湿H2S环境中L360MCS钢焊接热影响区的应力导向氢致开裂行为
收稿日期: 2009-10-10
修回日期: 2010-01-28
网络出版日期: 2010-05-11
基金资助
国家自然科学基金项目50871122和高等学校博士学科点专项科研基金项目20070425021资助
STRESS ORIENTED HYDROGEN INDUCED CRACKING BEHAVIOR OF HEAT AFFECTED ZONE OF L360MCS STEEL IN WET H2S ENVIRONMENT
Received date: 2009-10-10
Revised date: 2010-01-28
Online published: 2010-05-11
Supported by
Supported by National Natural Science Foundation of China (No.50871122), Specialized Research Fund for the Doctoral Program of Higher Education (No.20070425021})
利用裂纹面分离及SEM和EDS研究了L360MCS钢焊接热影响区(HAZ)在湿H2S环境中的应力导向氢致开裂(SOHIC)行为. 结果表明: 应力导向氢致开裂裂纹由轴向和纵向两种裂纹组成, 先形成轴向裂纹, 后形成纵向裂纹, 两种裂纹均独立形核. 裂纹带有明显的阶梯状氢致开裂特征, 裂纹面呈现准解理型断口形貌. 拉应力在裂纹形核和扩展方面起主要作用, 拉应力不仅增加了拉伸区的过饱和氢浓度, 而且直接推动纵向裂纹的扩展. 轴向裂纹在MnS和CaS夹杂以及析出相处形核, 以氢压为主要的裂纹扩展动力. 而纵向裂纹则主要在析出相处萌生, 裂纹扩展受拉应力和氢压双重控制, 拉应力为主导.
关键词： 管线钢; 热影响区(HAZ); 应力导向氢致开裂(SOHIC); H2S; 拉应力
周成双 . 湿H2S环境中L360MCS钢焊接热影响区的应力导向氢致开裂行为[J]. 金属学报, 2010 , 46(5) : 547 -553 . DOI: 10.3724/SP.J.1037.2009.00669
Stress oriented hydrogen induced cracking (SOHIC) behavior of heat affected zone (HAZ) of L360MCS steel in wet H$_{2}$S
environment was studied by separating crack, SEM and EDS. The cracks are formed by four--point bending test in
wet H$_{2}$S environment. The microstructure of HAZ is obviously different from
the base metal, and the hardness of HAZ is lower than those of the base metal and welding joint. The fracture
surface of the cracks was separated and the hydrogen blisters were torn off. The cross section and fracture surface of
the cracks are analyzed by SEM and EDS. Results show that the cracks of SOHIC appeared as axial crack and vertical
crack, and the former is preferential. The appearance of cracks is associated with the low hardness value of
HAZ. The dimension of hydrogen blasters in tension stress zone of bended specimen is bigger than that in
unstressed specimen, which is due to hydrogen concentration in bended specimen is higher. Both axial and vertical
cracks nucleate independently and propagate in the quasi--cleavage manner. Tension stress not only increases the
supersaturated hydrogen concentration in tension stress zone but directly promotes vertical crack propagation.
Axial crack nucleates at MnS, CaS and precipitated phase, and propagates under internal hydrogen pressure.
Vertical crack mainly nucleates on precipitated phase and propagates under both internal hydrogen pressure and
tensile stress.
[1] Pargeter R J. In: NACE, ed., Corrosion 2007, Houston, TX: NACE, 2007: 115
[2] Guo H, Li G F, Cai X, Yang W. Acta Metall Sin, 2004; 40: 967
(郭浩, 李光福, 蔡珣 , 杨武. 金属学报, 2004; 40: 967)
[3] Ren X C, Wu M, Chu W Y, Li J X, Jiao L J, Jiang B, Chen G, Cui Y H. Acta Metall Sin, 2007; 43: 149
(任学冲, 武明, 褚武扬, 李金许, 乔利杰, 江波, 陈 刚, 崔银会. 金属学报, 2007; 43: 149)
[4] Liu Z Y, Zhai G L, Dui C W, Li X G. Acta Metall Sin, 2008; 44: 209
(刘智勇, 翟国丽, 杜翠薇, 李晓刚. 金属学报, 2008; 44: 209)
[5] Guo J, Yang S W, Shang C J, Wang Y, He X L. Corros Sci, 2008; 51: 242
[6] Ernesto V, Andrej A. Eng Fail Anal, 2009; 16: 164
[7] Cayard M S, Kane R D, Cooke D L. In: NACE, ed., Corrosion 97, Houston, TX: NACE, 1997: 525
[8] Cayard M S, Kane R D, Horvath R J. In: NACE ed., Corrosion 2002, Houston, TX: NACE, 2002: 554
[9] Orie K E, Fletcher F B. In: NACE, ed., Corrosion 99, Houston, TX: NACE, 1999: 632
[10] NACE International. NACE Standard MR0177–2005, Houston, 2005
[11] ASTM. ASTM Standard G39–99, Philadelphia, 2005
[12] NACE International. NACE Standard MR0284–2003, Houston, 2003
[13] Zhao M C, Shan Y Y, Qu J B, Xiao F R, Zhong Y, Yang K. In: CSM ed., CSM 2001 Annual Meeting Proceedings. Beijing: Metallurgical Industry Press, 2001: 891
(赵明纯, 单以银, 曲锦波, 肖福仁, 仲勇, 杨柯. 见中国金属学会主编, 2001年中国钢铁年会论文集.
北京: 冶金工业出版社, 2001: 891)
[14] Lee H W. Mater Sci Eng, 2007; A445: 328
[15] Sojka J, Jerome M, Sozanska M, Vanova P, Rytirova L, Jonsta P. Mater Sci Eng, 2008; A430: 237
[16] Wan K K, Seong U K, Boo Y Y, Kyoo Y K. Corros Sci, 2008; 50: 3336
[17] Parkins R N. Corrosion, 1987; 43: 130
[18] Chu R, Chen W, Wang S H. Corrosion, 2004; 60: 275
[19] Lynch S P. In: NACE, ed., Corrosion 2007, Houston, TX: NACE, 2007: 493
[20] Maroecic P, Mclellan R B. Acta Metall, 1998; 46: 5593
[21] Zang D, MeLellan R B. Acta Metall, 1999; 47: 1671
[22] Harada S, Ono D, Sugimoto H, Fukai Y. J Alloys Compd, 2007; 446: 474
[23] Rebak R B, Xia Z, Safruddin R, Szklarska S Z. Corrosion, 1996; 52: 396
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