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金属学报  1984, Vol. 20 Issue (6): 465-470    
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对压力下结晶形核率的理论计算
齐丕骧
内蒙古金属材料研究所
AN EXPRESSION FOR NUCLEATION RATE OF CRYSTALLIZATION UNDER PRESSURE
QI Pixiang (Nei Monggol Institute of Metallic Materials; Baotou) (Manuscript received 8 November; 1982; revised manuscript 31 March; 1984)
引用本文:

齐丕骧. 对压力下结晶形核率的理论计算[J]. 金属学报, 1984, 20(6): 465-470.
. AN EXPRESSION FOR NUCLEATION RATE OF CRYSTALLIZATION UNDER PRESSURE[J]. Acta Metall Sin, 1984, 20(6): 465-470.

全文: PDF(367 KB)  
摘要: 本文建立了均质形核条件下压力与温度对形核率影响的数学方程,用此方程计算了Betol压力下结晶的形核数。得出在压力不变条件下,形核率-温度曲线出现一峰值,增加压力此峰值向高温方向移动。对于结晶时体积收缩的晶体物质,在温度不变的条件下,形核率-压力曲线也出现峰值,温度升高此峰值向高压方向移动。
Abstract:An attempt was made of deriving an expression for the effects of pressure and temperature on the nucleation rate under the homogeneous crystalline condition, and thereafter numbers of the Betol's crystal nuclei were calculated. The resuits were shown that a peak value may be noticed on the plot of the nucleation rate vs temperature under the condition of constant pressure, and it may shift to the direction of elevated temperature with the increasing of pressure. For substances crystallized with volume shrinkage, a similar peak value may also be presented on the nucleation rate vs pressure plot under constant temperature, and it may shift to the higher pressure with temperature increased.
收稿日期: 1984-06-18     
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