B、Zr复合添加对IN718高温合金流动性的影响
收稿日期: 2022-10-12
修回日期: 2022-11-14
网络出版日期: 2023-03-28
基金资助
国家自然科学基金项目(51904218);国家自然科学基金项目(52031012)
Effect of Combined Addition of B and Zr on the Fluidity of IN718 Superalloy
Received date: 2022-10-12
Revised date: 2022-11-14
Online published: 2023-03-28
Supported by
National Natural Science Foundation of China(51904218);National Natural Science Foundation of China(52031012)
铸造高温合金的流动性对铸件成形和组织具有重要影响,但目前关于B和Zr元素对合金流动性的影响规律及其作用机制的研究尚不充分。本工作采用螺旋型流动性测试模型、高温激光共聚焦显微镜和双热电偶法等研究了不同B和Zr含量对IN718高温合金的流动性、凝固过程、枝晶搭接点温度及持久性能的影响,探讨了B和Zr复合添加对流动性的影响机理。结果表明,复合添加B和Zr可同时有效提高IN718高温合金的流动性和高温持久性能。合金中B和Zr含量分别为0.0059%和0.042% (质量分数)时,流动性最好,比原始合金提高了90%以上,持久寿命提高了77%。当合金中B和Zr含量较高时,枝晶在糊状区具有较低的生长速率,使得枝晶搭接点温度(TDCP)降低,增大了液相线温度(TL)与枝晶搭接温度之差(TL- TDCP),延缓了枝晶搭接,从而有利于提高熔体流动性。
介子奇 , 刘鼎元 , $\boxed{\hbox{张军}}$ . B、Zr复合添加对IN718高温合金流动性的影响[J]. 金属学报, 2024 , 60(12) : 1615 -1621 . DOI: 10.11900/0412.1961.2022.00508
The fluidity of superalloy is an important property in the manufacture of large thin-walled and complex structure castings, but superalloys show high viscosity and a wide solidification temperature range, which may lead to serious defects, low yield, and poor performance. Therefore, the manufacturing of these castings is important to improve the fluidity by regulating the alloy composition. B and Zr, as common elements in superalloys, have important effects on solidification, microstructure, and mechanical properties. However, the effect of B and Zr on the fluidity and mechanism of superalloys remain unclear. In this study, the spiral fluidity test, high-temperature confocal laser scanning microscopy, and double-thermocouple method were used to investigate the fluidity, solidification, dendrite coherency point temperature, and stress rupture property of the IN718 superalloy with various B and Zr contents, whereas the mechanism of the effect of B and Zr on fluidity was also discussed. Results show that the combined addition of B and Zr can improve the fluidity and high-temperature stress rupture property of the IN718 superalloy. At different pouring temperatures, the fluidity of the alloy increases with the increase of B and Zr contents. The optimum fluidity is obtained with 0.0059%B and 0.042%Zr (mass fraction), respectively, which is about 90% higher than that of the original alloy and increases the stress rupture life by 77%. In the IN718 superalloy with a high content of B and Zr, the dendrite growth rate in the mushy zone is low, which reduces the dendrite coherency point temperature (TDCP), increases the difference between liquidus temperature (TL) and TDCP (TL- TDCP), delays the dendrite coherency, and improves the melt fluidity.
| 1 | Zhang J, Jie Z Q, Huang T W, et al. Research and development of equiaxed grain solidification and forming technology for nickel-based cast superalloys [J]. Acta Metall. Sin., 2019, 55: 1145 |
| 张 军, 介子奇, 黄太文 等. 镍基铸造高温合金等轴晶凝固成形技术的研究和进展 [J]. 金属学报, 2019, 55: 1145 | |
| 2 | Sun B D, Wang J, Kang M D, et al. Investment casting technology and development trend of superalloy ultra limit components [J]. Acta Metall. Sin., 2022, 58: 412 |
| 孙宝德, 王 俊, 康茂东 等. 高温合金超限构件精密铸造技术及发展趋势 [J]. 金属学报, 2022, 58: 412 | |
| 3 | Zielińska M, Yavorska M, Por?ba M, et al. Thermal properties of cast nickel based superalloys [J]. Arch. Mater. Sci. Eng., 2010, 44: 35 |
| 4 | El-Bagoury N. Ni based superalloy: Casting technology, metallurgy, development, properties and applications [J]. Int. J. Eng. Sci. Res. Technol., 2016, 5: 108 |
| 5 | Jie Z Q, Zhang J, Huang T W, et al. Effects of boron and zirconium additions on the fluidity, microstructure and mechanical properties of IN718C superalloy [J]. J. Mater. Res., 2016, 31: 3557 |
| 6 | Moosavy H N, Aboutalebi M R, Seyedein S H, et al. A solidification model for prediction of castability in the precipitation-strengthened nickel-based superalloys [J]. J. Mater. Process. Technol., 2013, 213: 1875 |
| 7 | Zhang J, Singer R F. Effect of Zr and B on castability of Ni-based superalloy IN792 [J]. Metall. Mater. Trans., 2004, 35A: 1337 |
| 8 | Qi F, Yu L X, Zhao G D, et al. Effect of Zr on solidification segregation behavior of K417G alloy and its anomalous effect during rapid cooling process [J]. J. Alloys Compd., 2020, 835: 155243 |
| 9 | Zhao G D, Yu L X, Yang G L, et al. The role of boron in modifying the solidification and microstructure of nickel-base alloy U720Li [J]. J. Alloys Compd., 2016, 686: 194 |
| 10 | Zhou Y, Wang B, Li S P, et al. On the segregation behavior and influences of minor alloying element Zr in nickel-based superalloys [J]. J. Alloys Compd., 2022, 897: 163169 |
| 11 | Heydari D, Fard A S, Bakhshi A, et al. Hot tearing in polycrystalline Ni-based IN738LC superalloy: Influence of Zr content [J]. J. Mater. Process. Technol., 2014, 214: 681 |
| 12 | Kontis P, Alabort E, Barba D, et al. On the role of boron on improving ductility in a new polycrystalline superalloy [J]. Acta Mater., 2017, 124: 489 |
| 13 | Hosseini S A, Madar K Z, Abbasi S M. Effect of homogenization heat treatments on the cast structure and tensile properties of nickel-base superalloy ATI 718Plus in the presence of boron and zirconium additions [J]. Mater. Sci. Eng., 2017, A689: 103 |
| 14 | Li X X, Ou M Q, Wang M, et al. Effect of boron addition on the microstructure and mechanical properties of K4750 nickel-based superalloy [J]. J. Mater. Sci. Technol., 2021, 60: 177 |
| 15 | Theska F, Buerstmayr R, Liu H, et al. Influence of grain boundary precipitation and segregation on cracking of cast and wrought superalloys containing B and Zr [J]. Mater. Charact., 2022, 187: 111881 |
| 16 | Zhang J, Jie Z Q, Liu M N, et al. A method for preparing fluidity testing mould and sample of superalloy [P]. Chin Pat, 114279802A, 2022 |
| 张 军, 介子奇, 刘淼楠 等. 一种高温合金流动性测试模具及测试试样的制备方法 [P]. 中国专利, 114279802A, 2022 | |
| 17 | Yan X W, Xu Q Y, Liu Q W, et al. Dendrite growth in nickel-based superalloy with in-situ observation by high temperature confocal laser scanning microscopy and numerical simulation [J]. Mater. Lett., 2021, 286: 129213 |
| 18 | Miao Z J, Shan A D, Wang W, et al. Solidification process of conventional superalloy by confocal scanning laser microscope [J]. Trans. Nonferrous Metals Soc. China, 2011, 21: 236 |
| 19 | Shin J S, Ko S H, Kim K T. Development and characterization of low-silicon cast aluminum alloys for thermal dissipation [J]. J. Alloys Compd., 2015, 644: 673 |
| 20 | Stangeland A, Mo A, Nielsen ?, et al. Development of thermal strain in the coherent mushy zone during solidification of aluminum alloys [J]. Metall. Mater. Trans., 2004, 35A: 2903 |
| 21 | Malekan M, Shabestari S G. Effect of grain refinement on the dendrite coherency point during solidification of the A319 aluminum alloy [J]. Metall. Mater. Trans., 2009, 40A: 3196 |
| 22 | Arnberg L, Chai G, Backerud L. Determination of dendritic coherency in solidifying melts by rheological measurements [J]. Mater. Sci. Eng., 1993, A173: 101 |
| 23 | Hong H U, Kim I S, Choi B G, et al. On the role of grain boundary serration in simulated weld heat-affected zone liquation of a wrought nickel-based superalloy [J]. Metall. Mater. Trans., 2012, 43A: 173 |
| 24 | Ebner A S, Jakob S, Clemens H, et al. Grain boundary segregation in Ni-base alloys: A combined atom probe tomography and first principles study [J]. Acta Mater., 2021, 221: 117354 |
| 25 | Yeh A C, Lu K W, Kuo C M, et al. Effect of serrated grain boundaries on the creep property of Inconel 718 superalloy [J]. Mater. Sci. Eng., 2011, A530: 525 |
| 26 | Tsai Y L, Wang S F, Bor H Y, et al. Effects of Zr addition on the microstructure and mechanical behavior of a fine-grained nickel-based superalloy at elevated temperatures [J]. Mater. Sci. Eng., 2014, A607: 294 |
| 27 | Yan B C, Zhang J, Lou L H. Effect of boron additions on the microstructure and transverse properties of a directionally solidified superalloy [J]. Mater. Sci. Eng., 2008, A474: 39 |
| 28 | Xiao L, Chaturvedi M C, Chen D L. Effect of boron and carbon on the fracture toughness of IN 718 superalloy at room temperature and 650oC [J]. J. Mater. Eng. Perform., 2005, 14: 528 |
| 29 | Flemings M C. Solidification processing [J]. Metall. Trans., 1974, 5: 2121 |
| 30 | Campbell J. Castings [M]. 2nd ed. Oxford: Butterworth-Heinemann, 2003: 70 |
| 31 | Farahany S, Idris M H, Ourdjini A, et al. Evaluation of the effect of grain refiners on the solidification characteristics of an Sr-modified ADC12 die-casting alloy by cooling curve thermal analysis [J]. J. Therm. Anal. Calorim., 2015, 119: 1593 |
| 32 | Grodzki J, Hartmann N, Rettig R, et al. Effect of B, Zr, and C on hot tearing of a directionally solidified nickel-based superalloy [J]. Metall. Mater. Trans., 2016, 47A: 2914 |
| 33 | Liu Q M, Huang S Z, Liu F, et al. Effect of boron content on microstructure evolution during solidification and mechanical properties of K417G alloy [J]. Acta Metall. Sin., 2019, 55: 720 |
| 刘巧沐, 黄顺洲, 刘 芳 等. B含量对K417G合金凝固过程中组织演变和力学性能的影响 [J]. 金属学报, 2019, 55: 720 |
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