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金属学报  1966, Vol. 9 Issue (2): 189-239    
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钼中非金属夹杂物的鉴定
朱惠滋;李静媛;浦以健
ON THE IDENTIFICATION OF NONMETALLIC INCLUSIONS IN MOLYBDENUM
CHU HUI-TZǔ; LI CHIN-YEN; P'U YI-CHIEN
引用本文:

朱惠滋;李静媛;浦以健. 钼中非金属夹杂物的鉴定[J]. 金属学报, 1966, 9(2): 189-239.
, , . ON THE IDENTIFICATION OF NONMETALLIC INCLUSIONS IN MOLYBDENUM[J]. Acta Metall Sin, 1966, 9(2): 189-239.

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摘要: 钼中存在的微量杂质,如氧、氮和碳等,对钼的可锻性和可塑性均有影响。而影响的大小,随它们在钼中的含量、分布位置和存在的形式而不同。为了阐明这一问题,先后用自耗电极真空电弧炉熔炼了含氧、氮和碳量不同的纯钼和钼合金。然后用金相、岩相、断口相、X射线和化学分析等方法研究了试样中氧、氮和碳所形成的夹杂物的类型和分布。试验结果指出,在2000倍下晶界上MoO_2消失的含量为0.0027%。此外,还肯定了试样中夹杂物的类型有:MoO_2,γ-Mo_2N,Mo_2C,ZrO_2,ZrN,TiO,TiN,TiO_2(含Mo),α-Al_2O_3及SiO_2。这些结果对解释钼的脆性和研究冶炼过程有一定参考价值。
Abstract:Specimens of molybdenum and Mo-base alloys with various amounts of oxygen, nitrogen and carbon were taken from ingots made by the consumable electrode vacuum arc melting process, and were examined by means of metallographic, petrographic and fractographic methods as weU as X-ray and chemical analyses. The following nonmetallic inclusions have been identified: MoO_2, γ-Mo_2N, Mo_2C, ZrO_2, ZrN, TiO, TiN, TiO_2 (containing Mo), α-Al_2O_3 and SiO_2. It was found that no MoO_2 was observed at the grain boundaries even at 2000 X when the oxygen content in molybdenum is below 0.0027%.
收稿日期: 1966-02-18     
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