O, N和Ni含量对0Cr25Ni7Mo4N双相不锈钢热轧塑性的影响*

  • 陈雨来 ,
  • 张泰然 ,
  • 王一德 ,
  • 李静媛
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  • 1 北京科技大学冶金工程研究院, 北京 100083
    2 北京科技大学材料科学与工程学院, 北京 100083
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陈雨来, 男, 1970年生, 副教授

收稿日期: 2014-01-27

  修回日期: 2014-04-28

  网络出版日期: 2014-08-25

基金资助

国家自然科学基金项目51174026;十二五国家科技支撑计划项目2012BAE04B02

EFFECTS OF O, N AND Ni CONTENTS ON HOT PLASTICITY OF 0Cr25Ni7Mo4N DUPLEX STAINLESS STEEL

  • Yulai CHEN ,
  • Tairan ZHANG ,
  • Yide WANG ,
  • Jingyuan LI
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  • 1 Metallurgical Engineering Research Institute, University of Science and Technology Beijing, Beijing 100083
    2 School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083

Received date: 2014-01-27

  Revised date: 2014-04-28

  Online published: 2014-08-25

Supported by

Supported by National Natural Science Foundation of China (No.51174026), National Science and Technology Pillar Program during the Twelfth Five-Year Plan Period (No.2012BA-E04B02)

摘要

对不同O, N和Ni含量的0Cr25Ni7Mo4N双相不锈钢进行了1200 ℃, 4道次热轧实验. 利用OM, SEM和EBSD观察分析了实验钢的组织和夹杂物. 结果表明, 低O, N和Ni含量的实验钢热轧塑性良好. O含量为0.0059%的实验钢中夹杂物主要为Al2O3和MgO·Al2O3, 分布于晶粒内部, 未对热塑性造成不良影响. O含量为0.038%和0.046%的实验钢则发生了轧制边裂, 开裂处为α/γ相界, 相界内的大颗粒Cr2O3和MnO2夹杂是造成开裂的主要原因. 其中O含量较低(0.038%)的实验钢, 由于N和Ni含量过高, 使钢中γ相体积分数在热轧状态时高达60%. 过多的γ相降低了γ晶粒内部的总应变量, 使其不足以发生再结晶软化, 最终造成更严重的热轧开裂.

本文引用格式

陈雨来 , 张泰然 , 王一德 , 李静媛 . O, N和Ni含量对0Cr25Ni7Mo4N双相不锈钢热轧塑性的影响*[J]. 金属学报, 2014 , 50(8) : 905 -912 . DOI: 10.11900/0412.1961.2014.00057

Abstract

In order to identity the effect of narrow composition control on the hot plasticity of duplex stainless steel, hot rolling test of OCr25Ni7Mo4N steels with various oxygen, nitrogen and nickel contents were performed at 1200 ℃ for 4 steps. The microstructures and inclusions were observed by OM, SEM and EBSD. The steels with the lowest oxygen, nitrogen and nickel contents showed excellent hot plasticity. The inclusions in the steel with 0.0059% oxygen were mainly Al2O3 and MgO·Al2O3, which distributed in the grain interior and did no harm to the hot plasticity of the steel. The steels containing 0.038% and 0.046% oxygen actually cracked at the sheet edge during hot rolling, which resulted from the large inclusion particles of Cr2O3 and MnO2 at the α/γ boundary. Furthermore, the reason for more serious cracking occurred in the steel containing 0.038% oxygen than that containing 0.046% oxygen was its relatively higher contents of nitrogen and nickel, making γ volume fraction of the steel as high as 60% in the hot rolling state. Excessive γ reduced its total strain, so that the inadequate stain did not induce the recrystallization of γ phase, which resulted in hot rolling cracking finally.

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