Ti36Zr40Ni20Pd4准晶的热稳定性与室温储氘性能
收稿日期: 2009-12-10
修回日期: 2010-03-03
网络出版日期: 2010-05-11
基金资助
中国工程物理研究院科学技术发展基金资助项目2007A07002
THERMAL STABILITY AND DEUTERIUM ABSORPTION AT ROOM TEMPERATURE OF Ti36Zr40Ni20Pd4 QUASICRYSTAL
Received date: 2009-12-10
Revised date: 2010-03-03
Online published: 2010-05-11
Supported by
Supported by Science and Technology Development Foundation of China Academy of Engineering Physics (No.2007A07002)
在Ti40Zr40Ni20准晶合金中掺Pd制备了Ti36Zr40Ni20Pd4准晶合金, 利用X射线衍射(XRD)、金相(OM)、光电子能谱(XPS)、气固反应等对其组织结构和吸氘特性进行了研究. 结果表明, 在吸铸态下该合金形成了二十面体准晶相, 准晶格常数为0.5174 nm. 其热力学稳定性较差, 约400 ℃时转变为tI-Zr2Ni与C14-TiZrNiPd晶体相. 室温下, 其吸氘能力为11.0 mmol/g(相当于 2.2%的吸氢质量分数), 吸氘速率达到0.030 s-1, 准晶结构不变但准晶格膨胀5.5%. 添加的Pd起到催化作用, 与初始合金相比, Ti36Zr40Ni20Pd4准晶合金的活化与储氘能力明显提高.
关键词： Ti-Zr-Ni-Pd合金; 准晶; 氘; 催化
黄火根 , 陈亮 , 李嵘 . Ti36Zr40Ni20Pd4准晶的热稳定性与室温储氘性能[J]. 金属学报, 2010 , 46(5) : 629 -633 . DOI: 10.3724/SP.J.1037.2009.00821
Ti-Zr-Ni quasicrystals can absorb a large amount of hydrogen, so have strong application potential in the hydrogen energy field and international thermonuclear experimental reactor (ITER) program. However, the hydrogenation of the quasicrystals is often hindered and even poisoned due to their surface oxidation. To inhibit the oxidation, Pd has been selected, because of its catalysis to hydrogen absorption, as a minor alloying element in Ti-Zr-Ni quasicrystals. In this paper, the Ti36Zr40Ni20Pd4 alloy was designed and its thermal stability and room--temperature deuteration were studied with XRD, DSC, OM, XPS and gas--solid reaction measurement apparatus. The XRD result shows that a single icosahedral quasicrystal (IQC) phase with a quasilattice constant aR=0.5174 nm was formed in the alloy by suction-casting method, which is metastable and transforms to conventional crystals tI-Zr2Ni and C14-TiZrNiPd (MgZn2 type) phase at about 400℃. The deuteration test below the transformed temperature indicates that the alloy can absorb deuterium up to a large concentration of 11.0 mmol/g (corresponding to 2.2%H, mass fraction) at room temperature after vacuuming and heating activation without any surface treatment. Once fully activated, the IQC can load deuterium rapidly with an absorption rate of\linebreak 0.030 s-1 at ambient temperature, and has the quasilattice constant with about 5.5% expansion after two absorption cycles. The Ti36Zr40Ni20Pd4 IQC has better activation property and hydrogen capacity than the Ti40Zr40Ni20 IQC, which shows the catalyzing function of Pd.
Key words： Ti-Zr-Ni-Pd alloy; quasicrystal; deuterium; catalyzing
[1] Bogdanovic B, Schwickardi M. Appl Phys, 2001; 72A: 221
[2] Chen P, Xiong Z T, Luo J Z, Lin J Y, Tan K L. Nature, 2002; 420: 302
[3] Xiong Z T, Yong C K, Wu G T, Chen P, Shaw W, Karkamkar A, Autrey T, Jones M O, Johnson S R, Edwards P P, David W I F. Nat Mater, 2008; 7: 138
[4] Feng K M. Chin Nucl Power, 2009; 2: 212
(冯开明. 中国核电, 2009; 2: 212)
[5] Gibbons P C, Hennig R G, Huett V T, Kelton K F. J Non–Cryst Solids, 2004; 334: 461
[6] Kelton K F, Hartzell J J, Hennig R G, Huett V T, Takasaki A. Philos Mag, 2006; 86: 957
[7] Liu B Z, Liu D M, Wu Y M, Li L Q, Wang L M. Int J Hydro Energy, 2007; 32: 2429
[8] Liu B Z, Wu Y M, Wang L M. J Power Source, 2006; 162: 713
[9] Liu B Z, Wu Y M, Wang L M. J Power Source, 2006; 159: 1458
[10] Liu B Z, Wu Y M, Wang L M. Int J Hydrogen Energy, 2006; 31: 1394
[11] Liu B Z, Wu Y M, Wang L M. Rare Met, 2007; 26: 440
[12] Takasaki A, Huett V T, Kelton K F. J Non–Cryst Solids, 2004; 334: 457
[13] Takasaki A, Kelton K F. Int J Hydrogen Energy, 2006; 31: 183
[14] Hennig R G, Majzoub E H, Carlsson A E, Kelton K F, Henley C L, Yelon W B, Misture S. Mater Sci Eng, 2000; 294A: 361
[15] Kim J Y, Hennig R, Huett V T, Gibbons P C, Kelton K F. J Alloys Compd, 2005; 404: 388
[16] Huang H G, Dong P, Yin C, Zhang P C, Bai B, Dong C. Int J Hydrogen Energy, 2008; 33: 722
[17] Huang H G, Li R, Yin C, Zheng S T, Zhang P C. Int J Hydrogen Energy, 2008; 33: 4607
[18] Liu B Z, Liu J J, Mi G F, Zhang Z, Wu Y M, Wang L M. J Alloys Compd, 2009; 475: 881
[19] Liu B Z, Zhang Y D, Mi G F, Zhang Z, Wang L M. Int J Hydrogen Energy, 2009; 34: 6925
[20] Huang H G, Yin C, Wu J, Zhang P C. Chin J Nonferrous Met, 2008; 18: 108
(黄火根, 银陈, 吴江, 张鹏程. 中国有色金属学报, 2008; 18: 108)
[21] Cahn J W, Shechtman D, Gratias D. J Mater Res, 1986; 1: 13
[22] Qiang J B, Wang Y M, Wang D H, Dong C. Rare Met Mater Eng, 2004; 33: 949
(羌建兵, 王英敏, 王德和, 董闯. 稀有金属材料与工程, 2004; 33: 949)
[23] Huang H G, Jia J P, Li R. Acta Metall Sin, 2009; 45: 1272
(黄火根, 贾建平, 李嵘. 金属学报, 2009; 45: 1272)
[24] Hirooka Y, Miyake M, Sano T. J Nucl Mater, 1981; 96: 227
[25] Huang L J, Yu B X, Gao S J. Met Funct Mater, 1998; 5: 124
(黄利军, 虞炳西, 高树浚. 金属功能材料, 1998; 5: 124)
[26] Wang W W, Long X G. J Nucl Radiochem, 2007; 29: 80
(王伟伟, 龙兴贵. 核化学与放射化学, 2007; 29: 80)
[27] Coddens G, Viano A M, Gibbons P C, Kelton K F, Kramer M J. Solid State Comm, 1997; 104: 179
[28] Faust K R, Pfitsch D W, Stojanovich N A, McDowell A F, Adolphi N L, Majzoub E H, Kim J Y, Gibbons P C, Kelton K F. Phys Rev, 2000; 62B: 11444
/
| 〈 |
|
〉 |
