研究论文

高温时效对T23钢粗晶热影响区显微组织及再热裂纹敏感性的影响

  • 王学 ,
  • 李勇 ,
  • 王家庆 ,
  • 胡磊
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  • 1.安徽工业大学 先进金属材料绿色制备与表面技术教育部重点实验室 马鞍山 243032
    2.武汉大学 动力与机械学院 武汉 430072
    3.大唐锅炉压力容器检验中心有限公司 合肥 230088
王 学,男,1971年生,教授,博士

收稿日期: 2020-08-27

  修回日期: 2020-09-10

  网络出版日期: 2020-11-16

基金资助

国家自然科学基金项目(51574181);四川省科技计划项目(2018JY0668)

Effect of High Temperature Ageing on Microstructure and Stress-Relief Cracking Susceptibility of Coarse Grain Heat Affected Zone in T23 steel

  • Xue WANG ,
  • Yong LI ,
  • Jiaqing WANG ,
  • Lei HU
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  • 1.Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Ministry of Education, Anhui University of Technology, Ma'anshan 243032, China
    2.School of Power and Mechanics, Wuhan University, Wuhan 430072, China
    3.Da Tang Boiler Pressure Vessel Inspection Center Co. , Ltd. , Hefei 230088, China
WANG Xue, professor, Tel: 13554693820, E-mail: wangxue2011@whu.edu.cn

Received date: 2020-08-27

  Revised date: 2020-09-10

  Online published: 2020-11-16

Supported by

National Natural Science Foundation of China(51574181);Sichuan Science and Technology Program(2018JY0668)

摘要

利用热模拟机制备T23钢粗晶热影响区(CGHAZ)试样,对其进行650℃、0~48 h时效实验,对时效前后的试样进行高温短时蠕变破断实验,评价其再热裂纹敏感性,采用OM、SEM、TEM + EDS等手段分析CGHAZ在时效过程中的显微组织演变,对断口形貌及断口附近显微组织进行观察,分析合金元素在晶界附近的分布,揭示T23钢CGHAZ形成再热裂纹的机理,探究时效改善再热裂纹敏感性的原因。结果表明,T23钢CGHAZ在焊态下为马氏体/贝氏体混合组织,硬度较高;经650℃时效后组织发生回复及再结晶,位错密度下降,亚晶粒(板条)尺寸增大,M23C6M7C3MX碳(氮)化物等在晶内、晶界逐渐析出,硬度逐渐下降。焊态CGHAZ对再热裂纹敏感,时效后CGHAZ的再热裂纹敏感性下降;当时效时间超过24 h时,对再热裂纹不敏感。焊态CGHAZ产生再热裂纹主要是由于M23C6在晶界析出长大,导致晶界形成软化区,并促进孔洞的形成,减弱了晶间结合力。时效使不稳定的CGHAZ组织发生预先转变,碳化物大量析出,基体发生回复与再结晶,降低了晶内强度,同时晶界附近合金元素贫化消除,晶内和晶界强度的差异减小,塑性变形能力明显提升,故再热裂纹敏感性降低。CGHAZ时效后的硬度与再热裂纹敏感性有一定的对应关系,当硬度高于250 HB时对再热裂纹敏感,硬度低于250 HB时对再热裂纹不敏感。

本文引用格式

王学 , 李勇 , 王家庆 , 胡磊 . 高温时效对T23钢粗晶热影响区显微组织及再热裂纹敏感性的影响[J]. 金属学报, 2021 , 57(6) : 736 -748 . DOI: 10.11900/0412.1961.2020.00331

Abstract

Owing to its high creep rupture strength, good weldability, and low costs, T23 steel is an ideal material for manufacturing the heating components of water walls, superheaters and reheaters in ultra-super critical plants. However, its coarse grain heat affected zone (CGHAZ) is prone to stress-relief cracking (SRC) during post-weld heat treatment or high-temperature service. The mechanism of SRC is controversial and an effective method for forecasting and preventing SRC in T23 components is currently lacking. Clarifying the mechanism of SRC in the CGHAZ of T23 steel, and developing a practical engineering technique for predicting and preventing SRC generation, are therefore essential. In this work, CGHAZ specimens of T23 steel were simulated in a thermo-mechanical simulator, and aged at 650oC for 0-48 h. After simulating the microstructure evolution of the as-welded CGHAZ during service, the SRC susceptibility of the CGHAZ was evaluated. The microstructural changes and carbide precipitation were observed by OM, SEM, TEM, and EDS. The as-welded CGHAZ of T23 steel was composed of mixed martensite and bainite with high hardness. After ageing at 650oC, the structure recovered and recrystallized with a lower dislocation density and larger sub-grains than the as-welded CGHAZ. Carbides such as M23C6, M7C3, and MX gradually precipitated inside the grains and grain boundaries, decreasing the hardness. The SRC susceptibility was high in the as-welded CGHAZ, but decreased with increasing ageing time. When the ageing time exceeded 24 h, the sample was SRC-resistant. The main cause of SRC in the CGHAZ was precipitation and growth of M23C6 on the grain boundaries, which induced the formation of softened zones in the matrix near the grain boundary, and promoted the formation of micro-voids. During ageing, the unstable microstructure in the as-welded CGHAZ transformed as carbides precipitated and the matrix recrystallized, thereby reducing the intragranular strength. Meanwhile, the depletion of alloy elements near the grain boundary was eliminated. The microstructural evolution decreased the difference between the intragranular and intergranular strengths in the CGHAZ. Finally, the CGHAZ showed significantly improved ductility and low SRC susceptibility. The hardness of the aged CGHAZ was positively related to the SRC susceptibility. At hardnesses above 250 HB, the CGHAZ was SRC-susceptible, but at hardnesses below 250 HB, the CGHAZ was SRC-resistant.

参考文献

1 Bendick W, Gabrel J, Hahn B, et al. New low alloy heat resistant ferritic steels T/P23 and T/P24 for power plant application [J]. Int. J. Pressure Vessels Pip., 2007, 84: 13
2 Arndt J, Haarmann K, Kottmann G, et al. The T23/T24 Book-New Grades for Waterwalls and Superheaters [M]. Vallourec & Mannesmann Tubes, 1998: 24
3 Igarashi M, Yoshizawa M, Matsuo H, et al. Long-term creep properties of low C-2.25Cr-1.6W-V-Nb steel (T23/P23) for fossil fired and heat recovery boilers [J]. Mater. Sci. Eng., 2009, A510-511: 104
4 Kucharova K, Sklenicka V, Kvapilova M, et al. Creep and microstructural processes in a low-alloy 2.25%Cr1.6%W steel (ASTM Grade 23) [J]. Mater. Charact., 2015, 109: 1
5 Vaillant J C, Vandenberghe B, Hahn B, et al. T/P23, 24, 911 and 92: New grades for advanced coal-fired power plants—Properties and experience [J]. Int. J. Pressure Vessels Pip., 2008, 85: 38
6 Yang F, Zhang Y L, Ren Y N, et al. Welding of New Type Heat-resistant Steels [M]. Beijing: China Electric Power Press, 2006: 79
6 杨 富, 章应霖, 任永宁等. 新型耐热钢焊接 [M]. 北京: 中国电力出版社, 2006: 79
7 Wang X, Xu D L, Chen Y C, et al. The reheat cracking susceptibility of T23 (7CrWVMoNb9-6) steel [J]. Mater. Sci. Technol., 2009, 17(): 172
7 王 学, 徐德录, 陈玉成等. T23钢再热裂纹敏感性 [J]. 材料科学与工艺, 2009, 17(): 172
8 Zhang B, Gao Z Y, Wang D T, et al. Tests studies on HCM2S steel's susceptibility to reheat cracking [J]. J. Power Eng., 2006, 26: 300
8 张 波, 高子瑜, 王德泰等. HCM2S钢再热裂纹敏感性的试验研究 [J]. 动力工程, 2006, 26: 300
9 Dhooge A, Vekeman J. New generation 21/4Cr steels T/P 23 and T/P 24 weldability and high temperature properties [J]. Weld. World, 2005, 49: 75
10 Nawrocki J G, Dupont J N, Robino C V, et al. The stress-relief cracking susceptibility of a new ferritic steel—Part 1: Single-pass heat-affected zone simulations [J]. Weld. J., 2000, 79: 355s
11 Long H G, Long Y, Chen H D. Mechanism of T23/12Cr1MoV dissimilar steel welding failure in high temperature reheater [J]. Electr. Power, 2011, 44(5): 70
11 龙会国, 龙 毅, 陈红冬. 高温再热器T23/12Cr1MoV异种钢焊缝失效机理 [J]. 中国电力, 2011, 44(5): 70
12 Hippsley C A, Knott J F, Edwards B C. A study of stress relief cracking in 214Cr 1 Mo steel—I. The effects of P segregation [J]. Acta Metall., 1980, 28: 869
13 Shin J, McMahon C J. Mechanisms of stress relief cracking in a ferritic steel[J]. Acta Metall., 1984, 32: 1535
14 Kanazawa S, Yamato K, Takeda T, et al. Study of reheat cracking in weldment (report 2): Relation between cracking susceptibility and some properties of HAZ at high temperature [J]. Trans. Jpn. Weld. Soc., 1977, 8: 119
15 Magula V, Grman D, Patscheider J. Segregation of impurities on grain boundaries in tests of resistance to “reheat and underclad” cracking [J]. Scr. Mater., 1997, 37: 1811
16 Tamaki K, Suzuki J, Tajiri M. Effect of Vanadium and Titanium on reheat cracking sensitivity: Study of reheat cracking of Cr-Mo steels (report 4) [J]. Trans. Jpn. Weld. Soc., 1984, 15: 17
17 Ito Y, Nakanishi M. Study on stress relief cracking in welded low alloy steels (report 1): The investigation of the condition under which stress relief cracking may occur [J]. J. Jpn. Weld. Soc., 1971, 40: 1261
18 Balaguer J P, Wang Z, Nippes E F. Stress-relief cracking of a copper-containing HSLA steel [J]. Weld. J., 1989, 68: 121s
19 Ito Y, Nakanishi M. Study on stress relief cracking in welded low alloy steels (report 2): The investigation of stress relief cracking susceptibility on low alloy steels [J]. J Jpn. Weld. Soc., 1972, 41: 59
20 Nawrocki J G, Dupont J N, Robino C V, et al. The mechanism of stress-relief cracking in a ferritic alloy steel [J]. Weld. J., 2003, 82(2): 25s
21 Li Y, Wang X, Wang J Q, et al. Stress-relief cracking mechanism in simulated coarse-grained heat-affected zone of T23 steel [J]. J. Mater. Process. Technol., 2019, 266: 73
22 Pilling J, Ridley N. Tempering of 2.25 Pct Cr-1 Pct Mo low carbon steels [J]. Metall. Trans., 1982, 13A: 557
23 Yu Z S, Nie M, Hou S F, et al. The carbide contained in HCM2S (T23) steel and evolution regularity thereof [J]. Therm. Power Gener., 2012, 41(9): 1
23 于在松, 聂 铭, 侯淑芳等. HCM2S(T23)钢中的碳化物及其演化规律 [J]. 热力发电, 2012, 41(9): 1
24 Zieliński A, Golański G, Sroka M, et al. Microstructure and mechanical properties of the T23 steel after long-term ageing at elevated temperature [J]. Mater. High Temp., 2016, 33: 154
25 Miyata K, Igarashi M, Sawaragi Y. Effect of trace elements on creep properties of 0.06C-2.25Cr-1.6W-0.1Mo-0.25V-0.05Nb steel [J]. ISIJ Int., 1999, 39: 947
26 Morito S, Yoshida H, Maki T, et al. Effect of block size on the strength of lath martensite in low carbon steels [J]. Mater. Sci. Eng., 2006, A438-440: 237
27 Anderson T L. Fracture Mechanics: Fundamentals and Applications [M]. 4th Ed., New York: CRC Press, 2017: 233
28 Cane B J, Middleton C J. Intergranular creep-cavity formation in low-alloy bainitic steels [J]. Met. Sci., 1981, 15: 295
29 Qian Z P. Deformation and Fracture of Materials [M]. Shanghai: Tongji University Press, 1989: 139
29 钱志屏. 材料的变形与断裂 [M]. 上海: 同济大学出版社, 1989: 139
30 Yin Y F, Faulkner R G. Model predictions of grain boundary chromium depletion in Inconel 690 [J]. Corros. Sci., 2007, 49: 2177
31 Chen B, Hao X C, Ma Y C, et al. Effects of nitrogen addition on microstructure and grain boundary microchemistry of Inconel alloy 690 [J]. Acta Metall. Sin., 2017, 53: 983
31 陈 波, 郝宪朝, 马颖澈等. 添加N对Inconel 690合金显微组织和晶界微区成分的影响 [J]. 金属学报, 2017, 53: 983
32 Wang X, Li X Q, Yang C, et al. Aging properties of T23 weld joint in water wall of USC boilers [J]. J. Chin. Soc. Power Eng., 2015, 35: 325
32 王 学, 李夕强, 杨 超等. 超超临界锅炉水冷壁T23接头时效性能 [J]. 动力工程学报, 2015, 35: 325
33 Mohyla P, Foldyna V. Improvement of reliability and creep resistance in advanced low-alloy steels [J]. Mater. Sci. Eng., 2009, A510-511: 234
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