研究论文

微米级选区激光熔化316L不锈钢的拉伸力学性能

  • 张楠 ,
  • 张海武 ,
  • 王淼辉
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  • 1 中机新材料研究院(郑州)有限公司 郑州 450001
    2 中国机械科学研究总院集团有限公司 北京 100044
张 楠,男,1983年生,高级工程师,博士
王淼辉,wangmh0103@163.com,主要从事金属增材制造技术研究

收稿日期: 2022-02-14

  修回日期: 2022-06-16

  网络出版日期: 2022-09-26

基金资助

国家自然科学基金项目(51975240);北京市自然科学基金项目(2222093);中国机械科学研究总院集团技术发展基金项目(812201Q9)

Tensile Mechanical Properties of Micro-Selective Laser Melted 316L Stainless Steel

  • ZHANG Nan ,
  • ZHANG Haiwu ,
  • WANG Miaohui
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  • 1 China Machinery Institute of Advanced Materials Co. Ltd., Zhengzhou 450001, China
    2 China Academy of Mechanical Science and Technology Group Co. Ltd., Beijing 100044, China
WANG Miaohui, professor, Tel: (010)60603546, E-mail: wangmh0103@163.com

Received date: 2022-02-14

  Revised date: 2022-06-16

  Online published: 2022-09-26

Supported by

National Natural Science Foundation of China(51975240);Beijing Natural Science Foundation(2222093);Technical Development Foundation of China Academy of Machinery Science and Technology Group Co. Ltd(812201Q9)

摘要

为辅助理解金属材料高精密增材制造成形机理,本工作利用微米级选区激光熔化(micro-selective laser melting,M-SLM)技术制备了316L不锈钢,对其拉伸性能及断裂行为进行了研究,并对断后横向和纵向拉伸试样显微组织和断口形貌进行了表征与分析,对近断面塑性变形区的晶粒取向、晶界特征分布等进行了电子背散射衍射(EBSD)分析。结果表明:M-SLM制备316L不锈钢晶粒内部存在尺寸为100~300 nm的胞状组织结构,拉伸断口呈韧窝状,窝口直径80~500 nm,这使得316L不锈钢的横向平均抗拉强度达692.1 MPa,纵向平均断后延伸率达54.6%,明显优于传统SLM技术制备的316L不锈钢。M-SLM制备316L不锈钢在拉伸过程中奥氏体Σ3孪晶界的出现与晶粒取向有关,其在取向接近<111>的晶粒中较易出现。进一步分析指出,Σ3晶界的出现阻断了特殊晶界网络的连通性。通过基于EBSD的矩形截面法对共格Σ3 (Σ3c)和非共格Σ3 (Σ3ic)晶界进行了统计分析,显示316L横向拉伸试样近断口区的Σ3cΣ3ic晶界数量百分比分别约为43%和57%,而纵向拉伸试样近断口区的Σ3c晶界数量百分比提高至约70%。Σ3c孪晶界的增加使得总晶界能降低,是导致M-SLM制备316L不锈钢纵向拉伸强度普遍低于横向拉伸强度的原因。

本文引用格式

张楠 , 张海武 , 王淼辉 . 微米级选区激光熔化316L不锈钢的拉伸力学性能[J]. 金属学报, 2024 , 60(2) : 211 -219 . DOI: 10.11900/0412.1961.2022.00041

Abstract

Compared with selective laser melting (SLM), the micro-SLM (M-SLM) technology offers the advantages of small spot diameter (< 20 μm), high forming precision (20-50 μm), and surface roughness (Ra) of up 1 μm, which implies that the M-SLM technology provides great potential for promotion and application in communication electronics, biomedical, and other fields in the future. In this work, 316L stainless steel was prepared using M-SLM, and its tensile properties and fracture behavior were studied. The microstructures of transverse and longitudinal tensile specimens were also investigated. In addition, the fracture morphology was characterized and analyzed, and the grain orientation and grain-boundary-characteristic distribution in the near-section plastic-deformation zone were further analyzed using electron backscatter diffraction (EBSD). The results showed that the 316L stainless steel prepared by M-SLM had a cellular structure with a size of 100-300 nm inside the grains. The tensile fracture was dimple-shaped, and the average dimple diameter was 80-500 nm, which allowed the transverse average tensile strength of the 316L stainless steel to reach 692.1 MPa, the longitudinal average elongation after fracture was 54.6%, which were obviously better than that of the 316L stainless steel prepared using traditional SLM. The appearance of austenite Σ3 twin boundaries in the stretching process of the 316L stainless steel prepared by M-SLM was related to the grain orientation, which could more likely appear in grains with an orientation close to <111>. Further analysis indicated that the appearance of Σ3 grain boundaries blocked the connectivity of the special grain-boundary network. Statistical analysis of the coherent Σ3 (Σ3c) and incoherent Σ3 (Σ3ic) grain boundaries using the EBSD-based rectangular-section method revealed that the amount percentages of Σ3c and Σ3ic in the near-fracture region of the 316L transverse tensile specimen were approximately 43% and 57%, respectively. Meanwhile, the amount percentage of Σ3c in the same region of the 316L longitudinal tensile specimen increased to approximately 70%. The increase in the coherent Σ3c twin boundary reduced the total grain-boundary energy, which explained why the longitudinal tensile strength of the 316L stainless steel prepared by M-SLM was generally lower than the transverse tensile strength.

参考文献

1 Lan H B, Li D C, Lu B H. Micro- and nanoscale 3D printing [J]. Sci. Sin. Technol., 2015, 45: 919
  兰红波, 李涤尘, 卢秉恒. 微纳尺度3D打印 [J]. 中国科学: 技术科学, 2015, 45: 919
2 Liu G, Zhang X F, Chen X L, et al. Additive manufacturing of structural materials [J]. Mater. Sci. Eng., 2021, R145: 100596
3 Gunasekaran J, Sevvel P, Solomon I J. Metallic materials fabrication by selective laser melting: A review [J]. Mater. Today Proc., 2020, 37: 252
4 Jin X Y, Lan L, He B, et al. A review on surface roughness of metals parts fabricated by selective laser melting [J]. Mater. Rep., 2021, 35: 3168
  金鑫源, 兰 亮, 何 博 等. 选区激光熔化成形金属零件表面粗糙度研究进展 [J]. 材料导报, 2021, 35: 3168
5 Zhang X Z, Chen L, Zhou J, et al. Simulation and experimental studies on process parameters, microstructure and mechanical properties of selective laser melting of stainless steel 316L [J]. J. Braz. Soc. Mech. Sci. Eng., 2020, 42: 402
6 Greco S, Gutzeit K, Hotz H, et al. Selective laser melting (SLM) of AISI 316L——Impact of laser power, layer thickness, and hatch spacing on roughness, density, and microhardness at constant input energy density [J]. Int. J. Adv. Manuf. Technol., 2020, 108: 1551
7 Stoll P, Spierings A, Wegener K. Impact of a process interruption on tensile properties of SS 316L parts and hybrid parts produced with selective laser melting [J]. Int. J. Adv. Manuf. Technol., 2019, 103: 367
8 Tascioglu E, Karabulut Y, Kaynak Y. Influence of heat treatment temperature on the microstructural, mechanical, and wear behavior of 316L stainless steel fabricated by laser powder bed additive manufacturing [J]. Int. J. Adv. Manuf. Technol., 2020, 107: 1947
9 Yang X Q, Liu Y, Ye J W, et al. Enhanced mechanical properties and formability of 316L stainless steel materials 3D-printed using selective laser melting [J]. Int. J. Miner. Metall. Mater., 2019, 26: 1396
10 Yang D C, Kan X F, Gao P F, et al. Influence of porosity on mechanical and corrosion properties of SLM 316L stainless steel [J]. Appl. Phys., 2022, 128A: 51
11 Yang X, Ma W J, Ren Y J, et al. Subgrain microstructures and tensile properties of 316L stainless steel manufactured by selective laser melting [J]. J. Iron Steel Res. Int., 2021, 28: 1159
12 Shin W S, Son B, Song W S, et al. Heat treatment effect on the microstructure, mechanical properties, and wear behaviors of stainless steel 316L prepared via selective laser melting [J]. Mater. Sci. Eng., 2021, A806: 140805
13 Wang Y M, Voisin T, McKeown J T, et al. Additively manufactured hierarchical stainless steels with high strength and ductility [J]. Nat. Mater., 2018, 17: 63
14 Shamsujjoha M, Agnew S R, Fitz-Gerald J M, et al. High strength and ductility of additively manufactured 316L stainless steel explained [J]. Metall. Mater. Trans., 2018, 49A: 3011
15 Kong D C, Dong C F, Wei S L, et al. About metastable cellular structure in additively manufactured austenitic stainless steels [J]. Addit. Manuf., 2021, 38: 101804
16 Nagarajan B, Hu Z H, Song X, et al. Development of micro selective laser melting: The state of the art and future perspectives [J]. Engineering, 2019, 5: 702
17 Bertoli U S, Wolfer A J, Matthews M J, et al. On the limitations of volumetric energy density as a design parameter for selective laser melting [J]. Mater. Des., 2017, 113: 331
18 Brandon D G. The structure of high-angle grain boundaries [J]. Acta Metall., 1966, 14: 1479
19 Elmer J W, Allen S M, Eagar T W. Microstructural development during solidification of stainless steel alloys [J]. Metall. Trans., 1989, 20A: 2117
20 Zong X W, Gao Q, Zhou H Z, et al. Effects of bulk laser energy density on anisotropy of selective laser sintered 316L stainless steel [J]. Chin. J. Lasers, 2019, 46: 0502003
  宗学文, 高 倩, 周宏志 等. 体激光能量密度对选区激光熔化316L不锈钢各向异性的影响 [J]. 中国激光, 2019, 46: 0502003
21 Lu L, Li Z B, Bi Z Y, et al. Relationship between tension toughness and fracture toughness of low carbon low alloy steel [J]. J. Iron Steel Res., 2014, 26(6): 67
  芦 琳, 李周波, 毕宗岳 等. 低碳低合金钢的静力韧度与断裂韧度 [J]. 钢铁研究学报, 2014, 26(6): 67
22 Gu D D, Chen H Y. Selective laser melting of high strength and toughness stainless steel parts: The roles of laser hatch style and part placement strategy [J]. Mater. Sci. Eng., 2018, A725: 419
23 Gu D D, Shi X Y, Poprawe R, et al. Material-structure-performance integrated laser-metal additive manufacturing [J]. Science, 2021, 372: eabg1487
24 Qi B, Liu Y D, Shi W T, et al. Study on overlap ratio of pulse laser selective melting forming [J]. Laser Technol., 2018, 42: 311
  祁 斌, 刘玉德, 石文天 等. 脉冲式激光选区熔化成形搭接率的研究 [J]. 激光技术, 2018, 42: 311
25 Ma Y Y, Liu Y D, Shi W T, et al. Effect of scanning speed on forming defects and properties of selective laser melted 316L stainless steel powder [J]. Laser Optoelectr. Progr., 2019, 56: 101403
  马英怡, 刘玉德, 石文天 等. 扫描速度对选区激光熔化316L不锈钢粉末成形缺陷及性能的影响 [J]. 激光与光电子学进展, 2019, 56: 101403
26 Shi W T, Wang P, Liu Y D, et al. Experimental study on surface quality and process of selective laser melting forming 316L [J]. Surface Technol., 2019, 48: 257
  石文天, 王 朋, 刘玉德 等. 选区激光熔化成形316L表面质量及工艺试验研究 [J]. 表面技术, 2019, 48: 257
27 Afkhami S, Dabiri M, Piili H, et al. Effects of manufacturing parameters and mechanical post-processing on stainless steel 316L processed by laser powder bed fusion [J]. Mater. Sci. Eng., 2021, A802: 140660
28 Kumar P, Jayaraj R, Suryawanshi J, et al. Fatigue strength of additively manufactured 316L austenitic stainless steel [J]. Acta Mater., 2020, 199: 225
29 Wu D J, Yu C S, Wang Q Y, et al. Synchronous-hammer-forging-assisted laser directed energy deposition additive manufacturing of high-performance 316L samples [J]. J. Mater. Process. Technol., 2022, 307: 117695
30 Matthews M J, Guss G, Khairallah S A, et al. Denudation of metal powder layers in laser powder bed fusion processes [J]. Acta Mater., 2016, 114: 33
31 Yu C F, Zhao C C, Zhang Z F, et al. Tensile properties of selective laser melted 316L stainless steel [J]. Acta Metall. Sin., 2020, 56: 683
  余晨帆, 赵聪聪, 张哲峰 等. 选区激光熔化316L不锈钢的拉伸性能 [J]. 金属学报, 2020, 56: 683
32 Gutierrez-Urrutia I, Zaefferer S, Raabe D. The effect of grain size and grain orientation on deformation twinning in a Fe-22wt.%Mn-0.6wt.%C TWIP steel [J]. Mater. Sci. Eng., 2010, A527: 3552
33 Sun S J, Tian Y Z, Lin H R, et al. Transition of twinning behavior in CoCrFeMnNi high entropy alloy with grain refinement [J]. Mater. Sci. Eng., 2018, A712: 603
34 de Campos M F, Loureiro S A, Rodrigues D, et al. Estimative of the stacking fault energy for a FeNi(50/50) alloy and a 316L stainless steel [J]. Mater. Sci. Forum, 2008, 591-593: 3
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