利用电子束毛化技术在TA15薄板(Ti-6Al-2Zr-1Mo-1V)表面生成“毛刺”, 通过OM, SEM, EDS和XRD分析了“毛刺”的组织、元素成分和性能. 研究发现, “毛刺”组织可分为边缘区、中心区、热影响区、基体; 边缘区为粗大晶粒和大量片状马氏体, 硬度最低; 中心区为大晶粒和规则排列的片状马氏体, 硬度次低; 热影响区晶粒较小, 晶界为α相, 晶内为平行排列的片状马氏体组织, 硬度最高; 不同区域的Al含量有明显差异. “毛刺”不同区域的硬度主要取决于Al含量和晶粒尺寸.
Electron beam surfi–sculpt is a novel surface processing technology, in which electron beam is controlled by magnetic field and deflected quickly over a substrate surface to displace materials in a settled manner, thus producing customized textured surface consisting of an array of protrusions above the original surface and a corresponding array of cavities in the substrate. This technology could be used in dissimilar materials connection between metals and composites, as the protrusions on metal surface would increase the interface area, which results in great improvements in both strength and absorbed energy. It could also be applied to improve the surface coating quality by tailor–making protrusions throughout a component surface so as to enhance the adhesive capacity between coating and substrate, as well as to optimize the stress distribution that occurs in coating process. The application performance of textured surface depends on the microstructure characterisation of protrusions, while the investigation on the microstructures and mechanical properties of the protrusion is lack. In this work, electron beam surfi–sculpt was carried out to produce protrusions on TA15 (Ti–6Al–2Zr–1Mo–1V) surface through multi–beam technique. The microstructure features of protrusions were investigated by OM, SEM and XRD, and the weight percentages of alloy elements were analyzed by EDS. In addition, the micro–hardness of the four zones were measured and the results were explained by its microstructure features and weight percentages of alloy elements. It was found that four zones exist in the protrusion, namely edge zone, central zone, heat affected zone (HAZ) and substrate. The edge zone is composed of coarse grain with platelet martensite inside, whose micro–hardness is the lowest. The central zone, whose micro–hardness is the second lowest, is constituted of coarse grain with regular–layed platelet martensite; however, the grain size is smaller than that in the edge zone. The HAZ is characterized of fine grain with boundary α and parallel–layed short platelet martensite inside, plus the highest micro–hardness. The weight percentages of Al in the HAZ and the substrate were higher than that in the edge zone and the central zone, which, together with different grain size of the four zones, are the two main reasons for the micro–hardness differences of the four zones.
[1] Dance B G I, Kellar E J C. International Pat, WO 2004/028731 A1, 2004
[2] Dance B G I. International Pat, WO 2002/094497 A3, 2002
[3] Wan Y, Xiong D S. J Mater Process Technol, 2008; 197: 96
[4] Vilhena L M, Sedlacek M, Podgornik B, Vizintin J, Babnik A, Mozina J. Tribol Int, 2009; 42: 1496
[5] Lamraoui A, Costil S, Langlade C, Coddet C. Surf Coat Technol, 2010; 205: S164
[6] Wong R C P, Hoult A P, Kim J K, Yu T X. J Mater Process Technol, 1997; 63: 579
[7] Voevodin A A, Zabinski J S. Wear, 2006: 261: 1285
[8] Liu Y, Chen D R, He Y F, Sui B, Zhao L. Tribology, 2002; 22: 477
(刘莹, 陈大融, 何云峰, 岁波, 赵 磊. 摩擦学学报, 2002; 22: 477)
[9] Wan D P, Chen B K, Shao Y M, Wang S L, Hu D J. J Appl Surf Sci, 2008; 255: 3251
[10] Liu H B, Wan D P, Hu D J. J Mater Process Technol, 2009; 209: 805
[11] Zhang K. Appl Laser, 2010; 30: 105
(张 匡. 应用激光, 2010; 30: 105)
[12] Cai C B, Ji Z S, Wang G J, Zhang H J. Trans Mater Heat Treat, 2009; 30: 111
(蔡春波, 吉泽升, 王国军, 张华军. 材料热处理学报, 2009; 30: 111)
[13] Deng Z M, Liu J, Zhao Y B, Hong Y S. J Mech Strength, 2004; 26: 154
(邓忠民, 刘敬, 赵亦兵, 洪友士. 机械强度, 2004; 26: 154)
[14] Vatsya S R, Nikumb S K. Phys Rev, 2003; 68B: 035410
[15] Wan D P, Hu D J, Liu H B, Cai L R. Chin J Lasers, 2007; 34: 1004
(万大平, 胡德金, 刘红斌, 蔡兰蓉. 中国激光, 2007; 34: 1004)
[16] Liu H B, Wan D P, Hu D J. Trans Mater Heat Treat, 2008; 29: 181
(刘红斌, 万大平, 胡德金. 材料热处理学报, 2008; 29: 181)
[17] Wang X C, Gong S L, Guo EM, Cao Z H, YuW, Song Z Y, Huang Y. Manuf Technol (Suppl), 2009: 53
(王西昌, 巩水利, 郭恩明, 曹正华, 余伟, 宋祚禹, 黄勇. 制造技术(增刊), 2009: 53)
[18] Wang X. Master Dissertation, Tsinghua University, Beijing, 2008
(王欣. 清华大学硕士学位论文, 北京, 2008)
[19] Xin S W, Zhao Y Q, Zeng W D. Titanium Ind Progress, 2007; 24: 23
(辛社伟, 赵永庆, 曾卫东. 钛工业进展, 2007; 24: 23)
[20] Glavicic M, Semiatin S L. Acta Mater, 2006; 54: 5337
[21] Zhang W F,Wang Y H, Li Y, Ma JM. Chin J Nonferrous Met, 2010; 20: 523
(张旺峰, 王玉会, 李艳, 马济民. 中国有色金属学报, 2010; 20: 523)
[22] Xin S W, Zhao Y Q, Zeng W D. Titanium Ind Progress, 2008; 25: 29
(辛社伟, 赵永庆, 曾卫东. 钛工业进展, 2008; 25: 29)
[23] Zhang X Y, Zhao Y Q, Bai C G. Titanium Alloy and its Application. Beijing: Chemical Industry Press, 2005: 235
(张喜燕, 赵永庆, 白晨光. 钛合金及应用. 北京: 化学工业出版社, 2005: 235)
[24] Beijing Institute of Aviation Materials. Aviation Materials Science. Shanghai: Shanghai Science and Technology Press, 1985: 234
(北京航空材料研究所. 航空材料学. 上海: 上海科学技术出版社, 1985: 234)
[25] Ворисова E A, translated by Chen S Q. Metallography Titanium Alloys. Beijing: National Defense Industry Press, 1980: 160
(Ворисова E A著, 陈石卿译. 钛合金金相学. 北京: 国防工业出版社, 1980: 160)
