基于增强相构型设计的石墨烯/Cu复合材料研究进展
收稿日期: 2021-03-24
修回日期: 2021-05-26
网络出版日期: 2021-06-08
基金资助
国家自然科学基金项目(51771130)
Progress on Graphene/Copper Composites Focusing on Reinforcement Configuration Design: A Review
Received date: 2021-03-24
Revised date: 2021-05-26
Online published: 2021-06-08
Supported by
National Natural Science Foundation of China(51771130)
铜基复合材料具有优异的功能特性及力学性能，在电子、电工等领域具有广阔的应用前景。作为一类理想的增强相，石墨烯具有优异的综合性能以及二维结构特征。相比于其他如颗粒增强相、晶须增强相，石墨烯与Cu的性能匹配性更好，同时其在Cu基体中的分布结构具有更强的可设计性，可显著改善铜基复合材料的综合性能，因此利用新工艺实现石墨烯分布构型的调控设计成为当今铜基复合材料研究的热点。本文总结了近年来石墨烯在Cu基体中分布的构型(均匀构型、层状构型以及网络构型)及其相应的制备工艺，讨论了石墨烯构型对于铜基复合材料性能的影响，并展望了石墨烯构型设计的新思路，以及特殊构型石墨烯/Cu复合材料未来的发展趋势以及应用领域。
赵乃勤 , 郭斯源 , 张翔 , 何春年 , 师春生 . 基于增强相构型设计的石墨烯/Cu复合材料研究进展[J]. 金属学报, 2021 , 57(9) : 1087 -1106 . DOI: 10.11900/0412.1961.2021.00120
Copper matrix composites have extensive application prospects in electronics and electrical engineering because of their excellent functional and mechanical properties. Graphene has excellent properties and a two-dimensional structure, making it an ideal reinforcement material. Compared with other reinforcements such as particles and whiskers, graphene has better performance matching with copper. Moreover, its distribution in the copper matrix can be controlled well, which can significantly improve the comprehensive properties of the composite. Therefore, controlling the distribution of graphene using novel fabrication processes is essential. This review focuses on the configuration of graphene distributed in a copper matrix (uniform configuration, layered configuration, and network configuration) and the corresponding fabrication processes. The effects of different graphene configurations on the properties of various copper matrix composites are discussed. New ideas for graphene configuration design, future development trends, and potential applications of graphene/copper matrix composites with unique configurations are anticipated.
| 1 | Xu X Z, Yi D, Wang Z C, et al. Greatly enhanced anticorrosion of Cu by commensurate graphene coating [J]. Adv. Mater., 2018, 30: 1702944 |
| 2 | Arnaud C, Lecouturier F, Mesguich D, et al. High strength-high conductivity double-walled carbon nanotube-copper composite wires [J]. Carbon, 2016, 96: 212 |
| 3 | Uddin S M, Mahmud T, Wolf C, et al. Effect of size and shape of metal particles to improve hardness and electrical properties of carbon nanotube reinforced copper and copper alloy composites [J]. Compos. Sci. Technol., 2010, 70: 2253 |
| 4 | Baig Z, Mamat O, Mustapha M. Recent progress on the dispersion and the strengthening effect of carbon nanotubes and graphene-reinforced metal nanocomposites: A review [J]. Crit. Rev. Solid State Mater. Sci., 2018, 43: 1 |
| 5 | Kang Q P, He X B, Ren S B, et al. Microstructure and thermal properties of copper-diamond composites with tungsten carbide coating on diamond particles [J]. Mater. Charact., 2015, 105: 18 |
| 6 | Deng H, Yi J H, Xia C, et al. Improving the mechanical properties of carbon nanotube-reinforced pure copper matrix composites by spark plasma sintering and hot rolling [J]. Mater. Lett., 2018, 210: 177 |
| 7 | Chen X F, Tao J M, Yi J H, et al. Balancing the strength and ductility of carbon nanotubes reinforced copper matrix composites with microlaminated structure and interdiffusion interface [J]. Mater. Sci. Eng., 2018, A712: 790 |
| 8 | Tjong S C. Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets [J]. Mater. Sci. Eng., 2013, R74: 281 |
| 9 | Feng M Q, Jia S G, Li S L, et al. Research progress of Cu/C composites [J]. Trans. Mater. Heat Treat., 2020, 41(12): 25 |
| 9 | 冯孟奇, 贾淑果, 李韶林等. 铜/碳复合材料的研究进展 [J]. 材料热处理学报, 2020, 41(12): 25 |
| 10 | Fan T X, Liu Y, Yang K M, et al. Recent progress on interfacial structure optimization and their influencing mechanism of carbon reinforced metal matrix composites [J]. Acta Metall. Sin., 2019, 55: 16 |
| 10 | 范同祥, 刘 悦, 杨昆明等. 碳/金属复合材料界面结构优化及界面作用机制的研究进展 [J]. 金属学报, 2019, 55: 16 |
| 11 | Yoon D, Son Y W, Cheong H. Negative thermal expansion coefficient of graphene measured by Raman spectroscopy [J]. Nano Lett., 2011, 11: 3227 |
| 12 | Novoselov K S, Geim A K, Morozov S V, et al. Two-dimensional gas of massless Dirac fermions in graphene [J]. Nature, 2005, 438: 197 |
| 13 | Sun Z Z, Yan Z, Yao J, et al. Growth of graphene from solid carbon sources [J]. Nature, 2010, 468: 549 |
| 14 | Wang G R, Dai Z H, Xiao J K, et al. Bending of multilayer van der Waals materials [J]. Phys. Rev. Lett., 2019, 123: 116101 |
| 15 | Lee C, Wei X D, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene [J]. Science, 2008, 321: 385 |
| 16 | Zhao N Q, Liu X H, Pu B W. Progress on multi-dimensional carbon nanomaterials reinforced aluminum matrix composites: A review [J]. Acta Metall. Sin., 2019, 55: 1 |
| 16 | 赵乃勤, 刘兴海, 蒲博闻. 多维度碳纳米相增强铝基复合材料研究进展 [J]. 金属学报, 2019, 55: 1 |
| 17 | Geng L, Fan G H. Progress on strengthening and toughening mechanism for metal matrix composites by configuration design [J]. Mater. China, 2016, 35: 686 |
| 17 | 耿 林, 范国华. 金属基复合材料的构型强韧化研究进展 [J]. 中国材料进展, 2016, 35: 686 |
| 18 | Jiang R R, Zhou X F, Fang Q L, et al. Copper-graphene bulk composites with homogeneous graphene dispersion and enhanced mechanical properties [J]. Mater. Sci. Eng., 2016, A654: 124 |
| 19 | Jia Z F, Li H Q, Zhao Y, et al. Electrical and mechanical properties of poly(dopamine)-modified copper/reduced graphene oxide composites [J]. J. Mater. Sci., 2017, 52: 11620 |
| 20 | Luo H B, Sui Y W, Qi J Q, et al. Mechanical enhancement of copper matrix composites with homogeneously dispersed graphene modified by silver nanoparticles [J]. J. Alloys Compd., 2017, 729: 293 |
| 21 | Tang Y X, Yang X M, Wang R R, et al. Enhancement of the mechanical properties of graphene-copper composites with graphene-nickel hybrids [J]. Mater. Sci. Eng., 2014, A599: 247 |
| 22 | Zhang D D, Zhan Z J. Preparation of graphene nanoplatelets-copper composites by a modified semi-powder method and their mechanical properties [J]. J. Alloys Compd., 2016, 658: 663 |
| 23 | Gao X, Yue H Y, Guo E J, et al. Mechanical properties and thermal conductivity of graphene reinforced copper matrix composites [J]. Powder Technol., 2016, 301: 601 |
| 24 | Shao G S, Liu P, Zhang K, et al. Mechanical properties of graphene nanoplates reinforced copper matrix composites prepared by electrostatic self-assembly and spark plasma sintering [J]. Mater. Sci. Eng., 2019, A739: 329 |
| 25 | Cui R, Han Y, Zhu Z X, et al. Investigation of the structure and properties of electrodeposited Cu/graphene composite coatings for the electrical contact materials of an ultrahigh voltage circuit breaker [J]. J. Alloys Compd., 2019, 777: 1159 |
| 26 | Pavithra C L P, Sarada B V, Rajulapati K V, et al. A new electrochemical approach for the synthesis of copper-graphene nanocomposite foils with high hardness [J]. Sci. Rep., 2014, 4: 4049 |
| 27 | Hwang J, Yoon T, Jin S H, et al. Enhanced mechanical properties of graphene/copper nanocomposites using a molecular-level mixing process [J]. Adv. Mater., 2013, 25: 6724 |
| 28 | Wang S Y, Han S B, Xin G Q, et al. High-quality graphene directly grown on Cu nanoparticles for Cu-graphene nanocomposites [J]. Mater. Des., 2018, 139: 181 |
| 29 | Chen Y K, Zhang X, Liu E Z, et al. Fabrication of in-situ grown graphene reinforced Cu matrix composites [J]. Sci. Rep., 2016, 6: 19363 |
| 30 | Yang Z Y, Wang L D, Cui Y, et al. High strength and ductility of graphene-like carbon nanosheet/copper composites fabricated directly from commercial oleic acid coated copper powders [J]. Nanoscale, 2018, 10: 16990 |
| 31 | Wang M, Wang L D, Sheng J, et al. Direct synthesis of high-quality graphene on Cu powders from adsorption of small aromatic hydrocarbons: A route to high strength and electrical conductivity for graphene/Cu composite [J]. J. Alloys Compd., 2019, 798: 403 |
| 32 | Yao G C, Mei Q S, Li J Y, et al. Cu/C composites with a good combination of hardness and electrical conductivity fabricated from Cu and graphite by accumulative roll-bonding [J]. Mater. Des., 2016, 110: 124 |
| 33 | Xiong D B, Cao M, Guo Q, et al. Graphene-and-copper artificial nacre fabricated by a preform impregnation process: Bioinspired strategy for strengthening-toughening of metal matrix composite [J]. ACS Nano, 2015, 9: 6934 |
| 34 | Xiong D B, Cao M, Guo Q, et al. High content reduced graphene oxide reinforced copper with a bioinspired nano-laminated structure and large recoverable deformation ability [J]. Sci. Rep., 2016, 6: 33801 |
| 35 | Yang Z Y, Wang L D, Shi Z D, et al. Preparation mechanism of hierarchical layered structure of graphene/copper composite with ultrahigh tensile strength [J]. Carbon, 2018, 127: 329 |
| 36 | Chu K, Wang X H, Wang F, et al. Largely enhanced thermal conductivity of graphene/copper composites with highly aligned graphene network [J]. Carbon, 2018, 127: 102 |
| 37 | Chu K, Wang X H, Li Y B, et al. Thermal properties of graphene/metal composites with aligned graphene [J]. Mater. Des., 2018, 140: 85 |
| 38 | Cao M, Xiong D B, Tan Z Q, et al. Aligning graphene in bulk copper: Nacre-inspired nanolaminated architecture coupled with in-situ processing for enhanced mechanical properties and high electrical conductivity [J]. Carbon, 2017, 117: 65 |
| 39 | Guo S, Zhang X, Shi C, et al. In situ synthesis of high content graphene nanoplatelets reinforced Cu matrix composites with enhanced thermal conductivity and tensile strength [J]. Powder Technol., 2020, 362: 126 |
| 40 | Zhang X, Shi C S, Liu E Z, et al. Achieving high strength and high ductility in metal matrix composites reinforced with a discontinuous three-dimensional graphene-like network [J]. Nanoscale, 2017, 9: 11929 |
| 41 | Chen Y K, Zhang X, Liu E Z, et al. Fabrication of three-dimensional graphene/Cu composite by in-situ CVD and its strengthening mechanism [J]. J. Alloys Compd., 2016, 688: 69 |
| 42 | Zhang X, Xu Y X, Wang M C, et al. A powder-metallurgy-based strategy toward three-dimensional graphene-like network for reinforcing copper matrix composites [J]. Nat. Commun., 2020, 11: 2775 |
| 43 | Qiao Z J, Zhou T, Kang J L, et al. Three-dimensional interpenetrating network graphene/copper composites with simultaneously enhanced strength, ductility and conductivity [J]. Mater. Lett., 2018, 224: 37 |
| 44 | Luo H B, Sui Y W, Qi J Q, et al. Copper matrix composites enhanced by silver/reduced graphene oxide hybrids [J]. Mater. Lett., 2017, 196: 354 |
| 45 | Zhu Y B, Bai H, Xue C, et al. Thermal conductivity and mechanical properties of a flake graphite/Cu composite with a silicon nano-layer on a graphite surface [J]. RSC Adv., 2016, 6: 98190 |
| 46 | Chu K, Wang J, Liu Y P, et al. Graphene defect engineering for optimizing the interface and mechanical properties of graphene/copper composites [J]. Carbon, 2018, 140: 112 |
| 47 | Zhang X, Shi C S, Liu E Z, et al. Effect of interface structure on the mechanical properties of graphene nanosheets reinforced copper matrix composites [J]. ACS Appl. Mater. Interfaces, 2018, 10: 37586 |
| 48 | Guo S Y, Zhang X, Shi C S, et al. Enhanced mechanical properties and electrical conductivity of graphene nanoplatelets/Cu composites by in situ formation of Mo2C nanoparticles [J]. Mater. Sci. Eng., 2019, A766: 138365 |
| 49 | Chu K, Wang F, Li Y B, et al. Interface structure and strengthening behavior of graphene/CuCr composites [J]. Carbon, 2018, 133: 127 |
| 50 | Zhang X, Zhao N Q, He C N. The superior mechanical and physical properties of nanocarbon reinforced bulk composites achieved by architecture design—A review [J]. Prog. Mater. Sci., 2020, 113: 100672 |
| 51 | Tian Y Z, Wu S D, Zhang Z F, et al. Microstructural evolution and mechanical properties of a two-phase Cu-Ag alloy processed by high-pressure torsion to ultrahigh strains [J]. Acta Mater., 2011, 59: 2783 |
| 52 | Shin S E, Choi H J, Shin J H, et al. Strengthening behavior of few-layered graphene/aluminum composites [J]. Carbon, 2015, 82: 143 |
| 53 | Kim W J, Lee T J, Han S H. Multi-layer graphene/copper composites: Preparation using high-ratio differential speed rolling, microstructure and mechanical properties [J]. Carbon, 2014, 69: 55 |
| 54 | Sun C, Zhang X, Zhao N Q, et al. Influence of spark plasma sintering temperature on the microstructure and strengthening mechanisms of discontinuous three-dimensional graphene-like network reinforced Cu matrix composites [J]. Mater. Sci. Eng., 2019, A756: 82 |
| 55 | Chu K, Wang F, Wang X H, et al. Anisotropic mechanical properties of graphene/copper composites with aligned graphene [J]. Mater. Sci. Eng., 2018, A713: 269 |
| 56 | Kim Y, Lee J, Yeom M S, et al. Strengthening effect of single-atomic-layer graphene in metal-graphene nanolayered composites [J]. Nat. Commun., 2013, 4: 2114 |
| 57 | Li Z, Wang H T, Guo Q, et al. Regain strain-hardening in high-strength metals by nanofiller incorporation at grain boundaries [J]. Nano Lett., 2018, 18: 6255 |
| 58 | Güler ?, Ba?c? N. A short review on mechanical properties of graphene reinforced metal matrix composites [J]. J. Mater. Res. Technol., 2020, 9: 6808 |
| 59 | Cao M, Xiong D B, Yang L, et al. Ultrahigh electrical conductivity of graphene embedded in metals [J]. Adv. Funct. Mater., 2019, 29: 1806792 |
| 60 | Salvo C, Mangalaraja R V, Udayabashkar R, et al. Enhanced mechanical and electrical properties of novel graphene reinforced copper matrix composites [J]. J. Alloys Compd., 2019, 777: 309 |
| 61 | Behera A K, Mallik A. Ultrasound assisted electroplating of nano-composite thin film of Cu matrix with electrochemically in-house synthesized few layer graphene nano-sheets as reinforcement [J]. J. Alloys Compd., 2018, 750: 587 |
| 62 | Chen F Y, Ying J M, Wang Y F, et al. Effects of graphene content on the microstructure and properties of copper matrix composites [J]. Carbon, 2016, 96: 836 |
| 63 | Kim S J, Shin D H, Choi Y S, et al. Ultrastrong graphene-copper core-shell wires for high-performance electrical cables [J]. ACS Nano, 2018, 12: 2803 |
| 64 | Shuai J, Xiong L Q, Zhu L, et al. Enhanced strength and excellent transport properties of a superaligned carbon nanotubes reinforced copper matrix laminar composite [J]. Composites, 2016, 88A: 148 |
| 65 | Zhang B B, Tao N R, Lu K. A high strength and high electrical conductivity bulk Cu-Ag alloy strengthened with nanotwins [J]. Scr. Mater., 2017, 129: 39 |
| 66 | Mao P Y, Qiao J X, Zhao Y, et al. Ultrahigh thermal stability of carbon encapsulated Cu nanograin on a carbon nanotube scaffold [J]. Carbon, 2021, 172: 712 |
| 67 | Lee H C, Jo M, Lim H, et al. Toward near-bulk resistivity of Cu for next-generation nano-interconnects: Graphene-coated Cu [J]. Carbon, 2019, 149: 656 |
| 68 | Ahn Y, Jeong Y, Lee D, et al. Copper nanowire-graphene core-shell nanostructure for highly stable transparent conducting electrodes [J]. ACS Nano, 2015, 9: 3125 |
| 69 | Boden A, Boerner B, Kusch P, et al. Nanoplatelet size to control the alignment and thermal conductivity in copper-graphite composites [J]. Nano Lett., 2014, 14: 3640 |
| 70 | Firkowska I, Boden A, Boerner B, et al. The origin of high thermal conductivity and ultralow thermal expansion in copper-graphite composites [J]. Nano Lett., 2015, 15: 4745 |
| 71 | Cao H J, Xiong D B, Tan Z Q, et al. Thermal properties of in situ grown graphene reinforced copper matrix laminated composites [J]. J. Alloys Compd., 2019, 771: 228 |
| 72 | Yang K M, Ma Y C, Zhang Z Y, et al. Anisotropic thermal conductivity and associated heat transport mechanism in roll-to-roll graphene reinforced copper matrix composites [J]. Acta Mater., 2020, 197: 342 |
| 73 | Cho S C, Kikuchi K, Kawasaki A. On the role of amorphous intergranular and interfacial layers in the thermal conductivity of a multi-walled carbon nanotube-copper matrix composite [J]. Acta Mater., 2012, 60: 726 |
| 74 | Kim K T, Eckert J, Liu G, et al. Influence of embedded-carbon nanotubes on the thermal properties of copper matrix nanocomposites processed by molecular-level mixing [J]. Scr. Mater., 2011, 64: 181 |
| 75 | Cho S C, Kikuchi K, Miyazaki T, et al. Multiwalled carbon nanotubes as a contributing reinforcement phase for the improvement of thermal conductivity in copper matrix composites [J]. Scr. Mater., 2010, 63: 375 |
| 76 | Chu K, Wu Q Y, Jia C C, et al. Fabrication and effective thermal conductivity of multi-walled carbon nanotubes reinforced Cu matrix composites for heat sink applications [J]. Compos. Sci. Technol., 2010, 70: 298 |
| 77 | He J S, Wang X T, Zhang Y, et al. Thermal conductivity of Cu-Zr/diamond composites produced by high temperature-high pressure method [J]. Composites, 2015, 68B: 22 |
| 78 | Bai G Z, Li N, Wang X T, et al. High thermal conductivity of Cu-B/diamond composites prepared by gas pressure infiltration [J]. J. Alloys Compd., 2018, 735: 1648 |
| 79 | Chang G, Sun F Y, Duan J L, et al. Effect of Ti interlayer on interfacial thermal conductance between Cu and diamond [J]. Acta. Mater., 2018, 160: 235 |
| 80 | Li J W, Zhang H L, Wang L H, et al. Optimized thermal properties in diamond particles reinforced copper-titanium matrix composites produced by gas pressure infiltration [J]. Composites, 2016, 91A: 189 |
/
| 〈 |
|
〉 |
