研究论文

W含量对Ti-42Al-5Mn-xW合金相转变行为的影响

  • 李小兵 ,
  • 潜坤 ,
  • 舒磊 ,
  • 张孟殊 ,
  • 张金虎 ,
  • 陈波 ,
  • 刘奎
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  • 1.季华实验室 材料科学与技术研究部 佛山 528200
    2.中国科学院金属研究所 师昌绪先进材料创新中心 沈阳 110016
李小兵,男,1988年生,研究员,博士
陈 波,chenbo@jihualab.ac.cn,主要从事轻质高强TiAl合金材料研究

收稿日期: 2022-03-15

  修回日期: 2022-07-05

  网络出版日期: 2022-07-25

基金资助

国家自然科学基金项目(51971215);季华实验室科研项目(X210291TL210)

Effect of W Content on the Phase Transformation Behavior in Ti-42Al-5Mn- xW Alloy

  • LI Xiaobing ,
  • QIAN Kun ,
  • SHU Lei ,
  • ZHANG Mengshu ,
  • ZHANG Jinhu ,
  • CHEN Bo ,
  • LIU Kui
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  • 1.Department of Materials Science and Technology Research, Ji Hua Laboratory, Foshan 528200, China
    2.Shi-changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
CHEN Bo, professor, Tel: 13066683332, E-mail: chenbo@jihualab.ac.cn

Received date: 2022-03-15

  Revised date: 2022-07-05

  Online published: 2022-07-25

Supported by

National Natural Science Foundation of China(51971215);Scientific Research Project of Ji Hua Laboratory(X210291TL210)

摘要

以低成本、易变形的Ti-42Al-5Mn合金(原子分数,%)为研究对象,利用DSC、EPMA、EBSD及Pandat热力学计算软件系统研究了W含量(0.5%~1.0%)对合金相变行为和组织的影响。结果表明,随着W含量由0.5%提高至1.0%,合金β单相区开始温度(Tβ )和γ相溶解温度(Tγ-solv)几乎未发生变化,而共析转变温度(Teut)稍有增加。W添加会在一定程度上影响合金固态相变路线,随着W含量增加至0.5%,合金近服役温度下的平衡相由α2 + γ + Laves逐渐演变为βo + α2 + γ + Laves。W添加会对合金片层组织特征产生显著影响。在(γ + α + β)三相区处理时,随着W含量的提高,合金缓冷后组织中片层含量显著降低,当W含量为0.8%和1.0%时,合金组织以γ晶粒和βo相为主,几乎消除了α2/γ层片组织。在(α + β)两相区处理时,合金缓冷后均为近片层组织,且随着W含量由0.5%提高至1.0%,片层组织晶团得到明显细化。

本文引用格式

李小兵 , 潜坤 , 舒磊 , 张孟殊 , 张金虎 , 陈波 , 刘奎 . W含量对Ti-42Al-5Mn-xW合金相转变行为的影响[J]. 金属学报, 2023 , 59(10) : 1401 -1410 . DOI: 10.11900/0412.1961.2022.00119

Abstract

Advanced intermetallic β-solidifying γ-TiAl-based alloys have various potential applications in the aerospace and automobile industries due to their low density, functionality at higher temperatures, and high specific strength/modulus. The crucial aspect that needs to be considered when developing a new β-solidifying γ-TiAl alloy is to clarify the influence law of β-stabilizer elements on the phase transformation behavior of γ-TiAl alloys. In this work, the impact of W contents (0.5%-1.0%, atomic fraction) on the phase transformation behavior and microstructure characteristics of Ti-42Al-5Mn-xW (atomic fraction) alloy with low cost and superior temperature workability was systematically investigated. The findings demonstrate that there were minor changes in the β-phase single region temperature (Tβ ) and γ phase solvus temperature (Tγ-solv); furthermore, the eutectoid reaction temperature (Teut) increases with the W content from 0.5% to 1.0%. Addition of W influences the solid phase transformation pathway to a certain extent. When the concentration of W increases to 0.5%, the equilibrium phase of the alloy at near service temperature gradually changes from α2 + γ + Laves to βo + α2 + γ + Laves. Additionally, W addition will also have a substantial effect on the lamellar microstructure. The volume fraction of lamellar microstructure considerably decreased after alloying with (0.5%-1.0%)W for Ti-42Al-5Mn alloy when being treated in the (γ + α + β) triple-phase region followed by furnace cooling. Increasing the W content to 0.8% and 1.0% results in the development of γ and βo grain phases with almost complete removal of α2/γ lamellar structures. However, the W-free and W-bearing Ti-42Al-5Mn alloys show near complete lamellar structures when treated in (α + β) two-phase region followed by furnace cooling. Furthermore, when the content of W increased from 0.5% to 1.0%, an equiaxed grain structure with refined lamellar colonies is typically obtained.

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