金属学报  2008, Vol. 44 Issue (2): 177-182

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CaZr0.9In0.1O3高温质子导体管的制备及性质表征

王 东 史苍际 刘春明 王常珍

(东北大学材料与冶金学院; 沈阳 110004)

Preparation Of High Temperature Proton Conductor Tube CaZr0.9In0.1O3-α And Its Properties

东北大学

王东; 史苍际; 刘春明; 王常珍 . CaZr0.9In0.1O3高温质子导体管的制备及性质表征[J]. 金属学报, 2008, 44(2): 177-182 .

摘要 参考文献 相关文章 Metrics 全文: PDF(462 KB)   摘要: 用直接合成法制备了高温质子导体CaZr0.9In0.1O3-α，粉体平均粒径为1.88μm. 用热铸法制得的质子导体管密度为理论值的97.44%. SEM断口形貌显示晶粒尺寸在1～3μm，结构致密. X射线能谱仪（EDS）和X射线荧光光谱仪（XRF）发现，烧成后材料中的In含量减少. 由热力学分析，这是In2O3在1200℃以上升华、离解造成的. 空气气氛下CaZr0.9In0.1O3-α在931～1300K的电导激活能为1.47eV，电导率为0.91×10-4～1.21×10-2S•cm-1，略低于其在文献报道中氢气气氛下的测定值，但高于CaZr0.97In0.03O3-α在空气气氛下的测定值，符合理论推断. 关键词 ： CaZrO3掺杂,  CaZr0.9In0.1O3-α,  交流阻抗谱     Abstract：High temperature proton conducotor CaZr0.9In0.1O3-α was prepared by direct synthesis method, and the average grain diameter of the powder was 1.88μm. Hot pressure casting method was used for preparing the tube, whose density was 97.44% relative to theoretical density. SEM fracture analysis showed the grain size was 1～3μm. EDS and XRF showed that the material had In elelment lost after sintered. This is because In2O3 sublimed and decomposed when temperature was higher than 1200℃. The conductivity of CaZr0.9In0.1O3-α was 0.91×10-4～1.21×10-2 S•cm-1 at the temperature range of 931～1300K in air. The value was a little small than the value in H2 and larger than the value of CaZr0.97In0.03O3-α in air in the literature. This was corresponded with theoretical conjecture. Key words： CaZrO3 doped    CaZr0.9In0.1O3-α    AC impedance spectroscopy    high temperature proton conductor 收稿日期: 2007-03-28      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 王东 史苍际 刘春明 王常珍 44.8K 链接本文: https://www.ams.org.cn/CN/Y2008/V44/I2/177 [1]Iwahara H,Esaka T,Uchida H,Maeda N.Solid State Ion- ics,1981;3-4:359 [2]Uchida H,Maeda N,Iwahara H.Solid State lonics,1983; 11:117 [3]Iwahara H,Esaka T,Uchida H,Yarnauchi T,Ogaki K. Solid State Ionics,1986;18-19:1003 [4]Iwahara H.Solid State Ionics,1988;28-30:573 [5]Iwahara H,Uchida H,Ondo K,Ogaki K.J Electrochem Soc,1988;135:529 [6]Iwahara H.Proc Int Seminar Solid State Ionic Devices, Singapore,1988;18-23:289 [7]Uchida H,Yoshikawa H,Esaka T,Ohtsu S,Iwahara H. Solid State Ionics,1989;36:89 [8]Yajima T,Koide K,Yamamoto K,Iwahara H.Denki Ka- gaku,1990;58:547 (Yajima T,Koide K,Yamamoto K,Iwahara H.电气化学工业物理化学,1990;58:547) [9]Yajima T,Iwahara H,Koide K,Yamamoto K.Sensors Actuators B:Chemical,1991;5B:145 [10]Yajima T,Iwahara H,Uchida H.Solid State Ionics,1991; 47:117 [11]Yajima T,Kazeoka H,Yogo T,Iwahara H.Solid State Ionics,1991;47:271 [12]Yajima T,Suzuki H,Yogo T,Iwahara H.Solid State Ion- ics,1992;51:101 [13]Hibino T,Mizutani K,Yajima T,Iwahara H.Solid State Ionics,1992;57:303 [14]Iwahara H,Yajima T,Hibino T,Ozaki K,Suzuki H.Solid State Ionics,1993;61:65 [15]Iwahara H.Solid State Ionics,1995;77:289 [16]Yajima T,Koide K,Takai H,Fukatsu N,Iwahara H.Solid State Ionics,1995;79:333 [17]Xu X G,Wang C Z,Yu H L,Liu H B.J Northeast Univ (Nat Sci),1996;17:374 (徐秀光，王常珍，于化龙，刘宏波．东北大学学报(自然科学版)，1996；17：374) [18]Yang N R,Yue W H.The Handbook of Inorganic Metal- loid Materials Atlas.Wuhan:Wuhan University of Tech- nology Press,2000:211 (杨南如，岳文海．无机非金属材料图谱手册．武汉：武汉工业大学出版社，2000：211) [19]Fedorov B E,Akchurin P X.Translated by Zhang Q Y, Xu K M.Indium Chemistry Handbook.Beijing:Peking University Press,2005:24 (著．张启运，徐克敏译．铟化学手册．北京：北京大学出版社，2005：24) [1] 赵博 杜翠薇 刘智勇 李晓刚 杨吉可 李月强. 剥离涂层下的X80钢在鹰潭土壤模拟溶液中的腐蚀行为[J]. 金属学报, 2012, 48(12): 1530-1536. Viewed Full text Abstract Cited   Shared      Discussed