真空熔炼的物理化学

金属学报

1964, Vol. 7

Issue (1): 85-103

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真空熔炼的物理化学

邵象华

冶金工业部钢铁研究院

PHYSICAL CHEMISTRY OF VACUUM MELTING

SHAO HSIANG-HUA(Iron and Steel Research Institute; The Ministry of Metallurgical Industry)

引用本文:

邵象华. 真空熔炼的物理化学[J]. 金属学报, 1964, 7(1): 85-103.
. PHYSICAL CHEMISTRY OF VACUUM MELTING[J]. Acta Metall Sin, 1964, 7(1): 85-103.

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摘要: 真空对熔炼过程的影响。脫气的热力学基础;气体在鉄、鎳、钴中的溶解度、活度;第三元素的影响。杂貭和合金元素在真空条件下的揮发;揮发过程中合金組成变化的規律;揮发系数。液态金属中氧的活度;氫脫氧;揮发脫氧;碳脫氧。坩堝耐火材料与熔池之間的反应;坩堝反应与脫氧的关系。真空熔炼中各类反应的动力学;扩散;揮发速率及真空度对揮发速率的影响;脫气速率;脫氧速率;坩堝反应速率。关于今后真空熔炼物理化学研究工作的意見。

Abstract：A critical review of literature on the physico-chemical aspects of vacuum melting of metals and alloys, with particular reference to the thermodynamics and kinetics of degassing, distillation of impurity or alloying elements, deoxidation, and metal-crucible reactions. Fields of further research work are suggested.

收稿日期: 1964-01-18

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