Cu-2.0Fe合金等温处理过程中富Fe析出相的形态演变

  • 陈凯旋 ,
  • 李宗烜 ,
  • 王自东 ,
  • Demange Gilles ,
  • 陈晓华 ,
  • 张佳伟 ,
  • 吴雪华 ,
  • Zapolsky Helena
展开
  • 1北京科技大学 材料科学与工程学院 北京 100083
    2北京科技大学 新金属材料国家重点实验室 北京 100083
    3Group of Materials Science, University of Rouen Normandy, 76801 Saint-Etienne du Rouvray, France
陈凯旋,男,1991年生,副教授,博士
王自东,wangzd@mater.ustb.edu.cn,主要从事金属材料加工理论和工艺的研究

收稿日期: 2021-12-16

  修回日期: 2022-01-14

  网络出版日期: 2022-07-08

基金资助

国家自然科学基金项目(52101119);北京市自然科学基金青年项目(2214072);北京科技大学青年教师学科交叉研究项目(中央高校基本科研业务费专项资金)(FRF-IDRY-20-034);中央高校基本科研业务费专项资金项目(00007490)

Morphological Evolution of Fe-Rich Precipitates in a Cu-2.0Fe Alloy During Isothermal Treatment

  • CHEN Kaixuan ,
  • LI Zongxuan ,
  • WANG Zidong ,
  • Demange Gilles ,
  • CHEN Xiaohua ,
  • ZHANG Jiawei ,
  • WU Xuehua ,
  • Zapolsky Helena
Expand
  • 1School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
    2State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
    3Group of Materials Science, University of Rouen Normandy, 76801 Saint-Etienne du Rouvray, France

Received date: 2021-12-16

  Revised date: 2022-01-14

  Online published: 2022-07-08

Supported by

National Natural Science Foundation of China(52101119);Beijing Municipal Natural Science Fo-undation(2214072);Interdisciplinary Research Project for Young Teachers of USTB (Fundamental Research Funds for the Central Universities)(FRF-IDRY-20-034);Fundamental Research Funds for the Central Universities(00007490)

摘要

研究了Cu-2.0Fe (质量分数,%)合金中富Fe析出相形态的演变行为及其与等温温度和保温时间的关系。结果表明,Cu-2.0Fe合金在Fe相fcc温区内的924、964和984℃保温时,富Fe相粗化并伴随着球状(纳米级)→立方状(亚微米级)→四分支花瓣状(亚微米级)→多分支花瓣状(微米级)的形态演变。随着等温温度和保温时间的增加,多分支花瓣状颗粒的尺寸逐步增大,分支数量逐步增加。多分支花瓣状颗粒的长大需要吞噬周边的小颗粒,导致温度升高时纳米~亚微米级富Fe颗粒的数量密度下降。基于相场模拟的分析表明,界面能、弹性能和化学驱动力的综合作用诱发富Fe相的多重形态演变,其中四分支花瓣状颗粒长大过程中,在弹性应变能和化学驱动力相互角逐作用下,从一次分支上生长出二次分支,进而产生了多分支花瓣状的形态。

本文引用格式

陈凯旋 , 李宗烜 , 王自东 , Demange Gilles , 陈晓华 , 张佳伟 , 吴雪华 , Zapolsky Helena . Cu-2.0Fe合金等温处理过程中富Fe析出相的形态演变[J]. 金属学报, 2023 , 59(12) : 1665 -1674 . DOI: 10.11900/0412.1961.2021.00568

Abstract

The morphology of precipitates changes during coarsening regimes, thereby resulting in the modification of mechanical properties of metallic materials. Hence, understanding the morphological evolution in precipitates is critical to tailor the macroscopic properties of industrial alloys. In particular, the morphology of Fe-rich precipitates in Cu alloys is complex, and it evolves from sphere to cube to petal and finally splits, which has been observed during casting and furnace cooling. However, morphological changes in Fe-rich precipitates during isothermal treatment remain unclear; thus, revealing the mechanism of morphological evolution is necessary. In this study, the relationship among the morphological evolution behavior of Fe-rich precipitates in Cu-2.0Fe (mass fraction, %) alloy, temperature, and time under different isothermal-treated processes was analyzed using SEM and TEM coupled with phase-field modeling. Results show morphology changes from a sphere in nanoscale to a cube in submicron scale to a four-branched petal in the submicron scale, and to a multi-branched petal in micron scale during coarsening of Fe-rich precipitates in Cu-2.0Fe alloy isothermally treated at 924, 964, and 984oC (i.e., the temperature range of the fcc Fe phase). The size of multi-branched petal-like Fe-rich precipitates and the number of branches increase with the increase of isothermal temperature and holding time. During coarsening of multi-branched petal-like precipitates, the surrounding small Fe-rich precipitates are engulfed, and thence the number density of the smaller ones in nano and submicron scales decreases when the temperature increases. The modeling result elucidates the multiple morphological evolution of Fe-rich precipitates, which is identical to the experiments, under the effects of interfacial energy, elastic energy, and chemical driving force. In particular, the combined effect of the latter two energies induces the initiation and growth of secondary branches out of primary branches in the four-branched petals, thereby producing multi-branched petal-like precipitates.

参考文献

1 Chen K X, Chen X H, Ding D, et al. Formation mechanism of in-situ nanostructured grain in cast Cu-10Sn-2Zn-1.5Fe-0.5Co (wt.%) alloy[J]. Mater. Des., 2016, 94: 338
2 Chen K X, Chen X H, Wang Z D, et al. Optimization of deformation properties in as-cast copper by microstructural engineering. Part I. Microstructure[J]. J. Alloys Compd., 2018, 763: 592
3 Li Z, Wu R. Research development of theoretical basis and application of strengthening precipitates in steel[J]. Mater. Rep., 2020, 34(Z2): 412
  李 钊, 吴 润. 钢中强化析出相的理论基础及其应用研究进展[J]. 材料导报, 2020, 34(Z2): 412
4 Jiang S H, Wang H, Wu Y, et al. Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation[J]. Nature, 2017, 544: 460
5 Sun W W, Zhu Y M, Marceau R, et al. Precipitation strengthening of aluminum alloys by room-temperature cyclic plasticity[J]. Science, 2019, 363: 972
6 Sidorov V, Polovov I, Rusanov B, et al. Density, electroresistivity and magnetic susceptibility of Al-Sc alloy in crystalline and liquid states[J]. J. Alloys Compd., 2019, 787: 1345
7 Liu C W, Li Y S, Zhu L H, et al. Precipitation kinetics of γ phase in an inverse Ni-Al alloy[J]. Comput. Condens. Matter, 2017, 11: 40
8 Li W Y, Cao C C, Yin S. Solid-state cold spraying of Ti and its alloys: A literature review[J]. Prog. Mater. Sci., 2020, 110: 100633
9 Marquis E A, Seidman D N. Nanoscale structural evolution of Al3Sc precipitates in Al(Sc) alloys[J]. Acta Mater., 2001, 49: 1909
10 Van Dalen M E, Dunand D C, Seidman D N. Effects of Ti additions on the nanostructure and creep properties of precipitation-strengthened Al-Sc alloys[J]. Acta Mater., 2005, 53: 4225
11 Miyazaki T, Imamura H, Kozakai T. The formation of “γ' precipitate doublets” in Ni-Al alloys and their energetic stability[J]. Mater. Sci. Eng., 1982, 54: 9
12 Hu B F, Liu G Q, Wu K, et al. Morphological instability of γ' phase in nickel-based powder metallurgy superalloys[J]. Acta Metall. Sin., 2012, 48: 257
  胡本芙, 刘国权, 吴 凯 等. 镍基粉末冶金高温合金中γ'相形态不稳定性研究[J]. 金属学报, 2012, 48: 257
13 Nguyen L, Shi R P, Wang Y Z, et al. Quantification of rafting of γ' precipitates in Ni-based superalloys[J]. Acta Mater., 2016, 103: 322
14 Chen Y Q, Prasath Babu R, Slater T J A, et al. An investigation of diffusion-mediated cyclic coarsening and reversal coarsening in an advanced Ni-based superalloy[J]. Acta Mater., 2016, 110: 295
15 Wang L, Zenk C, Stark A, et al. Morphology evolution of Ti3AlC carbide precipitates in high Nb containing TiAl alloys[J]. Acta Mater., 2017, 137: 36
16 Tian G F, Chen Y, Zou J W, et al. Research on morphology instability of γ' precipitates in FGH4096 superalloy[J]. Powder Metall. Ind., 2018, 28(6): 23
  田高峰, 陈 阳, 邹金文 等. FGH4096合金γ'析出相的形态失稳研究[J]. 粉末冶金工业, 2018, 28(6): 23
17 Vogel F, Wanderka N, Balogh Z, et al. Mapping the evolution of hierarchical microstructures in a Ni-based superalloy[J]. Nat. Commun., 2013, 4: 2955
18 Jokisaari A M, Naghavi S S, Wolverton C, et al. Predicting the morphologies of γ' precipitates in cobalt-based superalloys[J]. Acta Mater., 2017, 141: 273
19 Wang Z D, Wang X W, Wang Q S, et al. Fabrication of a nanocomposite from in situ iron nanoparticle reinforced copper alloy[J]. Nanotechnology, 2009, 20: 075605
20 Ye Y X, Yang X Y, Liu C Z, et al. Enhancement of strength and ductility of Cu-Sn-Zn alloy by iron addition[J]. Mater. Sci. Eng., 2014, A612: 246
21 Cao M M, Zhou Z M, Tang L W, et al. Development of Cu-Fe alloys with high strength and high conductivity[J]. Mater. Rep., 2011, 25: 487
  曹敏敏, 周志明, 唐丽文 等. 高强高导Cu-Fe合金的研究进展[J]. 材料导报, 2011, 25: 487
22 Chen K X, Korzhavyi P A, Demange G, et al. Morphological instability of iron-rich precipitates in Cu-Fe-Co alloys[J]. Acta Mater., 2019, 163: 55
23 Han S Z, Kim K H, Kang J, et al. Design of exceptionally strong and conductive Cu alloys beyond the conventional speculation via the interfacial energy-controlled dispersion of γ-Al2O3 nanoparticles[J]. Sci. Rep., 2015, 5: 17364
24 B?hm H J, Rasool A. Effects of particle shape on the thermoelastoplastic behavior of particle reinforced composites[J]. Int. J. Solids Struct., 2016, 87: 90
25 Qin S Y, Chen C R, Zhang G D, et al. The effect of particle shape on ductility of SiCp reinforced 6061 Al matrix composites[J]. Mater. Sci. Eng., 1999, A272: 363
26 Hu H, Li L, Xu L. Research progress on the preparation technology of Cu-Fe alloy[J]. Powder Metall. Technol., 2019, 37: 468
  胡 号, 李 雷, 许 磊. Cu-Fe合金制备技术研究进展[J]. 粉末冶金技术, 2019, 37: 468
27 Hu G X, Cai X, Rong Y H. Fundamentals of Materials Science[M]. 3rd Ed., Shanghai: Shanghai Jiao Tong University Press, 2010: 152
  胡赓祥, 蔡 珣, 戎咏华. 材料科学基础[M]. 第3版. 上海: 上海交通大学出版社, 2010: 152
28 Zuo L F, Ni R, Wang Z D, et al. Nano-precipitates in low carbon high strength steel during the tempering process[J]. J. Iron Steel Res., 2013, 25(2): 39
  左龙飞, 倪 睿, 王自东 等. 低碳高强钢中纳米析出相回火过程中的透射分析[J]. 钢铁研究学报, 2013, 25(3): 39
29 Demange G, Chamaillard M, Zapolsky H, et al. Generalization of the Fourier-spectral Eyre scheme for the phase-field equations: Application to self-assembly dynamics in materials[J]. Comput. Mater. Sci., 2018, 144: 11
文章导航

/