热处理温度对Ti0.5Zr1.5NbTa0.5Sn0.2 高熵合金组织结构与力学性能的影响
收稿日期: 2021-12-13
修回日期: 2022-04-12
网络出版日期: 2022-06-13
基金资助
国家自然科学基金项目(51771049);国家自然科学基金项目(51790484);冲击环境材料技术重点实验室基金项目(JCKYS20-20602005)
Effect of Heat Treatment Temperature on Microstructure and Mechanical Properties of Ti0.5Zr1.5NbTa0.5Sn0.2 High-Entropy Alloy
Received date: 2021-12-13
Revised date: 2022-04-12
Online published: 2022-06-13
Supported by
National Natural Science Foundation of China(51771049);National Natural Science Foundation of China(51790484);National Key Laboratory Foundation of Science and Technology on Materials under Shock and Impact(JCKYS20-20602005)
制备了一种中等密度(约8.0 g/cm3)的难熔高熵合金Ti0.5Zr1.5NbTa0.5Sn0.2 (摩尔比),系统研究了热处理温度对合金组织结构和力学性能的影响。结果表明:铸态Ti0.5Zr1.5NbTa0.5Sn0.2合金组织为富Zr和富Ta bcc相以及晶内的板条状Zr5Sn3。随着热处理温度升高,富Ta bcc相体积分数逐渐减少,Zr5Sn3体积分数先增加后减少。当热处理温度为1400℃时,样品呈现近单相bcc结构。准静态条件下,系列样品均具有良好的压缩塑性变形能力;随着热处理温度的提高,合金屈服强度逐渐上升,1400℃热处理样品的屈服强度为1749 MPa。动态变形时,合金表现出明显的应变率强化效应,屈服强度显著增加,1400℃热处理样品的屈服强度达到2750 MPa,塑性变形量有所下降。强度随热处理温度提升的原因是9.8%的平均原子尺寸差带来了显著的固溶强化效果。
韩林至 , 牟娟 , 周永康 , 朱正旺 , 张海峰 . 热处理温度对Ti0.5Zr1.5NbTa0.5Sn0.2 高熵合金组织结构与力学性能的影响[J]. 金属学报, 2022 , 58(9) : 1159 -1168 . DOI: 10.11900/0412.1961.2021.00551
Refractory high-entropy alloys (RHEAs) have great application potential in extreme conditions due to their outstanding high-temperature properties. However, several issues, such as high density, poor room temperature plasticity, and high cost limit their practical application. A new Ti0.5Zr1.5NbTa0.5Sn0.2 (molar ratio) RHEA with a medium density of approximately 8.0 g/cm3 was prepared to address the aforementioned issues; the effects of heat treatment temperature on the alloy's microstructure and mechanical properties were systematically examined. The findings indicate that as-cast Ti0.5Zr1.5NbTa0.5Sn0.2 RHEA contains Zr-rich and Ta-rich bcc phases and lath-like Zr5Sn3 intermetallics in the crystal. The volume fraction of the Ta-rich bcc phase gradually decreases with the increase in heat treatment temperature, and Zr5Sn3 intermetallic first increases and then decreases. The sample presents a near single-phase bcc structure when the heat treatment temperature is 1400oC. A series of samples have good compressive plastic deformation ability under quasi-static conditions, and the alloy's yield strength increased gradually with an increasing heat treatment temperature. The sample's yield strength quenched at 1400oC is as high as 1749 MPa. The alloy showed strain rate strengthening effect under dynamic loading, and the yield strength significantly increased. The sample's yield strength quenched at 1400oC reaches 2750 MPa; however, the plastic deformation ability is reduced. The reason why the strength increases with the heat treatment temperature is that the 9.8% average atomic size difference results in a significant solid solution strengthening effect.
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