Mn1.2Fe0.8P0.76Ge0.24磁制冷材料相变过程与磁性能关系的研究

张孟; 刘丹敏; 刘翠秀; 黄清镇; 王少博; 张虎; 岳明

doi:10.3724/SP.J.1037.2012.00775

金属学报 >

2013 , Vol. 49 >Issue 7: 783 - 788

DOI: https://doi.org/10.3724/SP.J.1037.2012.00775

论文

Mn_1.2Fe_0.8P_0.76Ge_0.24磁制冷材料相变过程与磁性能关系的研究

张孟 ,
刘丹敏 ,
刘翠秀 ,
黄清镇 ,
王少博 ,
张虎 ,
岳明

展开

1) 北京工业大学固体微结构与性能研究所, 北京 100124
2) NIST Center for Neutron Research, National Institute of Standards and Technology,Gaithersburg, Maryland 20899
3) 北京工业大学材料科学与工程学院, 北京 100124

张孟, 男, 1986年生, 硕士生

收稿日期: 2012-12-25

修回日期: 2013-04-12

网络出版日期: 2013-07-11

基金资助

国家自然科学基金项目51071007和51171003, 国家重点基础研究发展计划项目2010CB833100, 北京自然科学基金项目1112005和CSNS用户专项项目资助

收起

RESEARCH OF THE RELATIONSHIP BETWEEN PHASE TRANSITION PROCESS AND MAGNETIC PROPERTIES IN MAGNETIC REFRIGERATION MATERIAL Mn_1.2Fe_0.8P_0.76Ge_0.24

ZHANG Meng ,
LIU Danmin ,
LIU Cuixiu ,
HUANG Qingzhen ,
WANG Shaobo ,
ZHANG Hu ,
YUE Ming

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1) Institute of Microstructure and Property of Advanced Materials, Beijing University of Technology, Beijing 100124
2) NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899
3) College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124

Received date: 2012-12-25

Revised date: 2013-04-12

Online published: 2013-07-11

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摘要

利用机械合金化(MA)结合放电等离子烧结(SPS)技术, 制备了Mn_1.2Fe_0.8P_0.76Ge_0.24磁制冷材料,并采用SEM观察烧结样品的显微组织, 利用中子衍射、超导量子干涉磁强计(SQUID)、差示扫描量热仪(DSC)和X射线衍射(XRD)等手段对相变过程和磁热性能进行了研究.结果表明: 烧结样品显微组织均匀致密, Mn_1.2Fe_0.8P_0.76Ge_0.24化合物具有六方Fe₂P型晶体结构.外加磁场和温度的变化都可以引起材料的磁热相变, 即顺磁相与铁磁相之间的可逆一级相变.材料的磁熵变与相转变的程度有密切关系, 随着外加磁场的增大或温度的降低,合金由顺磁相向铁磁相转变, 从而使材料磁熵变增大. 分析发现,材料的磁熵变大小与相转变过程中发生转变的相变百分比是直接对应的,温度诱导相变与磁场诱导相变所得结果一致.

关键词： 磁制冷材料; 磁热相变过程; 中子衍射

本文引用格式

张孟 , 刘丹敏 , 刘翠秀 , 黄清镇 , 王少博 , 张虎 , 岳明 . Mn_1.2Fe_0.8P_0.76Ge_0.24磁制冷材料相变过程与磁性能关系的研究[J]. 金属学报, 2013 , 49(7) : 783 -788 . DOI: 10.3724/SP.J.1037.2012.00775

Abstract

In recent years, the MnFePGe compound has drawn tremendous attention not only for its excellent magnetocaloric effect (MCE), but also for its great commercial interest.Compared with other advanced MCE materials such as GdSiGe, MnFePAs, etc.,it possesses many practical advantages such as more abundant raw materials,lower fabrication costs as well as better environmental amity. In this work, Mn_1.2Fe_0.8P_0.76Ge_0.24 compound was prepared by mechanical milling and subsequent spark plasma sintering (SPS) technique, its microstructure was investigated by SEM, meanwhile the relationship between phase transition and the properties was investigated by neutrondiffraction, SQUID, DSC and XRD. The results show that the Mn_1.2Fe_0.8P_0.76Ge_0.24 compound is compact, and possess a hexagonal Fe₂P-type crystal structure. Generally, either applied magnetic field or temperature change will induce the transformation between paramagnetic phase and ferromagnetic phase. When the applied magnetic field increased or temperature reduced, paramagnetic phase transformed to ferromagnetic phase and caused the magnetic entropy change to become larger. It is found that the magnetic entropy change of Mn_1.2Fe_0.8P_0.76Ge_0.24 compound is directly corresponding to the percentage of the phase transition.

Key words： magnetic refrigeration material; magnetic thermal phase transition process; neutron diffraction

参考文献

[1] Dan'kov S Y, Tishin A M, Pecharsky V K, Gschneidner K A. Phys Rev, 1998; 57B: 3478

[2] Pecharsky V K, Gschneidner K A.Phys Rev Lett, 1997; 78: 4494

[3] Hu F X, Shen B G, Sun J R.Appl Phys Lett, 2001; 78: 3675

[4] Tegus O, Bruck E, Buschowet K H J, de Boer F R. Nature, 2002; 415: 150

[5] Wang G F, Song L, Li F A, Ha S C L, Li X W, Tegus O. Acta Metall Sin, 2008; 43: 889

(王高峰, 松林, 李福安, 哈斯朝鲁, 李新文, 特古斯. 金属学报, 2008; 43: 889)

[6] Hu F X, Qian X L, Wang G J, Sun J R, Shen B G, Cheng Z H, Gao J. Chin Phys, 2005; 14: 2329

[7] Li F A, Song L, Bao L H, Ha S C L, Tegus O, Huang J H.Acta Metall Sin, 2008; 44: 371

(李福安, 松林, 包黎红, 哈斯朝鲁, 特古斯, 黄焦宏. 金属学报, 2008; 44: 371)

[8] Tegus O, Bruck E, Li X W, Zhang L, Dagula W, de Boer F R, Buschow K H J.J Magn Magn Mater, 2004; 272: 2389

[9] Kim Y K, Cho Y W. J Alloys Compd, 2005; 394: 19

[10] Tegus O, Lin G X, Dagula W, Fuquan B, Zhang L, Bruck E, de Boer F R,Buschow K H J. J Magn Magn Mater, 2005; 290: 658

[11] Hermann R P, Tegus O, Bruck E, Buschow K H J, de Boer F R, Long G J,Grandjean F. Phys Rev, 2004; 70B: 214425

[12] Tegus O, Koyama K, Her J L, Watanabe K, Bruck E, Buschow K H J,de Boer F R.Physica, 2007; 392B: 151

[13] Bruck E, Kamarad J, Sechovsky V, Arnold Z, Tegus O, de Boer F R.J Magn Magn Mater,2007; 310: e1008

[14] Tegus O, Fuquan B, Dagula W, Zhang L, Bruck E, Si P Z, de Boer F R,Buschow K H J.J Alloys Compd, 2005; 396: 6

[15] Thanh D T Cam, Bruck E, Tegus O, Klaasse J C P, Buschow K H J. J Magn Magn Mater,2007; 310: e1012

[16] Thanh D T, Bruck E, Tegus O, Klaasse J C P, Gortenmulder T J,Buschow K H J. J Appl Phys, 2006; 99: 1

[17] Li X W, Tegus O, Zhang L, Dagula W, Bruck E, Buschow K H J, de Boer F R.IEEE Trans Magn, 2003; 39: 3148

[18] Yue M, Li Z Q, Xu H, Huang Q Z, Liu X B, Liu D M, Zhang J X. J Appl Phys, 2010; 107: 09A939

[19] Dagula W, Tegus O, Fuquan B, Zhang L, Si P Z, Zhang M, Zhang W S,Bruck E, de Boer F R, Buschow K H J. IEEE Trans Magn, 2005; 41: 2778

[20] Qu Z Q, Wang G F, Lin S, Tegus O, Bruck E, Buschow K H J. J Phys: Condes Matter,2006; 18: 11577

[21] Bao Y M, Zhang K D. Magnetic Refrigeration Technology. Beijing: Chemical Industry Press, 2004: 69

(鲍雨梅, 张康达. 磁制冷技术. 北京: 化学工业出版社, 2004: 69)

[22] Feng H B, Zhou Y, Jia D C. Mater Sci Thchnol, 2003; 11: 327

(冯海波, 周玉, 贾德昌. 材料科学与工艺, 2003; 11: 327)

[23] Zhang J X, Liu K G, Zhou M L. Powder Metall Technol, 2002; 20: 129

(张久兴, 刘科高, 周美玲. 粉末冶金技术, 2002; 20: 129)

[24] Gao L, Miyamoto H.J Inorg Mater, 1997; 12: 129

(高濂, 宫本大树. 无机材料学报, 1997; 12: 129)

[25] Yamada H, Goto T. { Phys Rev, 2003; 68B: 184417

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