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金属学报  1985, Vol. 21 Issue (1): 40-46    
  论文 本期目录 | 过刊浏览 |
关于一些A-15型化合物的长程有序参数
张宏
中国科学院上海冶金研究所
ON THE LONG RANGE ORDER PARAMETERS OF CERTAIN A-15 TYPE COMPOUNDS
ZHANG Hong Shanghai Institute of Metallurgy.Academia Sinica
引用本文:

张宏. 关于一些A-15型化合物的长程有序参数[J]. 金属学报, 1985, 21(1): 40-46.
. ON THE LONG RANGE ORDER PARAMETERS OF CERTAIN A-15 TYPE COMPOUNDS[J]. Acta Metall Sin, 1985, 21(1): 40-46.

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摘要: 用结构因数F(S_(6c),y)对一些成分为A_(1-y)B_y的A-15型化合物的长程有序参数重新进行了计算(S_(6c)是6c子晶格的长程有序参数),指出了van Rcuth等和wang等分析计算所用的目标函数中各项的权重因子以及由此得到的关于这些化合物中有序-无序状态的结论均需要重新考察.同时指出.用X射线衍射强度分析所得的成分和其它精确方法所得的成分进行比较可作为所测得的长程有序参数的最小误差的一个判据,从而绐出获得目标函数中正确的权重因子和长程有序参数的一个必要条件.
Abstract:A review using the structural factor F(S_(6c),y)was carried out for the longrange order parameters of certain A-15 type compounds composed of A_(1-y)B_y cal-culated previously by Van Routh et al.and by Wang et al.from X-ray data.Itwas found that the weight factors in objective functions for analysis and calcu-lation by them seem to be doubtful and the conclusion drawn therefrom aboutthe order-disorder states in these compounds should be reexamined.The criterionwith a minimum error on calculation of the long range order parameters may beproposed by comparison between the composition y from X-ray intensity analysisand y_0 from other accurate determination.Therefore,a neccessary condition maybe suggested for ascertaining the modified weight factors in objective functions,and then the long range order parameters,i.e.,y should be equal to or approxi-mate to y_0.
收稿日期: 1985-01-18     
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