金属学报  1981, Vol. 17 Issue (6): 652-660

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氧化物系的多维键参数分析

刘征先;郑龙如;陈念贻;阎立诚

中国科学院上海冶金研究所;中国科学院上海冶金研究所;中国科学院上海冶金研究所;上海科学技术大学

MULTIDIMENSIONAL BOND-PARAMETER ANALYSIS OF OXIDE SYSTEMS

Liu Zhengxian; Zheng Longru and Chen Nianyi (Shanghai Institute of Metallurgy; Academia Siniea) and Yan Licheng (Shanghai University of Science and Technology)

刘征先;郑龙如;陈念贻;阎立诚. 氧化物系的多维键参数分析[J]. 金属学报, 1981, 17(6): 652-660.
, , , . MULTIDIMENSIONAL BOND-PARAMETER ANALYSIS OF OXIDE SYSTEMS[J]. Acta Metall Sin, 1981, 17(6): 652-660.

摘要 参考文献 相关文章 Metrics 全文: PDF(560 KB)   摘要: 运用化学键参数模式识别方法,总结氧化物系热力学性质的半经验规律,提出经验函数L作为氧化物酸碱性的标度。L和复合氧化物生成热、氧化物熔体的混合热、活度系数以及Masson熔渣模型聚合平衡常数K_(1,n)等均有对应关系。举例说明了L函数的应用。 Abstract：The semiempirical rules of the thermodynamical properties of oxide systems have been proposed by the pattern recognition technique with chemical bond-parameter, and an empirical function L has been suggested as a scale for the acidity or basicity of oxides. It seems to indicate that the correlation between L and such physico-chemical quantities as the heat of formation of complex oxides, the heat of mixing of oxide melts, the activity coefficient and polymerization equilibrium constant K_(1,n) of Masson's model of slags may be presented respectively. The applications of L function are illustrated with some examples. 收稿日期: 1981-06-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 刘征先 郑龙如 陈念贻 阎立诚 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1981/V17/I6/652 [1] 陈念贻,中国科学,(1974) ,No.6,580;(1975) .No.4,399． [2] 陈念贻,温元凯,金属学报,15(1979) ,85． [3] Kowalski, B. R. and Bender, C. F., J. Am. Chem. Soc., 94 (1972) , 5632． [4] Nilsson, N. J., Learning Machines, McGraw-Hill, New York, 1965, p.63． [5] 陈念贻,键参数函数及其应用,科学出版社,1976,p.15． [6] Sanderson, R. T., Chemical Bonds and Bond Energy, 2nd ed, Academic Press, New York, 1976, p. 126． [7] Didtschenko, R. and Rochow, E. G., J. Am. Chem. Soc., 76 (1954) , 3291． [8] Erdos, E., Collect. Czech. Chem. Commun., 27 (1962) , 1428． [9] Schwitzgebel, K. et al., J. Chem. Eng. Data, 16 (1971) , 418． [10] #12 [11] #12 [12] Bodsworth, C., Physical Chemistry of Iron and Steel Manufacture, Longmans, London and Cokhester, 1963, p. 326． [13] Masson, R. C., J. Am. Ceram. Soc., 51 (1968) , 134． [14] Carbo, J. and Richardson, F. D,, Trans. Inst. Mining Metall., 81 (1972) , C131． [15] Flood, H. and Foerland, T., Acta Chem. Scand., 1 (1947) ,592． No related articles found! Viewed Full text Abstract Cited   Shared      Discussed