金属学报  1982, Vol. 18 Issue (6): 683-688

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LaNi_5活化机理的探讨

吕曼祺;银耀德;吴桂春;吴平森

中国科学院金属研究所;中国科学院金属研究所;中国科学院金属研究所;中国科学院金属研究所

AN APPROACH TO THE ACTIVATION MECHANISM OF LaNi_5

Lu Manqi; Yin Yaode; Wu Guichun; Wu Pingsen (Institute of Metal Research; Academia Sinica; Shenyang)

吕曼祺;银耀德;吴桂春;吴平森. LaNi_5活化机理的探讨[J]. 金属学报, 1982, 18(6): 683-688.
, , , . AN APPROACH TO THE ACTIVATION MECHANISM OF LaNi_5[J]. Acta Metall Sin, 1982, 18(6): 683-688.

摘要 参考文献 相关文章 Metrics 全文: PDF(479 KB)   摘要: 本文通过对LaNi_5活化过程动力学的研究,论证了LaNi_5的清洁表面具有使氢分子分解为氢原子的催化作用。这种催化作用因氧在表面的存在而丧失,活化过程就是清除氧的污染而形成清洁表面的过程。孕育期的存在是表面污染引起的,已活化的LaNi_5中未释放的氢可减轻氧对LaNi_5表面活性的影响。 Abstract：A discussion on the catalytic action of clean surface of LaNi_5, by which the molecular hydrogen disassociated into atoms, is presented according to the study of the activation process kinetics of LaNi_5. It was confirmed that the catalytic action will be poisoned by oxygen on its surface. The activation process is removal of the pollution by oxygen and thereby forms a clean surface. How the incubation period come into existence is due to the surface pollution. The unreleased hydrogen stored in activated LaNi_5 can relieve the influence of oxygen upon the surface activity of it. 收稿日期: 1982-06-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 吕曼祺 银耀德 吴桂春 吴平森 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1982/V18/I6/683 1 Van Vucht, J. H. N.; Kuijpers, H. A.; Bruning, H. C. A. M., Philips Res. Rep., 25(1970) , 133． 2 Siegmann, H. C.; Schlapbach, L.; Prundle, C.R., Phys. Rev. Lett., 40(1978) , 972． 3 Schlapbach, L.; J. Phys. F: Met. Phys., 10(1980) , 2477． 4 吕曼祺;银耀德;吴桂春;吴平森,待发表. 5 Barnes, R. G.; Happer, W. C.; Nelson, S. O.; Thome, D. K.; Torgeson, D.R., J. Less-Common Met., 49(1976) , 483． 6 Bowman, A. L.; Anderson, T. L., Proc. R. E. Conf. 10th, Carefree, Arizona, 1972, p. 485． 7 Boser, O., J. Less-Common Met., 46(1976) , 91． 8 吕曼祺;戚震中;吴平森,金属学报,16(1980) ,65． 9 Kuijpers, F. A.; Philips Res. Rep., Suppl.,(1973) , №. 2, 34． 10 Suzuki, T., Proceedings of Second JIM International Symposium on Hydrogen in Metals, Minakami, Gunma pref., Japan, 1979, p. 17． 11 Nomura, Kei; Akiba, E,; Ono, S.; Suda, S., ibid., p. 353．? No related articles found! Viewed Full text Abstract Cited   Shared      Discussed