高合金化GH4151合金复杂析出相演变行为
收稿日期: 2021-09-03
修回日期: 2021-12-13
网络出版日期: 2022-06-20
基金资助
高温结构材料重点实验室开放基金项目和中央高校基本科研业务费项目(FRF-TP-19-038A2)
Evolution Behavior of Complex Precipitation Phases in Highly Alloyed GH4151 Superalloy
Received date: 2021-09-03
Revised date: 2021-12-13
Online published: 2022-06-20
Supported by
National Key Laboratory of Advanced High-Temperature Materials Open Fund and Fundamental Research Funds for the Central Universities(FRF-TP-19-038A2)
利用OM、SEM及热力学计算等方法研究了GH4151合金在热处理过程中的组织演变行为。结果表明,高合金化导致合金的铸态组织复杂,包括Laves相、γ/γ′共晶、η相等低熔点相。由于各析出相的初熔温度不同,制定了三段式热处理,有效地消除了合金中的有害相。铸态GH4151合金中偏析元素Nb和Ti含量对低熔点相初熔温度的影响较大,Mo含量的影响相对较低,W含量的影响不明显。降低Ti含量,提高Nb、Mo含量可降低η相的初熔温度;提高Ti、Mo含量,降低Nb含量可降低Laves相的初熔温度。高含量的γ′相形成元素导致γ′相的组织演变行为具有冷却速率敏感性。15℃/min是GH4151合金中γ′相发生不规则生长的临界冷却速率。与低含量γ′相形成元素的合金相比,GH4151合金冷却速率高于15℃/min时,γ′相尺寸更大;冷却速率低于15℃/min时,γ′相不规则程度更高。高合金化的特点导致GH4151合金呈现复杂的组织演变行为。
王法 , 江河 , 董建新 . 高合金化GH4151合金复杂析出相演变行为[J]. 金属学报, 2023 , 59(6) : 787 -796 . DOI: 10.11900/0412.1961.2021.00375
Designing high-performance aeroengine is important for development in the aviation industry. One of the key components is turbine disk material that can operate at 800oC. Among various methods for strengthening alloys, increasing the alloying degree is important, and GH4151 is one of the typical alloys with a high alloying degree. It comprises a large number of refractory metal elements and γ'-forming elements. OM, SEM, and JMatPro software were used to study the sensitivity of GH4151 microstructure evolution during heat treatment processes. The results show that a high alloying degree produces a complex microstructure with low-melting phases, such as Laves, γ/γ′ eutectic, and η phases. Due to the difference in incipient melting temperature of each precipitated phase, a three-stage heat treatment was developed to effectively eliminate the harmful phases in the alloy. The contents of segregation elements Nb and Ti in the as-cast GH4151 alloy have an obvious influence on the incipient melting temperature, whereas the effect of Mo content is relatively slight, and that of W content is not obvious. Decreasing Ti content while increasing Nb and Mo contents could reduce the incipient melting temperature of the η phase. Furthermore, increasing Ti and Mo contents while decreasing Nb content could reduce the incipient melting temperature of Laves phase. A large amount of γ'-forming elements contributes to the cooling rate sensitivity of γ′ phase evolution. 15oC/min is the critical value for the irregular growth of the γ' phase in the GH4151 alloy. When compared to alloys with low γ′-forming elements content, the γ′ phase in GH4151 alloy has a larger size when the cooling rate is > 15oC/min, and exhibits an irregular shape when the cooling rate is < 15oC/min. Thus, a high alloying degree contributes to the complex and sensitive microstructure evolution behavior of GH4151 alloy.
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