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金属学报  2009, Vol. 45 Issue (8): 978-982    
  论文 本期目录 | 过刊浏览 |
含Er 5083合金均匀化退火过程中Al3Er相的TEM观察
林双平;黄晖;文胜平;聂祚仁
北京工业大学材料科学与工程学院; 北京 100124
TEM OBSERVATION OF THE Al3Er PHASE DURING HOMOGENIZING OF THE 5083 ALLOY WITH Er ADDITION
LIN Shuangping; HUANG Hui; WEN Shengping; NIE Zuoren
College of Materials Science and Engineering; Beijing University of Technology; Beijing 100124
引用本文:

林双平 黄晖 文胜平 聂祚仁. 含Er 5083合金均匀化退火过程中Al3Er相的TEM观察[J]. 金属学报, 2009, 45(8): 978-982.
, , , , . TEM OBSERVATION OF THE Al3Er PHASE DURING HOMOGENIZING OF THE 5083 ALLOY WITH Er ADDITION[J]. Acta Metall Sin, 2009, 45(8): 978-982.

全文: PDF(4180 KB)  
摘要: 

对半连续铸造的Al-4.6Mg-0.7Mn-0.1Zr-0.3Er (5083)合金均匀化退火过程中析出的Al3Er相的显微组织进行了透射电镜观察. 结果表明, 铸锭的均匀化退火过程中, 合金中析出了大量的不同形状、尺寸的沉淀物, 其中尺寸在10-50 nm之间的球形析出物为Al3Er相, 它与基体保持共格/半共格关系. 计算分析得出Al3Er粒子共格/半共格转换半径为rt=9.44 nm, 与实验结果相近.

关键词 均匀化退火 Al3Er 共格/半共格    
Abstract

The research on scandium additions in aluminium alloys has gained some interests over the last decades, due to the precipitation of Al3Sc phase particles, which have the beneficial effect on mechanical properties, weldability and corrosion resistance. But Sc is a very expensive strategic
metal. Therefore, a breakthrough of the selection of RE is expected. However, only a limited number of possibilities exist in Al–based alloys for the formation of coherent strengthening particles that are thermodynamically stable and have the ordered, L12 structure. It involves the addition of some suitable alloying elements such as La, Ce, Y, Sc and especially to Sc, while the effects of other single elements are scarcely referred. Recent studies have considered Er as a promising alloying element in Al–alloy, and it has been shown that a small Er addition can improve the material properties in several Al–alloy systems. Most of the beneficial effects are attributed to the formation of the Al3Er phase in these alloys.
However, few research have been done on the effect of homogenizing treatment on the precipitation of Er modified 5083 alloy. Although the Al3Sc and Al3(Sc,Zr) particles are wildly studied, but few studies about coherency and coarsening behaviors of Al3Er have been reported. The present investigation provides some information about orientation relationships of the precipitates with matrix and the coherency behavior of Al3Er phase.
Al3Er phase precipitates durinhomogenizing of the Er modified 5083 alloy produced by direct chill casting were analyzed by transmission electron microscopy (TEM).The results show that many particles with different shapes and sizes precipitate during homogenizing. Spheric precipitates with the size between 10—50 nm is Al3Er phase which are good coherent/semi–coherent with matrix; the orientation relationships between matrix and the spheric precipitates are derived:[111]m//[111]sp, (110)m//(110)sp, (101)m//(101)sp; [011]m//[011]s, (100)m//(200)sp, where the indexs m and sp indicate matrix and spheric precipitate, respectivety.

The radius for coherent/semi-conherent transition of Al3Er particle is determinined as 12---20 nm by TEM analysis; The calculated value of critical transition radius (rt=9.44 nm) of the Al3Er precipitates is correspondent with the experiments.

Key wordshomogenizing    Al3Er    coherent/semi-coherent
收稿日期: 2008-12-15     
ZTFLH: 

TG146.2

 
基金资助:

国家高技术研究发展计划项目2006AA03A207和2007AA03Z514资助

作者简介: 林双平, 男, 1982年生, 博士生

[1] Hecht R L, Kannan K, Ghosh A K, Bieler T R eds., Superplasticity and Superplastic Forming. Warrendale, PA:TMS, 1995: 259
[2] Kaibyshev R, Musin F, Lesuer D R, Nieh T G. Mater Sci Eng, 2003; A342: 169
[3] Wang Z T, Tian R Z. Handbook of Aluminum Alloy and It’s Processing. Changsha: Central South University Press, 2005: 292
(王祝堂, 田荣璋. 铝合金及其加工手册. 长沙: 中南大学出版社, 2005: 292)
[4] Nie Z R, Jin T N, Zou J X, Fu J B, Yang J J, Zuo T Y. Trans Nonferrous Met Soc Chin, 2003; 13: 509
[5] Filatov Y A, Yelagin V I, Zakharov V V. Mater Sci Eng, 2000; A280: 97
[6] Yang J J, Nie Z R, Jin T N, Xu G F, Fu J B, Ruan H Q,Zuo T Y. Trans Nonferrous Met Soc Chin, 2003; 13: 1035
[7] Kendig K L, Miracle D B. Acta Mater, 2002; 50: 4165
[8] Marquies E A, Seidman D N. Acta Mater, 2001; 49: 1909
[9] Yin Z M, Jiang F, Pan Q L. Trans Nonferrous Met Soc Chin, 2003; 13: 515
[10] Ratchev P, Verlinden B, Van Houtte P. Acta Metall Mater, 1995; 43: 621
[11] Jena A K, Chaturvedi M C. Phase Transformation in Materials, New Jersey: Prentice Hall, 1992: 61
[12] ElaginV I, Zakharov V V, Rostova T D. Met Sci Heat Treat, 1992; 34: 37
[13] Sanders I R E, Baumann S F, Stumpf H C. Mater Sci Technol, 1989; 31: 65
[14] Hollinshead P A. Mater Sci Technol, 1992; 8: 57
[15] Cao B Y, Joshib S P, Ramesh K T. Scr Mater, 2009; 60: 619
[16] Villars P, Calvert L D. Handbook of Crystallographic Data for Intermetallic Phases, Metals Park, Oh: ASM,1985; 2: 975
[17] Mondolfo L F. Aluminum Alloys: Structure and Properties. Beijing: Metal Industry Press, 1988: 12
([美]L. F. 蒙多尔福. 铝合金的组织与性能. 北京: 冶金工业出版社, 1988: 12)
[18] Seidman D N, Marquis E A, Dunand D C. Acta Mater, 2002; 50: 4021
[19] Jesser W A. Philos Mag, 1968; 19: 993
[20] Marquis E A, Seidman D N. Acta Mater, 2005; 53: 4259
[21] Iwamura S, Miura Y. Acta Mater, 2004; 52: 591

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