strength and yield strength of the T6-treated samples increased by 49.8% and 75.6%, respectively, but the elongation decreased. The fracture location of the tensile sample was in the repaired zone because of the formation of abnormally coarse grains.

参考文献

1 Song J F, She J, Chen D L, et al. Latest research advances on magnesium and magnesium alloys worldwide [J]. J. Magnes. Alloy., 2020, 8: 1
2 Xu T C, Yang Y, Peng X D, et al. Overview of advancement and development trend on magnesium alloy [J]. J. Magnes. Alloy., 2019, 7: 536
3 Yang Y, Xiong X M, Chen J, et al. Research advances in magnesium and magnesium alloys worldwide in 2020 [J]. J. Magnes. Alloy., 2021, 9: 705
4 Song B, Zhang J L, Zhang Y J, et al. Research progress of materials design for metal laser additive manufacturing [J]. Acta Metall. Sin., 2023, 59: 1
  宋 波, 张金良, 章媛洁 等. 金属激光增材制造材料设计研究进展 [J]. 金属学报, 2023, 59: 1
5 Wu G H, Wang C L, Sun M, et al. Recent developments and applications on high-performance cast magnesium rare-earth alloys [J]. J. Magnes. Alloy., 2021, 9: 1
6 Tang W N, Mo N, Hou J, et al. Research progress of additively manufactured magnesium alloys: A review [J]. Acta Metall. Sin., 2023, 59: 205
  唐伟能, 莫 宁, 侯 娟. 增材制造镁合金技术现状与研究进展 [J]. 金属学报, 2023, 59: 205
7 Cheng B, Mao C, Zhang M J, et al. Comparative study on microstructure and properties of laser welding and argon arc welding Hastelloy C-276/SS304 with filler wire [J]. Opt. Laser Technol., 2023, 164: 109565
8 Ci S W, Liang J J, Li J G, et al. Microstructure and tensile properties of DD32 single crystal Ni-base superalloy repaired by laser metal forming [J]. J. Mater. Sci. Technol., 2020, 45: 23
9 Lin X, Cao Y Q, Wu X Y, et al. Microstructure and mechanical properties of laser forming repaired 17-4PH stainless steel [J]. Mater. Sci. Eng., 2012, A553: 80
10 Smail B S, Cailloux T, Quinsat Y, et al. Integrated approach to stainless steel 316L parts repair for pitting corrosion using laser metal deposition [J]. J. Manuf. Processes, 2023, 95: 1
11 Yan W G, Zeng W, Man J X, et al. Microstructure and mechanical properties of a directionally solidified superalloy DZ411 plate sample repaired by laser melting deposition [J]. Mater. Sci. Eng., 2023, A876: 145141
12 Wang Z D, Yang K, Chen M Z, et al. Investigation of the microstructure and mechanical properties of Ti-6Al-4V repaired by the powder-blown underwater directed energy deposition technique [J]. Mater. Sci. Eng., 2022, A831: 142
13 Qin L Y, Pang S, Yang G, et al. Microstructure and micro-hardness of laser deposition repair ZL114A aluminum alloy [J]. Infrared Laser Eng., 2017, 46: 0506004
  钦兰云, 庞 爽, 杨 光 等. 激光沉积修复ZL114A铝合金的显微组织及显微硬度研究 [J]. 红外与激光工程, 2017, 46: 0506004
14 Peng L M, Deng Q C, Wu Y J, et al. Additive manufacturing of magnesium alloys by selective laser melting technology: A review [J]. Acta Metall. Sin., 2023, 59: 31
  彭立明, 邓庆琛, 吴玉娟 等. 镁合金选区激光熔化增材制造技术研究现状与展望 [J]. 金属学报, 2023, 59: 31
15 Dai J, Huang J, Li M, et al. Effects of heat treatments on laser welded Mg-rare earth alloy NZ30K [J]. Mater. Sci. Eng., 2011, A529: 401
16 Singh K. Effect of post-welding heat treatment on mechanical and microstructural properties of friction stir welded dissimilar magnesium alloys [J]. Mater. Today Proc., 2023, doi: 10.1016/j.matpr.2023.02.133
17 Tong X, Zhang G, Wu G H, et al. Addressing the abnormal grain coarsening during post-weld heat treatment of TIG repair welded joint of sand-cast Mg-Y-RE-Zr alloy [J]. Mater. Charact., 2021, 176: 111125
18 Zhang G Q, Tong X, Wu G H, et al. Research on the post-weld heat treatment of TIG repair welded joint of sand-cast Mg-Y-RE-Zr alloy [J]. Mater. Sci. Eng., 2021, A821: 141577
19 Yang G, Zhang W Q, Zhang J, et al. Evolution of microstructure of WE43 magnesium alloys fabricated by laser deposition manufacturing with subsequent friction stir processing [J]. Mater. Lett., 2023, 330: 133218
20 Jiao X Y, Li X J, Zhan L Q, et al. The Microstructural evolution and grain growth kinetics of fine-grained extruded Mg-Nd-Zn-Zr alloy [J]. Materials (Basel), 2022, 15: 3556
21 Ning Z L, Cao F Y, Liu H H, et al. Microstructure analysis of Mg-2.54Nd-0.26Zn-0.32Zr alloy [J]. Rare. Met. Mater. Eng., 2009, 38: 1997
  宁志良, 曹福洋, 刘洪汇 等. Mg-2.54Nd-0.26Zn-0.32Zr合金组织分析 [J]. 稀有金属材料与工程, 2009, 38: 1997
22 Ning Z L, Liu H H, Cao F Y, et al. The effect of grain size on the tensile and creep properties of Mg-2.6Nd-0.35Zn-xZr alloys at 250 °C [J]. Mater. Sci. Eng., 2013, A560: 163
23 Gao M, Wang H K, Hao K D, et al. Evolutions in microstructure and mechanical properties of laser lap welded AZ31 magnesium alloy via beam oscillation [J]. J. Manuf. Processes, 2019, 45: 92
24 Lei Z L, Bi J, Li P, et al. Analysis on welding characteristics of ultrasonic assisted laser welding of AZ31B magnesium alloy [J]. Opt. Laser Technol., 2018, 105: 15
25 Harooni M, Carlson B, Strohmeier B R, et al. Pore formation mechanism and its mitigation in laser welding of AZ31B magnesium alloy in lap joint configuration [J]. Mater. Des., 2014, 58: 265
26 Fu P H, Peng L M, Jiang H Yet al. Effects of heat treatments on the microstructures and mechanical properties of Mg-3Nd-0.2Zn-0.4Zr (wt.%) alloy [J]. Mater. Sci. Eng., 2008, A486: 183
27 Chen R N, Chen Q H, Peng P, et al. Abnormal grain growth induced by <1120> orientation of AZ31 magnesium alloy [J]. Mater. Sci. Technol., 2023, 39: 1337
28 Pei R S, Korte-Kerzel S, Al-Samman T. Normal and abnormal grain growth in magnesium: Experimental observations and simulations [J]. J. Mater. Sci. Technol., 2020, 50: 257
29 Tang J W, Chen L, Li Z G, et al. Formation of abnormal coarse grains and its effects on corrosion behaviors of solution treated ZK60 Mg alloy [J]. Corros. Sci., 2021, 180: 109201
30 Kim H J, Jin S C, Jung J G, et al. Influence of undissolved second-phase particles on dynamic recrystallization behavior of Mg-7Sn-1Al-1Zn alloy during low- and high-temperature extrusions [J]. J. Mater. Sci. Technol., 2021, 71: 87
31 Lezaack M B, Simar A. Avoiding abnormal grain growth in thick 7XXX aluminium alloy friction stir welds during T6 post heat treatments [J]. Mater. Sci. Eng., 2021, A807: 140901
32 Zheng D D, Li Z, Jiang Y L, et al. Effect of multiple thermal cycles on the microstructure evolution of GA151K alloy fabricated by laser-directed energy deposition [J]. Addit. Manuf., 2022, 57: 102957
33 Qin L Y, Pang S, Yang G, et al. Microstructure and mechanical property analysis of ZL114A aluminum alloy repaired by laser deposition [J]. Infrared Laser Eng., 2016, 43: 108
  钦兰云, 庞 爽, 杨 光 等. 激光沉积修复ZL114A铝合金组织和力学性能分析 [J]. 中国激光, 2016, 43: 108
34 Zheng R X, Du J P, Gao S, et al. Transition of dominant deformation mode in bulk polycrystalline pure Mg by ultra-grain refinement down to sub-micrometer [J]. Acta Mater., 2020, 198: 35
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