Al-20Mg合金高压凝固力学性能研究*
接金川, 男, 1981年生, 博士
收稿日期: 2013-11-25
修回日期: 2014-03-15
网络出版日期: 2014-08-25
基金资助
* 国家自然科学基金项目 51171054和51001041及博士后科学基金项目2013M530913资助
MECHANICAL BEHAVIOR OF Al-20Mg ALLOY SOLIDIFIED UNDER HIGH PRESSURE
Received date: 2013-11-25
Revised date: 2014-03-15
Online published: 2014-08-25
Supported by
Supported by National Natural Science Foundation of China (Nos.51171054 and 51001041) and China Postdoctoral Science Foundation (No.2013M530913)
将Al-20Mg合金在不同压力下凝固, 采用OM, XRD以及拉伸实验对合金凝固后的物相组织及力学性能进行研究. 结果表明, 随着凝固压力的升高, Mg元素在Al基体中的固溶度提高, 当凝固压力为2 GPa时, Al-20Mg合金转变成为过饱和固溶体, 其力学性能显著提高, 合金的抗拉强度提高到474.8 MPa, 是常压凝固之后合金抗拉强度的8.9倍, 屈服强度达到232.8 MPa, 延伸率也达到11.1%. 当凝固压力增加到3 GPa时, 合金的屈服强度有所下降, 这是由于更高压力下凝固后Mg在固溶体中的均匀分布会降低合金的力学性能. 高压凝固后Al-20Mg合金的断裂机制由常压下的解理断裂转变为高压下的韧性断裂.
接金川 , 邹鹑鸣 , 王宏伟 , 魏尊杰 . Al-20Mg合金高压凝固力学性能研究*[J]. 金属学报, 2014 , 50(8) : 971 -978 . DOI: 10.11900/0412.1961.2013.00767
Pressure is, like temperature, a basic thermodynamic variable which can be used to alter the matter state. The atom volume, free energy of matter and other physical and chemical properties can be changed due to the application of high pressure. Many interesting materials including superconducting, super-hard, amorphous, nano-materials can be prepared under high pressures. Meanwhile, the application of high pressure during solidification of metallic materials has also attracted much attention of researchers in recent years. However, the understanding of high pressure on alloy solidification behavior is still lacked, and needs more experimental and theoretical investigation. In the present work, the effect of high pressure on solidification microstructure, phase constitution and mechanical properties of Al-20Mg alloy was investigated by OM, XRD and tensile test. Influence of solute distribution on mechanical properties of solid solution was analyzed and the corresponding mechanism was discussed based on the solute strengthening theory. The results showed that the amount of intermetallic compound b-Al3Mg2 decreases and the amount of Al(Mg) solid solution increases in the Al-20Mg alloy solidified under high pressure, resulting in the remarkable enhancement of the mechanical properties. The Al-20Mg alloy is fragile under 1.0×105 Pa. However, it can transform to be a ductile material with elongation of 11% when solidified under 2 and 3 GPa. Meanwhile, its strength can be also greatly improved. The ultimate tensile strength of Al-20Mg alloy solidified under 2 GPa is 8.9 times of that solidified under 1.0×105 Pa. The yield strength of Al-20Mg alloy solidified under 2 GPa is higher than that under 3 GPa. This phenomenon was explained by solute strengthening theory, and proved that the inhomogeneous distribution of Mg solute in the solid solution can enhance the mechanical properties. The fracture characteristic is essentially altered under the condition of high pressure solidification. The Al-20Mg alloy is cleavage fracture under 105 Pa, however, it transforms to the dimple fracture when solidified under 2 and 3 GPa. The present work provides a potential route to improve the mechanical properties of solid solution through the control of solute distribution in the solid solution.
| [1] | Mcmillan P F. Nat Mater, 2002; 1: 19 |
| [2] | Sharma S M, Sikka S K. Prog Mater Sci, 1996; 40: 1 |
| [3] | Zaug J M, Soper A K, Clark S M. Nat Mater, 2008; 7: 890 |
| [4] | Liao S C, Mayo W E, Pae K D. Acta Mater, 1997; 45: 4027 |
| [5] | Wei Z J, Wang Z L,Wang H W, Cao L. J Mater Sci, 2007; 42: 7123 |
| [6] | He D W, He M, Kiminami C S, Kuo K H, Zhang F X, Xu Y F, Wang W K. J Mater Res, 2001; 16: 910 |
| [7] | Zhang G Z, Yu X F, Wang X Y, Jia G L, Gao Y Y, Hao Z Y, Guo X B. Acta Metall Sin, 1999; 35: 285 |
| [7] | (张国志, 于溪凤, 王向阳, 贾光霖, 高允彦, 郝兆印, 郭学彬. 金属学报, 1999; 35: 285) |
| [8] | Zhang J, Zhang H F, Dong P, Quan M X, Hu Z Q. Acta Metall Sin, 2004; 40: 211 |
| [8] | (张 甲, 张海峰, 董 盼, 全明秀, 胡壮麒. 金属学报, 2004; 40: 211) |
| [9] | Canadinc D, Maier H J, Gabor P, May J. Mater Sci Eng, 2008; A496: 114 |
| [10] | Cui G R, Ma Z Y, Li S X. Scr Mater, 2008; 58: 1082 |
| [11] | Jie J C, Zou C M, Wang H W, Wei Z J. Mater Lett, 2010; 64: 869 |
| [12] | Jie J C, Zou C M, Brosh E, Wang H W, Wei Z J, Li T J. J Alloys Compd, 2013; 578: 394 |
| [13] | Starink M J, Zahra A M. Acta Mater, 1998; 46: 3381 |
| [14] | Zhang D L, Massalski T B, Paruchuri M R. Metall Mater Trans, 1994; 25A: 73 |
| [15] | Schoenitz M, Dreizin E L. J Mater Res, 2003; 18: 1827 |
| [16] | Scudino S, Sperling S, Sakaliyska M, Thomas C, Feuerbacher M, Kim K B, Ehrenberg H, Eckert J. Acta Mater, 2008; 56: 1136 |
| [17] | Scudino S, Sakaliyska M, Surreddi K B, Eckert J. J Alloys Compd, 2009; 483: 2 |
| [18] | Mourik P V, Maaswinkel N M, Keijser T H D, Mittemeijer E J. J Mater Sci, 1989; 24: 3779 |
| [19] | Vacher P, Boudrahem S. Acta Mater, 2006; 54: 4365 |
| [20] | Hall E O. Proceedings Phys Soc London, 1951; 64B: 747 |
| [21] | Petch N J. J Iron Steel Inst, 1953; 174: 25 |
| [22] | Mukai T, Higashi K, Tanimura S. Mater Sci Eng, 1994; A176: 181 |
| [23] | Chen X, Yan J, Karlsson A. Mater Sci Eng, 2006; A416: 139 |
| [24] | Deng D. Mater Des, 2009; 30: 359 |
| [25] | Lados D A, Apelian D, Wang L. Mater Sci Eng, 2010; A527: 3159 |
| [26] | Wang T G, Zhao S S, Hua W G, Li J B, Gong J, Sun C. Mater Sci Eng, 2010; A527: 454 |
/
| 〈 |
|
〉 |