非均质Mn分布对淬火-配分钢微观组织和力学性能的影响
收稿日期: 2022-06-24
修回日期: 2022-08-11
网络出版日期: 2022-10-12
基金资助
国家自然科学基金项目(52271004);国家自然科学基金项目(51901021);北京理工大学科技创新计划创新人才科技专项计划项目(2019CX01019)
Effect of Mn Heterogeneous Distribution on Microstructures and Mechanical Properties of Quenching and Partitioning Steels
Received date: 2022-06-24
Revised date: 2022-08-11
Online published: 2022-10-12
Supported by
National Natural Science Foundation of China(52271004);National Natural Science Foundation of China(51901021);Science and Technology Innovation Project of Beijing Institute of Technology(2019CX01019)
目前,基于非均质高温奥氏体来调控先进高强钢的组织和性能,引起研究学者的广泛关注。为进一步明晰合金元素非均质程度对组织和性能的影响,指导先进高强钢的设计,本工作采用以Mn配分的珠光体为初始组织的快速淬火-配分工艺,研究了奥氏体化时间和温度对高温奥氏体中非均质Mn分布的影响规律,进一步探讨了微观组织和力学性能的演变。结果表明,高温奥氏体的Mn分布能够调控淬火过程的马氏体转变。当高温奥氏体继承了珠光体中富Mn渗碳体和贫Mn铁素体中的Mn分布时,淬火后可获得富Mn片状残余奥氏体与贫Mn马氏体板条构成的鬼珠光体组织。随奥氏体化保温时间的延长和温度的升高,高温奥氏体中Mn元素非均质程度减弱,导致鬼珠光体组织减少,块状残余奥氏体和粗大板条马氏体数量增多、且尺寸增大。随着保温时间的延长,屈服强度由于细晶强化的减弱而降低;均匀延伸率由于块状残余奥氏体的增多而升高,颈缩后的延伸率因块状残余奥氏体形成的脆性马氏体而降低。由于残余奥氏体和马氏体的含量随着奥氏体化工艺不发生改变,使得抗拉强度和断裂总延伸率也不发生变化。由此可见,通过改变奥氏体化的工艺参数,能够在保证高抗拉强度(约1700 MPa)和高断裂总延伸率(约20%)的基础上,实现对屈服强度和均匀延伸率的进一步调控。
张超 , 熊志平 , 杨德振 , 程兴旺 . 非均质Mn分布对淬火-配分钢微观组织和力学性能的影响[J]. 金属学报, 2024 , 60(1) : 69 -79 . DOI: 10.11900/0412.1961.2022.00315
The ever increasing demand for safe and lightweight steel has promoted the development of advanced high-strength steel (AHSS). Recently, many AHSSs have been developed through chemical heterogeneity, resulting in microstructure refinement and mechanical property optimization. Although many efforts emphasize the construction of Mn-heterogeneous high-temperature austenite (γ-Fe), the influence of Mn-heterogeneous distribution remains unclear. In this work, different austenitization times and temperatures are applied to Mn-partitioned pearlite, followed by the same quenching and partitioning process. The effect of Mn distribution in high-temperature austenite on the microstructural evolution and mechanical properties is systematically investigated. Results show that the Mn-heterogeneous high-temperature austenite can tailor the austenite-to-martensite transformation during quenching. The Mn-depleted austenite is then readily transformed into lath martensite, and the Mn-enriched austenite is mainly retained as film roughness (RA), both of which assemble the ghost pearlite. With an increase in austenitization time and temperature, the Mn atom diffusion from the Mn-enriched austenite (originated from cementite lamellae) to the Mn-depleted one (originated from ferrite lamellae) increases, leading to the decreased chemical heterogeneity in high-temperature austenite. Thus, the fraction of ghost pearlite decreases while the fraction and size of blocky RA and coarse lath martensite increase. A wider lath martensite lowers the strength of the yield or the elastic limit of steel. The increased fraction and size of blocky RA ensure an increased uniform elongation by transformation-induced plasticity effect, whereas the transformation product (i.e., fresh martensite) is detrimental to the post-uniform elongation. Meanwhile, because the fractions of RA and martensite hardly change with austenitization condition, the ultimate tensile strength (about 1700 MPa) and total elongation (about 20%) are relatively constant. Therefore, tuning the Mn distribution in high-temperature austenite provides an effective strategy to tailor yield strength and uniform elongation while maintaining large ultimate tensile strength and total elongation.
| 1 | Xiong Z P, Saleh A A, Marceau R K W, et al. Site-specific atomic-scale characterisation of retained austenite in a strip cast TRIP steel [J]. Acta Mater., 2017, 134: 1 |
| 2 | Xiong X C, Chen B, Huang M X, et al. The effect of morphology on the stability of retained austenite in a quenched and partitioned steel [J]. Scr. Mater., 2013, 68: 321 |
| 3 | Xu W, Huang M H, Wang J L, et al. Review: Relations between metastable austenite and fatigue behavior of steels [J]. Acta Metall. Sin., 2020, 56: 459 |
| 徐 伟, 黄明浩, 王金亮 等. 综述: 钢中亚稳奥氏体组织与疲劳性能关系 [J]. 金属学报, 2020, 56: 459 | |
| 4 | Liu M, Hu H J, Tian J Y, et al. Effect of ausforming on the microstructures and mechanical properties of an ultra-high strength bainitic steel [J]. Acta Metall. Sin., 2021, 57: 749 |
| 刘 曼, 胡海江, 田俊羽 等. 变形对超高强贝氏体钢组织和力学性能的影响 [J]. 金属学报, 2021, 57: 749 | |
| 5 | Speer J, Matlock D K, De Cooman B C, et al. Carbon partitioning into austenite after martensite transformation [J]. Acta Mater., 2003, 51: 2611 |
| 6 | Caballero F G, Bhadeshia H K D H. Very strong bainite [J]. Curr. Opin. Solid State Mater. Sci., 2004, 8: 251 |
| 7 | Luo H W, Shi J, Wang C, et al. Experimental and numerical analysis on formation of stable austenite during the intercritical annealing of 5Mn steel [J]. Acta Mater., 2011, 59: 4002 |
| 8 | Ding R, Yao Y J, Sun B H, et al. Chemical boundary engineering: A new route toward lean, ultrastrong yet ductile steels [J]. Sci. Adv., 2020, 6: eaay1430 |
| 9 | Sun W W, Wu Y X, Yang S C, et al. Advanced high strength steel (AHSS) development through chemical patterning of austenite [J]. Scr. Mater., 2018, 146: 60 |
| 10 | Kim J H, Gu G, Kwon M H, et al. Microstructure and tensile properties of chemically heterogeneous steel consisting of martensite and austenite [J]. Acta Mater., 2022, 223: 117506 |
| 11 | Zhang C, Xiong Z P, Yang D Z, et al. Heterogeneous quenching and partitioning from manganese-partitioned pearlite: Retained austenite modification and formability improvement [J]. Acta Mater., 2022, 235: 118060 |
| 12 | Yang D Z, Xiong Z P, Zhang C, et al. Effect of tempering time on microstructures and mechanical properties of an Fe-0.39C-3.69Mn medium Mn steel [J]. J. Iron Steel Res., 2021, 33: 1161 |
| 杨德振, 熊志平, 张 超 等. 回火时间对Fe-0.39C-3.69Mn中锰钢的组织和力学性能的影响 [J]. 钢铁研究学报, 2021, 33: 1161 | |
| 13 | Cunningham J L, Medlin D J, Krauss G. Effects of induction hardening and prior cold work on a microalloyed medium carbon steel [J]. J. Mater. Eng. Perform., 1999, 8: 401 |
| 14 | Yang D Z, Xiong Z P, Zhang C, et al. Evolution of microstructures and mechanical properties with tempering temperature of a pearlitic quenched and tempered steel [J]. J. Iron Steel Res. Int., 2022, 29: 1393 |
| 15 | Santofimia M J, Zhao L, Petrov R, et al. Microstructural development during the quenching and partitioning process in a newly designed low-carbon steel [J]. Acta Mater., 2011, 59: 6059 |
| 16 | Wang C Y, Shi J, Cao W Q, et al. Study on the martensite in low carbon CrNi3Si2MoV steel treated by Q&P process [J]. Acta Metall. Sin., 2011, 47: 718 |
| 王存宇, 时 捷, 曹文全 等. Q&P工艺处理低碳CrNi3Si2MoV钢中马氏体的研究 [J]. 金属学报, 2011, 47: 718 | |
| 17 | Gao P F, Liang J H, Chen W J, et al. Prediction and evaluation of optimum quenching temperature and microstructure in a 1300 MPa ultra-high-strength Q&P steel [J]. J. Iron Steel Res. Int., 2022, 29: 307 |
| 18 | Xiong Z P, Jacques P J, Perlade A, et al. Characterization and control of the compromise between tensile properties and fracture toughness in a quenched and partitioned steel [J]. Metall. Mater. Trans., 2019, 50A: 3502 |
| 19 | Shi J, Sun X J, Wang M Q, et al. Enhanced work-hardening behavior and mechanical properties in ultrafine-grained steels with large-fractioned metastable austenite [J]. Scr. Mater., 2010, 63: 815 |
| 20 | Xu Y T, Li W, Du H, et al. Tailoring the metastable reversed austenite from metastable Mn-rich carbides [J]. Acta Mater., 2021, 214: 116986 |
| 21 | Yang Z N, Enomoto M, Zhang C, et al. Transition between alloy-element partitioned and non-partitioned growth of austenite from a ferrite and cementite mixture in a high-carbon low-alloy steel [J]. Philos. Mag. Lett., 2016, 96: 256 |
| 22 | Li S, Yang Z N, Enomoto M, et al. Study of partition to non-partition transition of austenite growth along pearlite lamellae in near-eutectoid Fe-C-Mn alloy [J]. Acta Mater., 2019, 177: 198 |
| 23 | Divinski S V, Hisker F, Kang Y S, et al. Tracer diffusion of 63Ni in nano-γ-FeNi produced by powder metallurgical method: Systematic investigations in the C, B, and A diffusion regimes [J]. Interface Sci., 2003, 11: 67 |
| 24 | Guo Q, Yen H W, Luo H, et al. On the mechanism of Mn partitioning during intercritical annealing in medium Mn steels [J]. Acta Mater., 2022, 225: 117601 |
| 25 | Li Z D, Yang Z G, Zhang C, et al. Influence of austenite deformation on ferrite growth in a Fe-C-Mn alloy [J]. Mater. Sci. Eng., 2010, A527: 4406 |
| 26 | Liu L, He B B, Cheng G J, et al. Optimum properties of quenching and partitioning steels achieved by balancing fraction and stability of retained austenite [J]. Scr. Mater., 2018, 150: 1 |
| 27 | Cech R E, Turnbull D. Heterogeneous nucleation of the martensite transformation [J]. JOM, 1956, 8: 124 |
| 28 | Jing S Y, Ding H, Ren Y P, et al. A new insight into annealing parameters in tailoring the mechanical properties of a medium Mn steel [J]. Scr. Mater., 2021, 202: 114019 |
| 29 | Gao G H, Gao B, Gui X L, et al. Correlation between microstructure and yield strength of as-quenched and Q&P steels with different carbon content (0.06-0.42?wt% C) [J]. Mater. Sci. Eng., 2019, A753: 1 |
| 30 | HajyAkbary F, Sietsma J, Miyamoto G, et al. Analysis of the mechanical behavior of a 0.3C-1.6Si-3.5Mn (wt%) quenching and partitioning steel [J]. Mater. Sci. Eng., 2016, A677: 505 |
| 31 | Bouquerel J, Verbeken K, De Cooman B C. Microstructure-based model for the static mechanical behaviour of multiphase steels [J]. Acta Mater., 2006, 54: 1443 |
| 32 | McGuire M F. Stainless Steels for Design Engineers [M]. Materials Park: ASM International, 2008: 74 |
| 33 | Irvine J, Baker T N. The influence of rolling variables on the strengthening mechanisms operating in niobium steels [J]. Mater. Sci. Eng., 1984, 64: 123 |
| 34 | Krauss G. Martensite in steel: Strength and structure [J]. Mater. Sci. Eng., 1999, A273-275: 40 |
| 35 | Rodriguez RM, Gutiérrez I. Unified formulation to predict the tensile curves of steels with different microstructures [J]. Mater. Sci. Forum, 2003, 426-432: 4525 |
| 36 | Xiong Z P, Timokhina I, Pereloma E. Clustering, nano-scale precipitation and strengthening of steels [J]. Prog. Mater. Sci., 2021, 118: 100764 |
| 37 | Smith D W, Hehemann R F. Influence of structural parameters on the yield strength of tempered martensite and lower bainite [J]. J. Iron Steel Inst., 1971, 209: 476 |
| 38 | Taylor G I. The mechanism of plastic deformation of crystals. Part I.—Theoretical [J]. Proc. R. Soc, 1934, 145A: 362 |
| 39 | Girault E, Jacques P, Harlet P, et al. Metallographic methods for revealing the multiphase microstructure of TRIP-assisted steels [J]. Mater. Charact., 1998, 40: 111 |
| 40 | Xiong Z P, Jacques P J, Perlade A, et al. Ductile and intergranular brittle fracture in a two-step quenching and partitioning steel [J]. Scr. Mater., 2018, 157: 6 |
| 41 | Wang Y, Zhang K, Guo Z H, et al. A new effect of retained austenite on ductility enhancement of low carbon Q-P-T steel [J]. Acta Metall. Sin., 2012, 48: 641 |
| 王 颖, 张 柯, 郭正洪 等. 残余奥氏体增强低碳Q-P-T钢塑性的新效应 [J]. 金属学报, 2012, 48: 641 | |
| 42 | Martelo D F, Mateo A, Chapetti M D. Crack closure and fatigue crack growth near threshold of a metastable austenitic stainless steel [J]. Int. J. Fatigue, 2015, 77: 64 |
| 43 | Mei Z, Morris J W. Influence of deformation-induced martensite on fatigue crack propagation in 304-type steels [J]. Metall. Trans., 1990, 21A: 3137 |
| 44 | Niendorf T, Rubitschek F, Maier H J, et al. Fatigue crack growth—Microstructure relationships in a high-manganese austenitic TWIP steel [J]. Mater. Sci. Eng., 2010, A527: 2412 |
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