金属学报  1985, Vol. 21 Issue (4): 113-119

论文 本期目录 | 过刊浏览 |

第三长周期过渡金属对PdSi_(16.5)非晶态合金延脆转变性能的影响

郑云;宁远涛

昆明贵金属研究所;昆明贵金属研究所

INFLUENCE OF TRANSITION METALS OF THE THIRD LONG PERIOD ON DUCTILE-BRITTLE TRANSFORMATION OF PdSi_(16.5)GLASS

ZHENG Yun;NING Yuantao Institute of Precious Metals;Kunming

郑云;宁远涛. 第三长周期过渡金属对PdSi_(16.5)非晶态合金延脆转变性能的影响[J]. 金属学报, 1985, 21(4): 113-119.
, . INFLUENCE OF TRANSITION METALS OF THE THIRD LONG PERIOD ON DUCTILE-BRITTLE TRANSFORMATION OF PdSi_(16.5)GLASS[J]. Acta Metall Sin, 1985, 21(4): 113-119.

摘要 参考文献 相关文章 Metrics 全文: PDF(536 KB)   摘要: 测定了用转鼓法制备的Pd_(82·5)M_1Si_(18·5)非晶态合金的应力松弛和延脆转变特性.发现前过渡金属Hf,Ta,W,Re显著提高该非晶态合金的延脆转变温度T_B和延脆转变激活能△E_B,后过渡金属中的Os,Pt对其影响较小,而Ir则使T_B下降较多.添加前、后两类不同的过渡金属PdSi_(16■)非晶态合金的延脆转变方式也有所不同.比较了添加元素对延脆转变温度T_B、玻璃转变温度T_g、延脆转变激活能△E_B以及玻璃转变激活能△E_g的影响.用Gaskell模型和Engel-Brewer过渡金属电子理论解释了前、后过渡金属对PdSi_(16·5),非晶态合金延脆转变的不同影响. Abstract：The stress relief and ductile-brittle transformation of the metallic glasses Pd_(82.5)M_1Si_(16.5)prepared by spinning roll have been examined.It was found that theductile-brittle transformation temperature,T_B,and activation energy,△E_B,of theglasses composed by the preceding transition metals,e.g.,Hf,Ta,W,Re,are in-creased markedly and by the later ones,e.g.,Os,Pt,influenced slightly,but byIr,T_B is decreased too many.The mode of ductile-brittle transformation of themetallic glasses PdSi_(16.5)is different among themselves composed by the precedingand later transition metals.The comparison of the influences of additives on theirtemperatures and activation energies of the ductile-brittle transformation and glasstransition has been made.These behaviours have been discussed on the basis ofthe Gaskell′s model and the Engel-Brewer′s electron theory of transition metals. 收稿日期: 1985-04-18      服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 郑云 宁远涛 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1985/V21/I4/113 1 Walter,J.W.;Luborsky,F.E.,Mater.Sci Eng.,33(1978) ,91． 2 Liebermann,H.H.;Luborsky,F.E.,Acta Metall.,29(1981) ,1413 3 宁远涛;郑云;祁更新,金属学报,19(1983) ,B 209． 4 Luborsky,F.E.;Walter,J.L.,J.Appl.Phys.,47(1976) ,3648． 5 Masumoto,T.;Maddin,R.,Acta Metall.,19(1971) ,725． 6 Chen,H.S.,J.Non-Crystal Solids,27(1978) ,257． 7 Chen,H.S.,Mater.Sci.Eng.,26(1976) ,79． 8 Freed,R.L.;Vander Sande,J.B.,Acta Metall.,28(1980) ,103．a No related articles found! Viewed Full text Abstract Cited   Shared      Discussed