双轴肩搅拌摩擦焊对6061-T6铝合金表面组织及其在3.5%NaCl中腐蚀行为的影响*

  • 乔岩欣 ,
  • 周洋 ,
  • 陈书锦 ,
  • 宋亓宁
展开
  • 1 江苏科技大学材料科学与工程学院, 镇江 212003
    2 河海大学机电工程学院, 常州 213022

收稿日期: 2016-01-13

  网络出版日期: 2016-08-18

基金资助

* 国家自然科学基金项目51401092和51575252以及51205175和江苏科技大学博士基金资助

EFFECT OF BOBBIN TOOL FRICTION STIR WELDING ON MICROSTRUCTURE AND CORROSION BEHAVIOR OF 6061-T6 ALUMINUM ALLOY JOINT IN 3.5%NaCl SOLUTION

  • Yanxin QIAO ,
  • Yang ZHOU ,
  • Shujin CHEN ,
  • Qining SONG
Expand
  • 1 School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China 2 School of Mechanical and Electrical Engineering, Hohai University, Changzhou 213022, China

Received date: 2016-01-13

  Online published: 2016-08-18

Supported by

Supported by National Natural Science Foundation of China (Nos.51401092, 51575252 and 51205175)

摘要

采用双轴肩搅拌摩擦焊(BTFSW)技术对7.8 mm厚6061-T6铝合金进行了焊接, 对焊接接头各部分的微观组织和截面显微硬度进行了分析, 并对母材和焊核在3.5%NaCl溶液中的腐蚀电化学行为和腐蚀产物膜进行了研究. 结果表明, BTFSW后焊缝表面质量良好, 热-机影响区晶粒发生再结晶和塑性变形, 部分再结晶晶粒发生了伸长和弯曲; 热影响区的部分晶粒在热循环的作用下发生粗化, 焊核呈细小的等轴晶组织; 焊接接头中前进侧热-机影响区硬度最低; 在3.5%NaCl溶液中, 6061-T6铝合金的极化曲线表现为阳极溶解和点蚀, 母材和焊核区的电化学阻抗谱均由容抗弧和感抗弧组成, BTFSW后6061铝合金的腐蚀电流降低; 浸泡480 h后, 呈疖状腐蚀的特征, 腐蚀产物为Al(OH)3和Al2O3. BTFSW可提高6061-T6铝合金的耐蚀性.

本文引用格式

乔岩欣 , 周洋 , 陈书锦 , 宋亓宁 . 双轴肩搅拌摩擦焊对6061-T6铝合金表面组织及其在3.5%NaCl中腐蚀行为的影响*[J]. 金属学报, 2016 , 52(11) : 1395 -1402 . DOI: 10.11900/0412.1961.2016.00026

Abstract

Friction stir welding (FSW) is a new solid-state joining method which offers several advantages compared with conventional welding methods, including better mechanical properties, lower residual stress and reduced occurrence of defects. It has already been used for joining Al alloys in the aerospace and automotive industries. In spite of the advantages, FSW also has drawbacks, such as the risk of root flaws in single-side welds. Using a bobbin tool instead is a promising way to solve this problem since the root region is avoided. Compared with standard (single-side) FSW techniques, the bobbin tool FSW has an extra shoulder attached to the tip of the probe, namely the lower shoulder. This setup makes BTFSW capable of joining closed profiles like hollow extrusions. Furthermore, root flaws, such as lack of penetration, which occasionally occurred in standard FSWtechiques, can be completely avoided. In this work, 6061-T6 aluminum alloy was welded by using bobbin tool friction stir weld (BTFSW). The influence of BTFSW on the microstructure development and hardness distribution in the weldment has been investigated. The corrosion behaviors of the base metal and weld nugget in 3.5%NaCl (mass fraction) solution were investigated using SEM, XRD and electrochemical measurements. The results showed that the weld surface of 6061-T6 welded by BTFSW is of good quality. No welding defect was detected in the joints. Three microstructural zones, i.e., nugget zone, thermo-mechanically affected zone, and heat affected zone were discernible. The microstructural analysis indicates that the weld nugget region exhibited fine and equiaxed grain structure with an average grain size of ~8 μm, indicating the occurrence of dynamic recrystallization due to severe plastic deformation and thermal exposure. The thermo-mechanically affected zone underwent plastic deformation and recrystallization occured in this zone due to deformation strain and thermal input. The low hardness zone, determined by constructing the hardness distribution profile on cross-section of joint, located at thermo-mechanically affected zone of advancing side. Although 6061-T6 alloys are readily weldable, they suffered from severe softening in the heat affected zone because of the dissolution of Mg2Si precipitates during the weld thermal cycle. BTFSW can improve the corrosion resistance of 6061-T6 aluminum alloy in 3.5%NaCl solution. The corrosion behavior results showed that both anodic dissolution and pitting were observed after the immersion test due to the inhomogeneous microstructure of 6061-T6 aluminum alloy. The corrosion products mainly composed of Al(OH)3 and Al2O3. Furthermore, the corrosion process and mechanism were also discussed.

参考文献

[1] Marzoli L M, Strombeck A V, Santos J F D, Gambaro C, Volpone L M.Compos Sci Technol, 2006; 66: 363
[2] Hong S J, Kim S S, Lee C G, Kim S J.Scr Mater, 2006; 55: 1007
[3] Zhao Y, Fu J, Zhang P L, Yan K, Jiang C Y.J Jiangsu Univ Sci Technol (Nat Sci Ed), 2006; 20(1): 90
[3] (赵勇, 付娟, 张培磊, 严铿, 蒋成禹. 江苏科技大学学报(自然科学版), 2006; 20(1): 90)
[4] Tong J H, Li L, Deng D, Wan F R.J Univ Sci Technol Beijing, 2008; 30: 1011
[4] (佟建华, 李炼, 邓冬, 万发荣. 北京科技大学学报, 2008; 30: 1011)
[5] Wang D, Wang Q Z, Xiao B L, Ni D R, Ma Z Y.Acta Metall Sin, 2014; 50: 489
[5] (王东, 王全兆, 肖伯律, 倪丁瑞, 马宗义. 金属学报, 2014; 50: 489)
[6] Liu F J, Fu L, Zhang W Y, Meng Q, Dong C L, Luan G H.Acta Metall Sin, 2015; 51: 281
[6] (刘奋军, 傅莉, 张纹源, 孟强, 董春林, 栾国红. 金属学报, 2015; 51: 281)
[7] Somasekharan A C, Murr L E.Mater Charact, 2004; 53: 19
[8] Xu W F, Liu J H, Chen D L.Acta Metall Sin, 2015; 51: 587
[8] (徐韦锋, 刘金合, CHEN Daolun. 金属学报, 2015; 51: 587)
[9] Ren S R, Ma Z Y, Chen L Q, Zhang Y Z.Acta Metall Sin, 2007; 43: 225
[9] (任淑荣, 马宗义, 陈礼清, 张玉政. 金属学报, 2007; 43: 225)
[10] Yan D Y, Shi Q Y, Wu A P, Juergen S, Liu Y, Zhang Z L.Acta Metall Sin, 2009; 45: 183
[10] (鄢东洋, 史清宇, 吴爱萍, Juergen Silvanus, 刘园, 张增磊. 金属学报, 2009; 45: 183)
[11] Xu W F, Liu J H, Luan G H, Dong C L.Acta Metall Sin, 2009; 45: 490
[11] (徐韦锋, 刘金合, 栾国红, 董春林. 金属学报, 2009; 45: 490)
[12] Liu H J, Fujii H, Maeda M, Nogi K.J Mater Sci Lett, 2003; 22: 1061
[13] Hilgert J, Schmidt H N B, dos Santos J F, Huber N.J Mater Process Technol, 2011; 211: 197
[14] Sued M K, Pons D, Lavroff J, Wong E H.D.Mater Des, 2014; 54: 632
[15] Paglia C S, Buchheit R G.Scr Mater, 2008; 58: 383
[16] Lafly A-L, Allehaux D, Marie F, Donne C D, Doker H.J Int Inst Weld, 2005; 49: 444
[17] Chen Y C, Nakata K.Mater Des, 2009; 30: 469
[18] Kumbhar N T, Sahoo S K, Samajdar I, Dey G K,Mater Des, 2011; 32: 1657
[19] Thomas W M, Wiesner C S, Marks D J, Staines D G.Sci Technol Weld Joining, 2009; 14: 247
[20] Corral J, Trillo E A, Li Y, Murr L E.J Mater Sci Lett, 2002; 19: 2117
[21] Gharavi F, Matoria K, Yunus R, Othman N, Fadaeifard F.J Mater Res Technol, 2015; 4: 314
[22] Emilie B, Angéline P Q, Monique P, Olivier D, Marie T.Corros Sci, 2011; 53: 3026
[23] Kang J, Fu R D, Luan G H, Dong C L, He M.Corros Sci, 2010; 52: 620
[24] Gupta R K, Das H, Pal T K.J Mater Eng Perform, 2012; 21: 1645
[25] Feng A H, Chen D L, Ma Z Y.Metall Mater Trans, 2010; 41A: 2626
[26] Yutaka S S, Mitsunori U, Hiroyuki Ka, Keisuke I.Mater Sci Eng, 2003; A354: 298
[27] Elangovan K, Balasubramanian V.Mater Des, 2008; 29: 362
[28] Liu F C, Ma Z Y.Metall Mater Trans, 2008; 39A: 2378
[29] Rajesh K G, Hrishikesh D, Tapan K P.J Mater Eng Perform, 2012; 21: 1645
[30] Zhou K, Wang B, Zhao Y, Liu J.Trans Nonferrous Met Soc China, 2015; 25: 2509
[31] Wang X H, Wang J H, Fu C W.Trans Nonferrous Met Soc China, 2014; 24: 3907
[32] Singh A K, Quraishi M A.Corros Sci, 2010; 52: 152
[33] Pardo A, Merino M C, Coy A E, Viejo F, Jr Arrabal R S F.Electrochim Acta, 2008; 53: 7890
[34] He J G, Wen J B, Li X D.Corros Sci, 2011; 53: 1948
[35] Ghods P, Isgor O B, McRae G A, Li J, Gu G P.Corros Sci, 2011; 53: 946
[36] Chen J, Wang J Q, Han E-H, Dong J H, Ke W.Electrochim Acta, 2007; 52: 3299
[37] Tan L, Allen T R.Corros Sci, 2010; 52: 548
[38] Yasakau K A.Electrochim Acta, 2007; 52: 7651
[39] Zhang J, Zhang T, Shao Y W, Meng G Z, Wang F H.Corros Sci Prot Technol, 2014; 26: 125
[39] (张晋, 张涛, 邵亚薇, 孟国哲, 王福会. 腐蚀科学与防护技术, 2014; 26: 125)
[40] Sun F L, Li X G, Lu L, Cheng X Q, Dong C F, Gao J.Acta Metall Sin, 2013; 49: 1219
[40] (孙飞龙, 李晓刚, 卢琳, 程学群, 董超芳, 高瑾. 金属学报, 2013; 49: 1219)
[41] Seetharaman R, Ravisankar V, Balasubramanian V.Trans Nonferrous Met Soc China, 2015; 25: 1427
[42] Voskov A L, Voronin G F.Russ J Phys Chem, 2010; 80A: 6105
[43] Nady H, Helal N H, El-Rabiee M M, Badawy W A.Mater Chem Phys, 2012; 134: 945
文章导航

/