纵向静磁场下单晶高温合金定向凝固籽晶回熔界面杂晶的形成与演化
收稿日期: 2022-04-24
修回日期: 2022-07-05
网络出版日期: 2022-08-04
基金资助
国家自然科学基金项目(51871142);省部共建高品质特殊钢冶金与制备国家重点实验室、上海市钢铁冶金新技术开发应用重点实验室自主研发项目(SKLASS 2021-Z08);上海市科学技术委员会项目(19DZ2270200)
Formation and Evolution of Stray Grains on Remelted Interface in the Seed Crystal During the Directional Solidification of Single-Crystal Superalloys Assisted by Vertical Static Magnetic Field
Received date: 2022-04-24
Revised date: 2022-07-05
Online published: 2022-08-04
Supported by
National Natural Science Foundation of China(51871142);Independent Research and Development Project of State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advanced Ferrometallurgy, Shanghai University(SKLASS 2021-Z08);Science and Technology Commission of Shanghai Municipality(19DZ2270200)
通过对单晶高温合金定向凝固生长过程中显微组织的考察,研究了磁场下杂晶在籽晶回熔区附近的产生及其在生长过程中的演变机制。磁场使得定向凝固籽晶重熔区界面上出现大取向杂晶和大角度晶界,其多分布于样品边缘,磁场强度和抽拉速率的增大均增加了杂晶数量和大角度晶界长度。凝固起始阶段形成的大取向杂晶和大角度晶界以较快速率被淘汰,演化成小取向枝晶和小角度晶界;随着凝固继续进行,枝晶取向和晶界角度进一步减小,但是演化速率急剧降低,拉速的增大强化了此演变过程。重熔区界面上杂晶的形成是由于热电磁力对枝晶的扭断,而宏观尺度上的热电磁环流在凝固过程挟制着扭断碎晶,使得碎晶演化成较多分布于样品边缘的杂晶。
苏震奇 , 张丛江 , 袁笑坦 , 胡兴金 , 芦可可 , 任维丽 , 丁彪 , 郑天祥 , 沈喆 , 钟云波 , 王晖 , 王秋良 . 纵向静磁场下单晶高温合金定向凝固籽晶回熔界面杂晶的形成与演化[J]. 金属学报, 2023 , 59(12) : 1568 -1580 . DOI: 10.11900/0412.1961.2022.00193
Nickel-based superalloys, especially single-crystal (SC) ones, have long been recognized as important materials for turbine blades used in aerospace and gas engines. Static magnetic fields are effective at controlling the material forming. The use of static magnetic fields during solidification has evolved as a sophisticated approach for efficiently controlling the microstructures and mechanical performance of metallic materials. In recent years, studies have shown that static magnetic fields have a complex effect on dendrites in SC superalloys. However, the mechanism of static magnetic fields regulating stray grains on remelted interface needs to be investigated further. This work studied the generation of stray grains near the seed remelted zone and the evolution mechanism during the directional solidification of the SC superalloy assisted by a magnetic field by tracing the solidification microstructure. The stray grains of large orientation that deviated from the <001> direction appeared on the remelted zone interface of the solidification microstructure when the magnetic field was applied, accompanied by the formation of a large-angle grain boundary (LAGB). Most of the stray grains were distributed at the sample edge. The increase in magnetic field intensity and pulling speed increased the number of stray grains and the length of the LAGB. As the solidification progressed, the large-orientation stray grains and the LAGBs were eliminated at a fast speed and evolved into small-orientation dendrites. During the following solidification, the orientation of the dendrites became even smaller and the evolution speed decreased sharply. The increase in withdrawal speed intensified the evolution process. The stray grains formed in the remelted zone can be attributed to the twisting dendrite by the thermoelectric magnetic force. The distribution of more stray grains around the sample was caused by the circulation from thermoelectric magnetic convection at the macroscopic scale.
| 1 | Guo J T. The current situation of application and development of superalloys in the fields of energy industry[J]. Acta Metall. Sin., 2010, 46: 513 |
| 郭建亭. 高温合金在能源工业领域中的应用现状与发展[J]. 金属学报, 2010, 46: 513 | |
| 2 | Ma D X. Development of single crystal solidification technology for production of superalloy turbine blades[J]. Acta Metall. Sin., 2015, 51: 1179 |
| 马德新. 高温合金叶片单晶凝固技术的新发展[J]. 金属学报, 2015, 51: 1179 | |
| 3 | Sun X F, Jin T, Zhou Y Z, et al. Research progress of nickel-base single crystal superalloys[J]. Mater. China, 2012, 31(12): 1 |
| 孙晓峰, 金 涛, 周亦胄 等. 镍基单晶高温合金研究进展[J]. 中国材料进展, 2012, 31(12): 1 | |
| 4 | Zhang J, Huang T W, Liu L, et al. Advances in solidification characteristics and typical casting defects in nickel-based single crystal superalloys[J]. Acta Metall. Sin., 2015, 51: 1163 |
| 张 军, 黄太文, 刘 林 等. 单晶高温合金凝固特性与典型凝固缺陷研究[J]. 金属学报, 2015, 51: 1163 | |
| 5 | Ren N, Panwisawas C, Li J, et al. Solute enrichment induced dendritic fragmentation in directional solidification of nickel-based superalloys[J]. Acta Mater., 2021, 215: 117043 |
| 6 | Zhang J, Wang L, Wang D, et al. Recent progress in research and development of nickel-based single crystal superalloys[J]. Acta Metall. Sin., 2019, 55: 1077 |
| 张 健, 王 莉, 王 栋 等. 镍基单晶高温合金的研发进展[J]. 金属学报, 2019, 55: 1077 | |
| 7 | D'Souza N, Newell M, Devendra K, et al. Formation of low angle boundaries in Ni-based superalloys[J]. Mater. Sci. Eng., 2005, A413-414: 567 |
| 8 | Zhou Y Z. Formation of stray grains during directional solidification of a nickel-based superalloy[J]. Scr. Mater., 2011, 65: 281 |
| 9 | Yang X L, Dong H B, Wang W, et al. Microscale simulation of stray grain formation in investment cast turbine blades[J]. Mater. Sci. Eng., 2004, A386: 129 |
| 10 | Meng X B, Lu Q, Li J G, et al. Modes of grain selection in spiral selector during directional solidification of nickel-base superalloys[J]. J. Mater. Sci. Technol., 2012, 28: 214 |
| 11 | Li Y F, Liu L, Huang T W, et al. The process analysis of seeding-grain selection and its effect on stray grain and orientation control[J]. J. Alloys Compd., 2016, 657: 341 |
| 12 | Hu S S, Yang W C, Li Z R, et al. Formation mechanisms and control method for stray grains at melt-back region of Ni-based single crystal seed[J]. Prog. Nat. Sci., 2021, 31: 624 |
| 13 | Hallensleben P, Schaar H, Thome P, et al. On the evolution of cast microstructures during processing of single crystal Ni-base superalloys using a Bridgman seed technique[J]. Mater. Des., 2017, 128: 98 |
| 14 | Zhang T, Ren W L, Dong J W, et al. Effect of high magnetic field on the primary dendrite arm spacing and segregation of directionally solidified superalloy DZ417G[J]. J. Alloys Compd., 2009, 487: 612 |
| 15 | Dong J W, Ren Z M, Ren W L, et al. Effect of horizontal magnetic field on the microstructure of directionally solidified Ni-based superalloy[J]. Acta Metall. Sin., 2010, 46: 71 |
| 董建文, 任忠鸣, 任维丽 等. 横向磁场对镍基高温合金定向凝固组织的影响[J]. 金属学报, 2010, 46: 71 | |
| 16 | Ren W L, Lu L, Yuan G Z, et al. The effect of magnetic field on precipitation phases of single-crystal nickel-base superalloy during directional solidification[J]. Mater. Lett., 2013, 100: 223 |
| 17 | Xuan W D, Song G, Duan F M, et al. Enhanced creep properties of nickel-base single crystal superalloy CMSX-4 by high magnetic field[J]. Mater. Sci. Eng., 2021, A803: 140729 |
| 18 | Li Q D, Shen J, Qin L, et al. Effect of traveling magnetic field on freckle formation in directionally solidified CMSX-4 superalloy[J]. Mater. Process. Technol., 2019, 274: 116308 |
| 19 | Xuan W D, Ren Z M, Li C J. Effect of a high magnetic field on microstructures of Ni-based superalloy during directional solidification[J]. J. Alloys Compd., 2015, 620: 10 |
| 20 | Zhang K L, Li Y J, Yang Y S. Influence of the low voltage pulsed magnetic field on the columnar-to-equiaxed transition during directional solidification of superalloy K4169[J]. J. Mater. Sci. Technol., 2020, 48: 9 |
| 21 | Ren W L, Niu C L, Ding B, et al. Improvement in creep life of a nickel-based single-crystal superalloy via composition homogeneity on the multiscales by magnetic-field-assisted directional solidification[J]. Sci. Rep., 2018, 8: 1452 |
| 22 | Xuan W D, Liu H, Lan J, et al. Effect of a transverse magnetic field on stray grain formation of Ni-based single crystal superalloy during directional solidification[J]. Metall. Mater. Trans., 2016, 47B: 3231 |
| 23 | Xuan W D, Liu H, Li C J, et al. Effect of a high magnetic field on microstructures of Ni-based single crystal superalloy during seed melt-back[J]. Metall. Mater. Trans., 2016, 47B: 828 |
| 24 | Xuan W D, Lan J, Liu H, et al. Effects of a high magnetic field on the microstructure of Ni-based single-crystal superalloys during directional solidification[J]. Metall. Mater. Trans., 2017, 48A: 3804 |
| 25 | Yuan X T, Zhou T, Ren W L, et al. Nondestructive effect of the cusp magnetic field on the dendritic microstructure during the directional solidification of nickel-based single crystal superalloy[J]. J. Mater. Sci. Technol., 2021, 62: 52 |
| 26 | Liu C L, Su H J, Zhang J, et al. Effect of electromagnetic field on microstructure of Ni-based single crystal superalloys[J]. Acta Metall. Sin., 2018, 54: 1428 |
| 刘承林, 苏海军, 张 军 等. 电磁场对镍基单晶高温合金组织的影响[J]. 金属学报, 2018, 54: 1428 | |
| 27 | Li Y J, Teng Y F, Feng X H, et al. Effects of pulsed magnetic field on microsegregation of solute elements in a Ni-based single crystal superalloy[J]. J. Mater. Sci. Technol., 2017, 33: 105 |
| 28 | Niu C L, Ren W L, Ding B, et al. The change of mushy-zone length of a nickel-based single-crystal superalloy during the static-magnetic-field-assisted directional solidification[J]. Cryst. Res. Technol., 2018, 53: 1700187 |
| 29 | Liu Q. EBSD technique and its applications in materials science[J]. Chin. J. Stereol. Image Anal., 2005, 10: 205 |
| 刘 庆. 电子背散射衍射技术及其在材料科学中的应用[J]. 中国体视学与图像分析, 2005, 10: 205 | |
| 30 | Xu W L, Wang F, Ma D X, et al. Sliver defect formation in single crystal Ni-based superalloy castings[J]. Mater. Des., 2020, 196: 109138 |
| 31 | Ren Z M, Lei Z S, Li C J, et al. New study and development on electromagnetic field technology in metallurgical processes[J]. Acta Metall. Sin., 2020, 56: 583 |
| 任忠鸣, 雷作胜, 李传军 等. 电磁冶金技术研究新进展[J]. 金属学报, 2020, 56: 583 | |
| 32 | Wang J, Fautrelle Y, Ren Z M, et al. Thermoelectric magnetic force acting on the solid during directional solidification under a static magnetic field[J]. Appl. Phys. Lett., 2012, 101: 251904 |
| 33 | Dahle A K, Arnberg L. Development of strength in solidifying aluminium alloys[J]. Acta Mater., 1997, 45: 547 |
| 34 | Khine Y Y, Walker J S. Thermoelectric magnetohydrodynamic effects during Bridgman semiconductor crystal growth with a uniform axial magnetic field[J]. J. Cryst. Growth, 1998, 183: 150 |
| 35 | Ma D X. Freckle formation during directional solidification of complex castings of superalloys[J]. Acta Metall. Sin., 2016, 52: 426 |
| 马德新. 定向凝固的复杂形状高温合金铸件中的雀斑形成[J]. 金属学报, 2016, 52: 426 | |
| 36 | Walton D, Chalmers B. The origin of the preferred orientation in the columnar zone of ingots[J]. Trans. Am. Inst. Min. Metall. Eng., 1959, 215: 447 |
| 37 | Zhou Y Z, Volek A, Green N R. Mechanism of competitive grain growth in directional solidification of a nickel-base superalloy[J]. Acta Mater., 2008, 56: 2631 |
| 38 | Hu S S, Liu L, Cui Q W, et al. Converging competitive growth in bi-crystal of Ni-based superalloy during directional solidification[J]. Acta. Metall. Sin., 2016, 52: 897 |
| 胡松松, 刘 林, 崔强伟 等. 镍基高温合金定向凝固过程中的汇聚型双晶竞争生长[J]. 金属学报, 2016, 52: 897 | |
| 39 | Guo C W, Takaki T, Sakane S, et al. Overgrowth behavior at converging grain boundaries during competitive grain growth: A two-dimensional phase-field study[J]. Int. J. Heat Mass Transfer, 2020, 160: 120196 |
| 40 | Zhou Y Z, Jin T, Sun X F. Structure evolution in directionally solidified bicrystals of nickel base superalloys[J]. Acta Metall. Sin., 2010, 46: 1327 |
| 周亦胄, 金 涛, 孙晓峰. 双晶镍基高温合金定向凝固过程的结构演化[J]. 金属学报, 2010, 46: 1327 |
/
| 〈 |
|
〉 |