Cu-V双合金化3Mn钢的组织和力学性能
收稿日期: 2022-03-07
修回日期: 2022-05-08
网络出版日期: 2022-06-06
基金资助
国家自然科学基金项目(51831002);中央高校基本科研业务费专项基金项目(06600019;06500151)
Microstructure and Mechanical Properties of Cu-V Dual Alloyed 3Mn Steel
Received date: 2022-03-07
Revised date: 2022-05-08
Online published: 2022-06-06
Supported by
National Natural Science Foundation of China(51831002);Fundamental Research Founds for the Central Universities(06600019;06500151)
研究了Cu-V双合金化的3Mn钢热轧板在550~650℃温轧和临界退火等制备工艺过程中(简称温轧退火样品)的组织演变与最终力学性能,并与热轧后在同样温度范围时效处理并临界退火的样品(简称热轧时效退火样品)进行对比。结果表明,温轧退火样品的塑性显著高于热轧时效退火样品,但2者屈服强度相似,这归因于温轧阶段引入大量缺陷,促进了临界退火时奥氏体逆转变过程,提高了残余奥氏体分数,最终可实现屈服强度高达1230~1320 MPa并保有23%~29%的延伸率,这一综合性能显著优于文献中Cu/V单一合金化的中锰钢,尤其是屈服强度大幅提高。这是由于采用了Cu-V双合金化并且在热轧后采用了温轧加临界退火的两段热变形处理工艺,除了在温轧阶段引入富Cu析出相以实现强化外,在临界退火阶段析出的VC还弥补了由于退火导致的软化,实现了高屈服强度;并形成25%~30%的残余奥氏体来提供相变诱导塑性,从而保证了高塑性。
许仁杰 , 屠鑫 , 胡斌 , 罗海文 . Cu-V双合金化3Mn钢的组织和力学性能[J]. 金属学报, 2024 , 60(6) : 817 -825 . DOI: 10.11900/0412.1961.2022.00101
Recently, medium Mn steels (MMnS) have been extensively investigated because of the excellent mechanical combination of strength and ductility achieved at the relatively low alloying cost. Intercritical annealing (IA) is a key process of MMnS to form intercritical austenite that can be retained fully or partially at room temperature, which can trigger transformation-induced plasticity and then improve work hardening during deformation. However, this process leads to a relatively low yield strength because the recovery, recrystallization, grain growth, coarsening, and dissolution of precipitates could occur during IA. In this study, the microstructural evolution and resultant mechanical properties of Cu-V dual alloyed 3Mn steel were examined during two manufacturing processes: hot rolling → warm rolling at 550-650°C → IA at 690°C for 10 min (termed as WR-IA) and hot rolling → aging at 550-650°C for 70 min → IA at 690°C for 10 min (termed as Aging-IA). That is,the two processes differentiate in either the warm rolling or the aging process used as the intermediate process. WR-IA specimens exhibit significantly higher ductility than Aging-IA ones, but they both have the same yield strength. The former is attributed to a large quantity of defects introduced during warm rolling, which promoted austenite reverse transformation during IA and led to a large fraction of retained austenite. The resultant tensile properties include yield strength of 1230-1320 MPa and ductility of 23%-29%, which is superior to those of either V- or Cu-alloyed MMnS published in references. In particular, higher yield strength was achieved because the dual alloying of Cu-V and the two-stage thermomechanical process, that is,warm rolling plus IA, are adopted. The first warm rolling promoted Cu-rich precipitates dispersed for strengthening, and the precipitation of VC during subsequent IA could compensate for the softening caused by IA. Consequently, a high yield strength was achieved. Meanwhile, 25%-30% fraction of austenite was retained, thereby providing transformation-induced plasticity during deformation, leading to high ductility.
Key words: medium Mn steel; warm rolling; precipitate; austenite; mechanical property
| 1 | Dong H, Cao W Q, Shi J, et al. Microstructure and performance control technology of the 3rd generation auto sheet steels [J]. Iron Steel, 2011, 46(6): 1 |
| 董 瀚, 曹文全, 时 捷 等. 第3代汽车钢的组织与性能调控技术 [J]. 钢铁, 2011, 46(6): 1 | |
| 2 | Hu B, Tu X, Luo H W, et al. Effect of warm rolling process on microstructures and tensile properties of 10 Mn steel [J]. J. Mater. Sci. Technol., 2020, 47: 131 |
| 3 | Wang C Y, Chang Y, Zhou F L, et al. M3 microstructure control theory and technology of the third-generation automotive steels with high strength and high ductility [J]. Acta Metall. Sin., 2020, 56: 400 |
| 王存宇, 常 颖, 周峰峦 等. 高强度高塑性第三代汽车钢的M3组织调控理论与技术 [J]. 金属学报, 2020, 56: 400 | |
| 4 | Suh D W, Kim S J. Medium Mn transformation-induced plasticity steels: Recent progress and challenges [J]. Scr. Mater., 2017, 126: 63 |
| 5 | Zhu Y S, Hu B, Luo H W. Influence of Nb and V on microstructure and mechanical properties of hot-rolled medium Mn steels [J]. Steel Res. Int., 2018, 89: 1700389 |
| 6 | Park T M, Jeong M S, Jung C, et al. Improved strength of a medium-Mn steel by V addition without sacrificing ductility [J]. Mater. Sci. Eng., 2021, A802: 140681 |
| 7 | Othen P J, Jenkins M L, Smith G D W. High-resolution electron microscopy studies of the structure of Cu precipitates in α-Fe [J]. Philos. Mag., 1994, 70A: 1 |
| 8 | Maruyama N, Sugiyama M, Hara T, et al. Precipitation and phase transformation of copper particles in low alloy ferritic and martensitic steels [J]. Mater. Trans. JIM, 1999, 40: 268 |
| 9 | Du Y B, Hu X F, Zhang S Q, et al. Microstructure and mechanical properties of HSLA steel containing 1.4%Cu [J]. Acta Metall. Sin., 2020, 56: 1343 |
| 杜瑜宾, 胡小锋, 张守清 等. 含1.4%Cu的HSLA钢的组织和力学性能 [J]. 金属学报, 2020, 56: 1343 | |
| 10 | Hu B, Rong X Q, Tian C, et al. Nanoscale precipitation and ultrafine retained austenite induced high strength-ductility combination in a newly designed low carbon Cu-bearing medium-Mn steel [J]. Mater. Sci. Eng., 2021, A822: 141685 |
| 11 | Isheim D, Vaynman S, Fine M E, et al. Copper-precipitation hardening in a non-ferromagnetic face-centered cubic austenitic steel [J]. Scr. Mater., 2008, 59: 1235 |
| 12 | Sherif M Y, Mateo C G, Sourmail T, et al. Stability of retained austenite in TRIP-assisted steels [J]. Mater. Sci. Technol., 2004, 20: 319 |
| 13 | Sugimoto K I, Kobayashi M, Hashimoto S I. Ductility and strain-induced transformation in a high-strength transformation-induced plasticity-aided dual-phase steel [J]. Metall. Mater. Trans., 1992, 23A: 3085 |
| 14 | Babu S S, Specht E D, David S A, et al. In-situ observations of lattice parameter fluctuations in austenite and transformation to bainite [J]. Metall. Mater. Trans., 2005, 36A: 3281 |
| 15 | Podder A S, Bhadeshia H K D H. Thermal stability of austenite retained in bainitic steels [J]. Mater. Sci. Eng., 2010, A527: 2121 |
| 16 | Tian C, Guo H, Enomoto M, et al. Non-uniform distribution and strengthening effect of Cu precipitates enclosed in austenite during intercritical annealing in a medium Mn steel [J]. Mater. Charact., 2022, 184: 111669 |
| 17 | Cheng P, Hu B, Liu S L, et al. Influence of retained austenite and Cu precipitates on the mechanical properties of a cold-rolled and intercritically annealed medium Mn steel [J]. Mater. Sci. Eng., 2019, A746: 41 |
| 18 | Zou Y, Xu Y B, Han D T, et al. Aging characteristics and strengthening behavior of a low-carbon medium-Mn Cu-bearing steel [J]. Mater. Sci. Eng., 2018, A729: 423 |
| 19 | Zou Y, Xu Y B, Han D T, et al. Combined contribution of Cu-rich precipitates and retained austenite on mechanical properties of a novel low-carbon medium-Mn steel plate [J]. J. Mater. Sci., 2019, 54: 3438 |
| 20 | Kong H J, Yang T, Chen R, et al. Breaking the strength-ductility paradox in advanced nanostructured Fe-based alloys through combined Cu and Mn additions [J]. Scr. Mater., 2020, 186: 213 |
| 21 | Yan S, Liang T S, Chen J Q, et al. A novel Cu-Ni added medium Mn steel: Precipitation of Cu-rich particles and austenite reversed transformation occurring simultaneously during ART annealing [J]. Mater. Sci. Eng., 2019, A746: 73 |
| 22 | Chen J, Ren J K, Liu Z Y, et al. 1.0 GPa low carbon medium Mn heavy steel plate with excellent ductility [J]. Mater. Sci. Technol., 2019, 35: 2143 |
| 23 | Yi H L, Zhang L R, Yu X X, et al. Structure and properties of vanadium microalloyed medium manganese steel [J]. J. Huazhong Univ. Sci. Technol. (Nat. Sci. Ed.), 2016, 44(1): 60 |
| 衣海龙, 张路冉, 余宣询 等. 钒微合金化中锰钢组织与性能研究 [J]. 华中科技大学学报(自然科学版), 2016, 44(1): 60 | |
| 24 | Mishra G, Chandan A K. Effect of cold deformation extent and ART annealing duration on the microstructure and mechanical properties of a medium manganese steel [J]. Mater. Chem. Phys., 2021, 271: 124940 |
| 25 | Warren B E. X-ray studies of deformed metals [J]. Prog. Metal Phys., 1959, 8: 147 |
| 26 | Williamson G K, Smallman R E. III. Dislocation densities in some annealed and cold-worked metals from measurements on the X-ray Debye-Scherrer spectrum [J]. Philos. Mag., 1956, 1: 34 |
| 27 | Ungár T, Borbély A. The effect of dislocation contrast on X-ray line broadening: A new approach to line profile analysis [J]. Appl. Phys. Lett., 1996, 69: 3173 |
| 28 | Taylor G I. The mechanism of plastic deformation of crystals. Part I.—Theoretical [J]. Proc. R. Soc. London, 1934, 145A: 362 |
| 29 | Han J, Lee S J, Jung J G, et al. The effects of the initial martensite microstructure on the microstructure and tensile properties of intercritically annealed Fe-9Mn-0.05C steel [J]. Acta Mater., 2014, 78: 369 |
| 30 | Takaki S, Fukunaga K, Syarif J, et al. Effect of grain refinement on thermal stability of metastable austenitic steel [J]. Mater. Trans., 2004, 45: 2245 |
| 31 | Ma J W, Lu Q, Sun L, et al. Two-step intercritical annealing to eliminate Lüders band in a strong and ductile medium Mn steel [J]. Metall. Mater. Trans., 2018, 49A: 4404 |
| 32 | Sun B H, Ma Y, Vanderesse N, et al. Macroscopic to nanoscopic in situ investigation on yielding mechanisms in ultrafine grained medium Mn steels: Role of the austenite-ferrite interface [J]. Acta Mater., 2019, 178: 10 |
| 33 | Luo H W, Dong H, Huang M X. Effect of intercritical annealing on the Lüders strains of medium Mn transformation-induced plasticity steels [J]. Mater. Des., 2015, 83: 42 |
| 34 | Hu B, Luo H W. A novel two-step intercritical annealing process to improve mechanical properties of medium Mn steel [J]. Acta Mater., 2019, 176: 250 |
| 35 | Luo H W, Qiu C H, Dong H, et al. Experimental and numerical analysis of influence of carbide on austenitisation kinetics in 5Mn TRIP steel [J]. Mater. Sci. Technol., 2014, 30: 1367 |
| 36 | Ding R, Dai Z B, Huang M X, et al. Effect of pre-existed austenite on austenite reversion and mechanical behavior of an Fe-0.2C-8Mn-2Al medium Mn steel [J]. Acta Mater., 2018, 147: 59 |
| 37 | Orowan E. Symposium on Internal Stresses in Metals and Alloys [M]. London: Institute of Metals, 1948: 451 |
| 38 | Gladman T. Precipitation hardening in metals [J]. Mater. Sci. Technol, 1999, 15: 30 |
/
| 〈 |
|
〉 |