研究论文

镁合金LPSO/SFs结构间{101¯2}孪晶交汇机制的原子尺度研究

  • 邵晓宏 ,
  • 彭珍珍 ,
  • 靳千千 ,
  • 马秀良
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  • 1中国科学院金属研究所 沈阳材料科学国家研究中心 沈阳 110016
    2河北科技大学 材料科学与工程学院 石家庄 050018
    3广西科技大学 电子工程学院 先进物质结构研究中心 柳州 545006
邵晓宏,女,1981年生,研究员,博士
马秀良,xlma@imr.ac.cn,主要从事材料界面结构与缺陷的电子显微学研究

收稿日期: 2022-10-21

  修回日期: 2022-12-08

  网络出版日期: 2023-02-07

基金资助

国家自然科学基金项目(51871222);国家自然科学基金项目(52171021)

Unravelling the {101¯2} Twin Intersection Between LPSO Structure/SFs in Magnesium Alloy

  • SHAO Xiaohong ,
  • PENG Zhenzhen ,
  • JIN Qianqian ,
  • MA Xiuliang
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  • 1Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2School of Materials Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
    3Center for the Structure of Advanced Matter, School of Electronic Engineering, Guangxi University of Science and Technology, Liuzhou 545006, China
MA Xiuliang, professor, Tel: (024)23971845, E-mail: xlma@imr.ac.cn

Received date: 2022-10-21

  Revised date: 2022-12-08

  Online published: 2023-02-07

Supported by

National Natural Science Foundation of China(51871222);National Natural Science Foundation of China(52171021)

摘要

以含长周期堆垛有序(LPSO)结构的Mg-Zn-Y(-Zr)合金为研究对象,运用透射电子显微方法,从原子尺度解析LPSO结构/富含溶质元素堆垛层错(SFs)对{101¯2}孪晶交汇行为的作用。结果表明:LPSO/SFs与孪晶交截处易形成基面-棱柱面,从而引起孪晶界在LPSO/SFs间弯曲成弓形,孪晶界存在Zn元素偏聚,Y元素偏聚不明显。LPSO/SFs间同轴{101¯2}孪晶变体交汇,引入基面-基面(BB)界面及柱面-柱面(PP)界面,且在近LPSO/SFs处产生三角形的局部基体结构。LPSO结构形成扭折时,{101¯2}孪晶在扭折界面单侧形核长大,此处扭折界面转为孪晶界面;残余扭折界面与基体侧孪晶扩展界面相交,在LPSO/SFs近邻处形成三角形的基体结构。LPSO/SFs/TSFs (孪晶层错)间不同孪晶变体形核,以及交汇引入的分割带来的Hall-Petch效应,可提升合金的硬化率。通过调控镁合金LPSO结构的间距和厚度引入不同孪晶变体,可为其优化性能提供新思路。

本文引用格式

邵晓宏 , 彭珍珍 , 靳千千 , 马秀良 . 镁合金LPSO/SFs结构间{101¯2}孪晶交汇机制的原子尺度研究[J]. 金属学报, 2023 , 59(4) : 556 -566 . DOI: 10.11900/0412.1961.2022.00532

Abstract

The effect of long-period stacking ordered (LPSO) structure/solute-rich element laminar stacking faults (SFs) on the intersection of co-zone {101¯2} twin variants was uncovered at the atomic scale by TEM. The results show that a basal-prismatic (BP) boundary is generally formed at the intersection of LPSO/SFs and twins, bending the twin boundaries (TBs) into a bow shape between the adjacent LPSO/SFs. The co-zone {101¯2} twin variants and LPSO/SFs intersect with each other, introducing a basal-basal (BB) boundary and prismatic-prismatic (PP) boundaries, associated with a triangular matrix near the LPSO/SFs. More Zn atoms than Y atoms were segregated into the TBs. Also, when the LPSO structure is kinked, the {101¯2} twin generates and grows on one side of the kink boundary, and the local kink boundary transforms into TB. The growing TB intersects with the residual kink boundary, leaving a triangular matrix near the LPSO/SFs. Multiple twin variants nucleate between the LPSO/SFs/TSFs (twinned stacking faults), and the associated Hall-Petch effect is brought by the segmentation introduced by the intersecting of variants, which can improve the Mg alloy hardening rate. Introducing different twin variants by regulating the LPSO structure's spacing and thickness in magnesium alloy may shed new light on optimizing their performance.

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