热轧变形量对高钛耐磨钢组织与力学性能的影响

  • 许帅 ,
  • 孙新军 ,
  • 梁小凯 ,
  • 刘俊 ,
  • 雍岐龙
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  • 1 钢铁研究总院工程用钢研究所 北京 100081
    2 江阴兴澄特种钢铁有限公司 江阴 214400
许 帅,男,1995年生,硕士生

收稿日期: 2020-04-17

  修回日期: 2020-06-18

  网络出版日期: 2020-07-06

基金资助

国家重点研发计划项目(2017YFB0305100)

Effect of Hot Rolling Deformation on Microstructure and Mechanical Properties of a High-Ti Wear-Resistant Steel

  • Shuai XU ,
  • Xinjun SUN ,
  • Xiaokai LIANG ,
  • Jun LIU ,
  • Qilong YONG
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  • 1 Department of Structural Steels, Central Iron & Steel Research Institute, Beijing 100081, China
    2 Jiangyin Xingcheng Special Steel Co., Ltd., Jiangyin 214400, China

Received date: 2020-04-17

  Revised date: 2020-06-18

  Online published: 2020-07-06

Supported by

National Key Research and Development Program of China(2017YFB0305100)

摘要

通过不同总压缩比的实验室热轧、微观组织和析出相表征及力学性能测试等实验,研究了热轧变形量对经过轧后热处理的高钛耐磨钢组织和力学性能的影响。随着轧制变形量的增大,高钛耐磨钢的强度、韧性和塑性均有提高:屈服强度、抗拉强度和总延伸率从压缩比为3∶1时的1202 MPa、1437 MPa和7.4%分别提高到压缩比为30∶1时的1311 MPa、1484 MPa和9.9%,而室温Charpy冲击功从压缩比为3∶1时的11 J大幅提高到压缩比为10∶1时的24 J。随着轧制变形量增大,铸态析出的微米级网状TiC逐渐细化和均匀化,同时尺寸小于15 nm的TiC颗粒占比增加,热处理后的原奥氏体晶粒尺寸则不断减小。通过对高钛耐磨钢各种强化方式的定量分析表明,采用沉淀强化和位错强化均方根叠加方式计算得到的高钛耐磨钢屈服强度与实测值吻合较好,高钛耐磨钢屈服强度随轧制压缩比增加而上升主要是由于晶界强化和沉淀强化作用增加所致。高钛耐磨钢的韧性和塑性随强度的提高不降反升,主要是因为大颗粒TiC在轧制变形过程中发生细化和均匀化。

本文引用格式

许帅 , 孙新军 , 梁小凯 , 刘俊 , 雍岐龙 . 热轧变形量对高钛耐磨钢组织与力学性能的影响[J]. 金属学报, 2020 , 56(12) : 1581 -1591 . DOI: 10.11900/0412.1961.2020.00124

Abstract

To improve the wear performance of steel without increasing its hardness, a high-Ti wear-resistant steel was reinforced with TiC particles. The effects of hot rolling deformation on the microstructure and mechanical properties of the wear-resistant steel containing 0.61%Ti after quenching and tempering were studied in hot rolling experiments with different reduction ratios. The steel products were subjected to microstructure and precipitate characterization and mechanical-property tests. Increasing the rolling deformation improved the strength, toughness, and plasticity of the tested steel. The yield strength, tensile strength, and total elongation were increased from 1202 MPa, 1437 MPa, and 7.4%, respectively, at a reduction ratio of 3∶1 to 1311 MPa, 1484 MPa, and 9.9%, respectively, at a reduction ratio of 30∶1. Meanwhile, increasing the reduction ratio from 3∶1 to 10∶1 remarkably increased the absorbed energy at room temperature (obtained in a Charpy impact test) from 11 J to 24 J. As the rolling deformation increased, the micron-sized net-like TiC particles that precipitated during solidification were gradually refined and homogenized, and the prior austenite grain size was also refined. Next, the strengthening mechanisms of the steel were quantitatively analyzed. The yield strength, calculated by adding the root mean squares of the dislocation and precipitate strengthening values, well agreed with the measured yield strength. The increasing yield strength of the tested steel at higher rolling reduction ratios is mainly attributable to increased grain-boundary strengthening and precipitation strengthening. As the strength of the steel increased, the toughness and plasticity also increased, mainly because the large TiC particles were refined and homogenized during the rolling deformation.

参考文献

[1] Deng X T, Wang Z D, Han Y, et al. Microstructure and abrasive wear behavior of medium carbon low alloy martensitic abrasion resistant steel [J]. J. Iron Steel Res. Int., 2014, 21: 98
[2] Zhang K, Yong Q L, Sun X J, et al. Effect of tempering temperature on microstructure and mechanical properties of high Ti microalloyed directly quenched high strength steel [J]. Acta Metall. Sin., 2014, 50: 913
[2] (张 可, 雍岐龙, 孙新军等. 回火温度对高Ti微合金直接淬火高强钢组织及性能的影响 [J]. 金属学报, 2014, 50: 913)
[3] Lindroos M, Valtonen K, Kemppainen A, et al. Wear behavior and work hardening of high strength steels in high stress abrasion [J]. Wear, 2015, 322-323: 32
[4] Bressan J D, Daros D P, Sokolowski A, et al. Influence of hardness on the wear resistance of 17-4 PH stainless steel evaluated by the pin-on-disc testing [J]. J. Mater. Process. Technol., 2008, 205: 353
[5] Ojala N, Valtonen K, Heino V, et al. Effects of composition and microstructure on the abrasive wear performance of quenched wear resistant steels [J]. Wear, 2014, 317: 225
[6] Srivastava A K, Das K. Microstructure and abrasive wear study of (Ti,W)C-reinforced high-manganese austenitic steel matrix composite [J]. Mater. Lett., 2008, 62: 3947
[7] Ni Z F, Sun Y S, Xue F, et al. Evaluation of electroslag remelting in TiC particle reinforced 304 stainless steel [J]. Mater. Sci. Eng., 2011, A528: 5664
[8] Xu L J, Xing J D, Wei S Z, et al. Study on relative wear resistance and wear stability of high-speed steel with high vanadium content [J]. Wear, 2007, 262: 253
[9] Liu L J. TiC precipitation behavior and its effect on properties in high titanium and high wear-resistant steels [D]. Beijing: Central Iron & Steel Research Institute, 2019
[9] (刘罗锦. 高钛高耐磨钢中TiC析出行为及对性能的影响 [D]. 北京: 钢铁研究总院, 2019)
[10] Sun X J, Liu L J, Liang X K, et al. TiC precipitation behavior and its effect on abrasion resistance of high titanium wear-resistant steel [J]. Acta Metall. Sin., 2020, 56: 661
[10] (孙新军, 刘罗锦, 梁小凯等. 高钛耐磨钢中TiC析出行为及其对耐磨粒磨损性能的影响 [J]. 金属学报, 2020, 56: 661)
[11] Liu L J, Liang X K, Liu J, et al. Precipitation process of TiC in low alloy martensitic steel and its effect on wear resistance [J]. ISIJ Int., 2020, 60: 168
[12] Jang J H, Lee C H, Heo Y U, et al. Stability of (Ti, M)C (M=Nb, V, Mo and W) carbide in steels using first-principles calculations [J]. Acta Mater., 2012, 60: 208
[13] Yu H L. Evolution behavior of cracks and inclusions in slab during rolling [D]. Shenyang: Northeastern University, 2008
[13] (喻海良. 轧制过程中轧件裂纹和夹杂物演变行为研究 [D]. 沈阳: 东北大学, 2008)
[14] Weng Y Q. Ultra-Fine Grained Steels [M]. Beijing: Metallurgical Industry Press, 2003: 1
[14] (翁宇庆. 超细晶钢 [M]. 北京: 冶金工业出版社, 2003: 1)
[15] Liang X K, Sun X J, Yong Q L, et al. Precipitation of TiC in high Ti steel [J]. J. Iron Steel Res., 2016, 28(9): 71
[15] (梁小凯, 孙新军, 雍岐龙等. 高钛钢中TiC析出机制 [J]. 钢铁研究学报, 2016, 28(9): 71)
[16] Yong Q L. Secondary Phases in Steels [M]. Beijing: Metallurgical Industry Press, 2006: 1
[16] (雍岐龙. 钢铁材料中的第二相 [M]. 北京: 冶金工业出版社, 2006: 1)
[17] Gladman T. Precipitation hardening in metals [J]. Mater. Sci. Technol., 1999, 15: 30
[18] Cooman B C, Speer J G. Strengthening Mechanisms [M]. Warrendale: Fundamentals of Steel Product Metallurgy, 2011: 270
[19] Kennett S C, Krauss G, Findley K O. Prior austenite grain size and tempering effects on the dislocation density of low-C Nb-Ti microalloyed lath martensite [J]. Scr. Mater., 2015, 107: 123
[20] Klemm-Toole J, Benz J, Thompson S W, et al. A quantitative evaluation of microalloy precipitation strengthening in martensite and bainite [J]. Mater. Sci. Eng., 2019, A763: 138145
[21] Akbary F H, Sietsma J, B?ttger A J, et al. An improved X-ray diffraction analysis method to characterize dislocation density in lath martensitic structures [J]. Mater. Sci. Eng., 2015, A639: 208
[22] Morito S, Nishikawa J, Maki T. Dislocation density within lath martensite in Fe-C and Fe-Ni alloys [J]. ISIJ Int., 2003, 43: 1475
[23] Kehoe M, Kelly P M. The role of carbon in the strength of ferrous martensite [J]. Scr. Metall., 1970, 4: 473
[24] Kobayashi Y, Takahashi J, Kawakami K. Experimental evaluation of the particle size dependence of the dislocation-particle interaction force in TiC-precipitation-strengthened steel [J]. Scr. Mater., 2012, 67: 854
[25] Petch N J. The cleavage strength of polycrystals [J]. J. Iron Steel Inst., 1953, 174: 25
[26] Petch N J. The ductile-brittle transition in the fracture of α-iron: I [J]. Philos. Mag., 1958, 34: 1089
[27] Wang C F. Study on structure control unit of strength and toughness of low alloy martensitic steel [D]. Beijing: Central Iron & Steel Research Institute, 2008
[27] (王春芳. 低合金马氏体钢强韧性组织控制单元的研究 [D]. 北京: 钢铁研究总院, 2008)
[28] Kocks U F. Superposition of alloy hardening, hardening strain, and dynamic recovery [A]. Proc. 5th Int. Conf. Strength of Metals and Alloys [C]. Oxford: Peramon Press, 1979: 1661
[29] Ashby M F. The deformation of plastically non-homogeneous materials [J]. Philos. Mag., 1970, 21: 399
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