W含量对Ti-42Al-5Mn-xW合金相转变行为的影响
收稿日期: 2022-03-15
修回日期: 2022-07-05
网络出版日期: 2022-07-25
基金资助
国家自然科学基金项目(51971215);季华实验室科研项目(X210291TL210)
Effect of W Content on the Phase Transformation Behavior in Ti-42Al-5Mn- xW Alloy
Received date: 2022-03-15
Revised date: 2022-07-05
Online published: 2022-07-25
Supported by
National Natural Science Foundation of China(51971215);Scientific Research Project of Ji Hua Laboratory(X210291TL210)
以低成本、易变形的Ti-42Al-5Mn合金(原子分数,%)为研究对象,利用DSC、EPMA、EBSD及Pandat热力学计算软件系统研究了W含量(0.5%~1.0%)对合金相变行为和组织的影响。结果表明,随着W含量由0.5%提高至1.0%,合金β单相区开始温度(Tβ )和γ相溶解温度(Tγ-solv)几乎未发生变化,而共析转变温度(Teut)稍有增加。W添加会在一定程度上影响合金固态相变路线,随着W含量增加至0.5%,合金近服役温度下的平衡相由α2 + γ + Laves逐渐演变为βo + α2 + γ + Laves。W添加会对合金片层组织特征产生显著影响。在(γ + α + β)三相区处理时,随着W含量的提高,合金缓冷后组织中片层含量显著降低,当W含量为0.8%和1.0%时,合金组织以γ晶粒和βo相为主,几乎消除了α2/γ层片组织。在(α + β)两相区处理时,合金缓冷后均为近片层组织,且随着W含量由0.5%提高至1.0%,片层组织晶团得到明显细化。
李小兵 , 潜坤 , 舒磊 , 张孟殊 , 张金虎 , 陈波 , 刘奎 . W含量对Ti-42Al-5Mn-xW合金相转变行为的影响[J]. 金属学报, 2023 , 59(10) : 1401 -1410 . DOI: 10.11900/0412.1961.2022.00119
Advanced intermetallic β-solidifying γ-TiAl-based alloys have various potential applications in the aerospace and automobile industries due to their low density, functionality at higher temperatures, and high specific strength/modulus. The crucial aspect that needs to be considered when developing a new β-solidifying γ-TiAl alloy is to clarify the influence law of β-stabilizer elements on the phase transformation behavior of γ-TiAl alloys. In this work, the impact of W contents (0.5%-1.0%, atomic fraction) on the phase transformation behavior and microstructure characteristics of Ti-42Al-5Mn-xW (atomic fraction) alloy with low cost and superior temperature workability was systematically investigated. The findings demonstrate that there were minor changes in the β-phase single region temperature (Tβ ) and γ phase solvus temperature (Tγ-solv); furthermore, the eutectoid reaction temperature (Teut) increases with the W content from 0.5% to 1.0%. Addition of W influences the solid phase transformation pathway to a certain extent. When the concentration of W increases to 0.5%, the equilibrium phase of the alloy at near service temperature gradually changes from α2 + γ + Laves to βo + α2 + γ + Laves. Additionally, W addition will also have a substantial effect on the lamellar microstructure. The volume fraction of lamellar microstructure considerably decreased after alloying with (0.5%-1.0%)W for Ti-42Al-5Mn alloy when being treated in the (γ + α + β) triple-phase region followed by furnace cooling. Increasing the W content to 0.8% and 1.0% results in the development of γ and βo grain phases with almost complete removal of α2/γ lamellar structures. However, the W-free and W-bearing Ti-42Al-5Mn alloys show near complete lamellar structures when treated in (α + β) two-phase region followed by furnace cooling. Furthermore, when the content of W increased from 0.5% to 1.0%, an equiaxed grain structure with refined lamellar colonies is typically obtained.
Key words: TiAl alloy; W content; phase transformation; lamellar structure; grain refinement
| 1 | Qu C F. Research and development of intermetallic titanium aluminides [J]. Rare Met. Mater. Eng., 1991, 20: 19 |
| 屈翠芬. 钛铝系金属间化合物的研究与发展 [J]. 稀有金属材料与工程, 1991, 20: 19 | |
| 2 | Qin G W, Hao S M. Ti-Al system intermetallic compounds [J]. Rare Met. Mater. Eng., 1995, 24(2): 1 |
| 秦高梧, 郝士明. Ti-Al系金属间化合物 [J]. 稀有金属材料与工程, 1995, 24(2): 1 | |
| 3 | Pollock T M. Alloy design for aircraft engines [J]. Nat. Mater., 2016, 15: 809 |
| 4 | Chen G, Peng Y B, Zheng G, et al. Polysynthetic twinned TiAl single crystals for high-temperature applications [J]. Nat. Mater., 2016, 15: 876 |
| 5 | Lasalmonie A. Intermetallics: Why is it so difficult to introduce them in gas turbine engines? [J]. Intermetallics, 2006, 14: 1123 |
| 6 | Clemens H, Chladil H F, Wallgram W, et al. In and ex situ investigations of the β-phase in a Nb and Mo containing γ-TiAl based alloy [J]. Intermetallics, 2008, 16: 827 |
| 7 | Yang R. Advances and challenges of TiAl base alloys [J]. Acta Metall. Sin., 2015, 51: 129 |
| 杨 锐. 钛铝金属间化合物的进展与挑战 [J]. 金属学报, 2015, 51: 129 | |
| 8 | Kim Y W, Kim S L. Advances in gammalloy materials-processes-application technology: Successes, dilemmas, and future [J] JOM, 2018, 70: 553 |
| 9 | Tetsui T, Shindo K, Kobayashi S, et al. A newly developed hot worked TiAl alloy for blades and structural components [J]. Scr. Mater., 2002, 47: 399 |
| 10 | Zhao P X, Li X B, Tang H J, et al. Improved high-temperature oxidation properties for Mn-containing beta-gamma TiAl with W addition [J]. Oxid. Met., 2020, 93: 433 |
| 11 | Tang H J, Li X B, Ma Y C, et al. Multistep evolution of βo phase during isothermal annealing of Ti-42Al-5Mn alloy: Formation of Laves phase [J]. Intermetallics, 2020, 126: 106932 |
| 12 | Li X B, Tang H J, Xing W W, et al. Microstructural stability, phase evolution and mechanical properties of a forged W-modified high-Mn β-γ-TiAl alloy [J]. Intermetallics, 2021, 136: 107230 |
| 13 | Li X B, Zhao P X, Chen B, et al. Effect of W addition on the solidification microstructure and element distribution behavior in Ti-42Al-5Mn alloy [J]. Rare Met. Mater. Eng., 2022, 51: 3850 |
| 李小兵, 赵鹏翔, 陈 波 等. W添加对Ti-42Al-5Mn合金凝固组织和元素分布行为的影响 [J]. 稀有金属材料与工程, 2022, 51: 3850 | |
| 14 | Xu H, Li X B, Xing W W, et al. Solidification pathway and phase transformation behavior in a beta-solidified gamma-TiAl based alloy [J]. J. Mater. Sci. Technol., 2019, 35: 2652 |
| 15 | Yang H W, Lin C. Phase transformation and microstructural evolution in Ti-44Al-4Nb-4Zr alloy during heat treatment [J]. Metall. Mater. Trans., 2006, 37A: 3191 |
| 16 | Schwaighofer E, Clemens H, Mayer S, et al. Microstructural design and mechanical properties of a cast and heat-treated intermetallic multi-phase γ-TiAl based alloy [J]. Intermetallics, 2014, 44: 128 |
| 17 | Mayer S, Petersmann M, Fischer F D, et al. Experimental and theoretical evidence of displacive martensite in an intermetallic Mo-containing γ-TiAl based alloy [J]. Acta Mater., 2016, 115: 242 |
| 18 | Clemens H, Wallgram W, Kremmer S, et al. Design of novel β-solidifying TiAl alloys with adjustable β/B2-phase fraction and excellent hot-workability [J]. Adv. Eng. Mater., 2008, 10: 707 |
| 19 | Chen R R, Fang H Z, Chen X Y, et al. Formation of TiC/Ti2AlC and α2 + γ in in-situ TiAl composites with different solidification paths [J]. Intermetallics, 2017, 81: 9 |
| 20 | Sun F S, Cao C X, Yan M G, et al. Alloying mechanism of beta stabilizers in a TiAl alloy [J]. Metall. Mater. Trans., 2001, 32A: 1573 |
| 21 | Zhang Y G, Han Y F, Chen G L, et al. Structural Intermetallics [M]. Beijing: National Defense Industry Press, 2001: 777 |
| 张永刚, 韩雅芳, 陈国良 等. 金属间化合物结构材料 [M]. 北京: 国防工业出版社, 2001: 777 | |
| 22 | Schmoelzer T, Mayer S, Sailer C, et al. In situ diffraction experiments for the investigation of phase fractions and ordering temperatures in Ti-44at%Al-(3-7)at%Mo alloys [J]. Adv. Eng. Mater., 2011, 13: 306 |
| 23 | Xu M, Zhang S Z, Zhao Y, et al. Effects of alloying element on the heat-treated microstructure based on β/γ TiAl [J]. Rare Met. Mater. Eng., 2019, 48(1): 183 |
| 徐 萌, 张树志, 赵 宇 等. 合金元素对β-γ TiAl合金热处理组织的影响 [J]. 稀有金属材料与工程, 2019, 48(1): 183 | |
| 24 | Yu T H, Koo C H. Microstructural evolution of a hot-rolled Ti-40Al-10Nb alloy [J]. Mater. Sci. Eng., 1997, A239-240: 694 |
| 25 | Stark A, Oehring M, Pyczak F, et al. In situ observation of various phase transformation paths in Nb-rich TiAl alloys during quenching with different rates [J]. Adv. Eng. Mater., 2011, 13: 700 |
| 26 | Schloffer M, Rashkova B, Sch?berl T, et al. Evolution of the ωo phase in a β-stabilized multi-phase TiAl alloy and its effect on hardness [J]. Acta Mater., 2014, 64: 241 |
| 27 | Tang H J, Xing W W, Li X B, et al. Insights into the gradient-characteristic precipitation behaviors of Laves phase induced by Fe/W/Mo addition in Ti42Al5Mn alloy [J]. Intermetallics, 2021, 128: 107022 |
| 28 | Takeyama M, Kobayashi S. Physical metallurgy for wrought gamma titanium aluminides: Microstructure control through phase transformations [J]. Intermetallics, 2005, 13: 993 |
| 29 | Singh V, Mondal C, Sarkar R, et al. Effects of Cr alloying on the evolution of solidification microstructure and phase transformations of high-Nb containing γ-TiAl based alloys [J]. Intermetallics, 2021, 131: 107117 |
| 30 | Chen G, Chen F R, Qi Z X, et al. PST TiAl single crystal and its application prospect [J]. J. Vib. Meas. Diag., 2019, 39: 915 |
| 陈 光, 陈奉锐, 祁志祥 等. 聚片孪生TiAl单晶及其应用展望 [J]. 振动、测试与诊断, 2019, 39: 915 |
/
| 〈 |
|
〉 |