研究论文

组元占比对层状纳米孪晶Cu力学行为的影响

  • 万涛 ,
  • 程钊 ,
  • 卢磊
展开
  • 1中国科学院金属研究所 沈阳材料科学国家研究中心 沈阳 110016
    2中国科学技术大学 材料科学与工程学院 沈阳 110016
万 涛,男,1995年生,博士生
卢 磊,llu@imr.ac.cn,主要从事纳米结构金属材料研究

收稿日期: 2022-11-01

  修回日期: 2022-12-14

  网络出版日期: 2023-01-18

基金资助

国家自然科学基金项目(51931010);国家自然科学基金项目(92163202);国家自然科学基金项目(52001312);中国科学院前沿科学重点研究计划项目(GJHZ2029);中国博士后科学基金(BX20190336);中国博士后科学基金(2019M661150);中国科学院金属研究所创新基金项目(2021-PY02)

Effect of Component Proportion on Mechanical Behaviors of Laminated Nanotwinned Cu

  • WAN Tao ,
  • CHENG Zhao ,
  • LU Lei
Expand
  • 1Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    2School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
LU Lei, professor, Tel: (024)23971939, E-mail: llu@imr.ac.cn

Received date: 2022-11-01

  Revised date: 2022-12-14

  Online published: 2023-01-18

Supported by

National Natural Science Foundation of China(51931010);National Natural Science Foundation of China(92163202);National Natural Science Foundation of China(52001312);Key Research Program of Frontier Science and International Partnership Program, Chinese Academy of Sciences(GJHZ2029);China Postdoctoral Science Foundation(BX20190336);China Postdoctoral Science Foundation(2019M661150);Innovation Fund of Institute of Metal Research, Chinese Academy of Sciences(2021-PY02)

摘要

利用直流电解沉积制备了表层为硬组元、芯部为软组元的3种层状纳米孪晶(LNT) Cu样品,其中软组元占比分别为10%、50%和90%。研究发现:随软组元占比增加,拉伸屈服强度由425 MPa下降至262 MPa,均匀延伸率由5.7%增加至17%。3种LNT Cu的屈服强度均高于利用混合法则计算的平均强度,即表现出明显的额外强化。当组元占比为50%时,LNT Cu在变形过程中的应变局域化被很好地抑制,组元间应变差较小且相互约束作用强,额外强化效应最明显。

本文引用格式

万涛 , 程钊 , 卢磊 . 组元占比对层状纳米孪晶Cu力学行为的影响[J]. 金属学报, 2023 , 59(4) : 567 -576 . DOI: 10.11900/0412.1961.2022.00554

Abstract

Laminated metals have the potential for achieving better mechanical properties, such as higher strength, ductility, and work hardening ability. The mechanism that leads to these advances stems from the inhomogeneous plastic deformations between soft and hard components where geometrically necessary dislocations (GNDs) are produced while the two adjacent components are mutually constrained. Many structural factors have already been extensively investigated during the optimization of the laminated structure, such as the effect of layer thickness and the strength differential between components on the overall resulting properties. However, the effect of component composition percentage, an important factor for laminated structures, on the mechanical properties and its underlying mechanism remains elusive. To unravel the effect of component composition percentage on the mechanical properties, we used stable nanotwinned structures as components to build laminated nanotwinned (LNT) Cu materials. Three LNT Cu samples with hard components on the surface layers and soft components in the core layer were designed and prepared by direct-current electrodeposition. The soft component percentages were set as 10%, 50%, and 90%. The mechanical behaviors of LNT Cu were explored by uniaxial tensile tests at room temperature. Yield strengths for all three LNT Cu were higher than that estimated by the rule of mixture, indicating an extra strengthening effect from the LNT structure. The LNT Cu containing 50% soft component (LNT-50%) demonstrated the greatest extra strengthening. Interestingly, full-field strain measurements and microstructure characterizations further indicated that the strain localization of LNT-50% was well suppressed and the lateral strain difference between the soft and hard components was obviously reduced. This indicated that the strong mutual constraint between the two components contributed to the greatest extra strengthening.

参考文献

1 Zhang X, Misra A, Wang H, et al. Enhanced hardening in Cu/330 stainless steel multilayers by nanoscale twinning [J]. Acta Mater., 2004, 52: 995
2 Huang C X, Wang Y F, Ma X L, et al. Interface affected zone for optimal strength and ductility in heterogeneous laminate [J]. Mater. Today, 2018, 21: 713
3 G?ken M, H?ppel H W. Tailoring nanostructured, graded, and particle-reinforced Al laminates by accumulative roll bonding [J]. Adv. Mater., 2011, 23: 2663
4 Koseki T, Inoue J, Nambu S. Development of multilayer steels for improved combinations of high strength and high ductility [J]. Mater. Trans., 2014, 55: 227
5 Huang M, Xu C, Fan G H, et al. Role of layered structure in ductility improvement of layered Ti-Al metal composite [J]. Acta Mater., 2018, 153: 235
6 Wang Y C, Luo X M, Chen L J, et al. Enhancement of shear stability of a Fe-based amorphous alloy using electrodeposited Ni layers [J]. J. Mater. Sci. Technol., 2018, 34: 2283
7 Ashby M F. The deformation of plastically non-homogeneous materials [J]. Philos. Mag., 1970, 21: 399
8 Fleck N A, Muller G M, Ashby M F, et al. Strain gradient plasticity: Theory and experiment [J]. Acta Metall. Mater., 1994, 42: 475
9 Gao H, Huang Y, Nix W D, et al. Mechanism-based strain gradient plasticity—I. Theory [J]. J. Mech. Phys. Solids, 1999, 47: 1239
10 Zeng Z, Li X Y, Xu D S, et al. Gradient plasticity in gradient nano-grained metals [J]. Extreme Mech. Lett., 2016, 8: 213
11 Kubin L P, Mortensen A. Geometrically necessary dislocations and strain-gradient plasticity: A few critical issues [J]. Scr. Mater., 2003, 48: 119
12 Gao H J, Huang Y G. Geometrically necessary dislocation and size-dependent plasticity [J]. Scr. Mater., 2003, 48: 113
13 Cao Z, Cheng Z, Xu W, et al. Effect of work hardening discrepancy on strengthening of laminated Cu/CuZn alloys [J]. J. Mater. Sci. Technol., 2022, 103: 67
14 Ma X L, Huang C X, Xu W Z, et al. Strain hardening and ductility in a coarse-grain/nanostructure laminate material [J]. Scr. Mater., 2015, 103: 57
15 Zhu Y T, Wu X L. Perspective on hetero-deformation induced (HDI) hardening and back stress [J]. Mater. Res. Lett., 2019, 7: 393
16 Fleck N A, Ashby M F, Hutchinson J W. The role of geometrically necessary dislocations in giving material strengthening [J]. Scr. Mater., 2003, 48: 179
17 Wu X L, Zhu Y T. Gradient and lamellar heterostructures for superior mechanical properties [J]. MRS Bull., 2021, 46: 244
18 Wu X L, Jiang P, Chen L, et al. Extraordinary strain hardening by gradient structure [J]. Proc. Natl. Acad. Sci. USA, 2014, 111: 7197
19 Beyerlein I J, Mara N A, Carpenter J S, et al. Interface-driven microstructure development and ultra high strength of bulk nanostructured Cu-Nb multilayers fabricated by severe plastic deformation [J]. J. Mater. Res., 2013, 28: 1799
20 Fu E G, Li N, Misra A, et al. Mechanical properties of sputtered Cu/V and Al/Nb multilayer films [J]. Mater. Sci. Eng., 2008, A493: 283
21 Wang Y F, Yang M X, Ma X L, et al. Improved back stress and synergetic strain hardening in coarse-grain/nanostructure laminates [J]. Mater. Sci. Eng., 2018, A727: 113
22 Wan T, Cheng Z, Bu L F, et al. Work hardening discrepancy designing to strengthening gradient nanotwinned Cu [J]. Scr. Mater., 2021, 201: 113975
23 Liang F, Tan H F, Zhang B, et al. Maximizing necking-delayed fracture of sandwich-structured Ni/Cu/Ni composites [J]. Scr. Mater., 2017, 134: 28
24 Cuan X Y, Pan J, Cao R Q, et al. Effect of amorphous layer thickness on the tensile behavior of bulk-sized amorphous Ni-P/crystalline Ni laminates [J]. Mater. Lett., 2018, 218: 150
25 Ma X L, Huang C X, Moering J, et al. Mechanical properties of copper/bronze laminates: Role of interfaces [J]. Acta Mater., 2016, 116: 43
26 Nizolek T, Beyerlein I J, Mara N A, et al. Tensile behavior and flow stress anisotropy of accumulative roll bonded Cu-Nb nanolaminates [J]. Appl. Phys. Lett., 2016, 108: 051903
27 Misra A, Hirth J P, Hoagland R G. Length-scale-dependent deformation mechanisms in incoherent metallic multilayered composites [J]. Acta Mater., 2005, 53: 4817
28 Wu X L, Jiang P, Chen L, et al. Synergetic strengthening by gradient structure [J]. Mater. Res. Lett., 2014, 2: 185
29 Meyers M A, Mishra A, Benson D J. Mechanical properties of nanocrystalline materials [J]. Prog. Mater. Sci., 2006, 51: 427
30 Kwan C C F, Wang Z R. Strain incompatibility and its influence on grain coarsening during cyclic deformation of ARB copper [J]. Philos. Mag., 2013, 93: 1065
31 Cheng Z, Zhou H F, Lu Q H, et al. Extra strengthening and work hardening in gradient nanotwinned metals [J]. Science, 2018, 362: eaau1925
32 Lu Q H, You Z S, Huang X X, et al. Dependence of dislocation structure on orientation and slip systems in highly oriented nanotwinned Cu [J]. Acta Mater., 2017, 127: 85
33 Cheng Z, Jin S, Lu L. Effect of electrolyte temperature on microstructures of direct-current electrodeposited nanotwinned Cu [J]. Acta Metall. Sin., 2018, 54: 428
  程 钊, 金 帅, 卢 磊. 电解液温度对直流电解沉积纳米孪晶Cu微观结构的影响 [J]. 金属学报, 2018, 54: 428
34 Cheng Z, Lu L. The effect of gradient order on mechanical behaviors of gradient nanotwinned Cu [J]. Scr. Mater., 2019, 164: 130
35 Chassaing E, Wiart R. Epitaxial growth and electrode impedance of copper electrodeposits [J]. Electrochim. Acta, 1984, 29: 649
36 You Z S, Lu L, Lu K. Tensile behavior of columnar grained Cu with preferentially oriented nanoscale twins [J]. Acta Mater., 2011, 59: 6927
37 Bai J S, Lu Q H, Lu L. Detwinning behavior induced by local shear strain in nanotwinned Cu [J]. Acta Metall. Sin., 2015, 52: 491
  白敬胜, 卢秋虹, 卢 磊. 纳米孪晶Cu中局部剪切应变诱导的退孪生行为 [J]. 金属学报, 2015, 52: 491
38 Semiatin S L, Piehler H R. Deformation of sandwich sheet materials in uniaxial tension [J]. Metall. Trans., 1979, 10A: 85
39 Zhu Y T, Ameyama K, Anderson P M, et al. Heterostructured materials: Superior properties from hetero-zone interaction [J]. Mater. Res. Lett., 2021, 9: 1
40 Bert C W, Mills E J, Hyler W S. Effect of variation in Poisson's ratio on plastic tensile instability [J]. J. Basic Eng., 1967, 89: 35
41 Sinclair C W, Saada G, Embury J D. Role of internal stresses in co-deformed two-phase materials [J]. Philos. Mag., 2006, 86: 4081
42 Jing L J, Pan Q S, Long J Z, et al. Effect of volume fraction of gradient nanograined layer on high-cycle fatigue behavior of Cu [J]. Scr. Mater., 2019, 161: 74
43 Li Y S, Zhang Y, Tao N R, et al. Effect of thermal annealing on mechanical properties of a nanostructured copper prepared by means of dynamic plastic deformation [J]. Scr. Mater., 2008, 59: 475
44 Zhang Z, Vajpai S K, Orlov D, et al. Improvement of mechanical properties in SUS304L steel through the control of bimodal microstructure characteristics [J]. Mater. Sci. Eng., 2014, A598: 106
文章导航

/