金属学报  2006, Vol. 42 Issue (5): 500-504

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固体透氧膜法制备金属Ta

程红伟; 鲁雄刚; 李谦; 刘建民; 丁伟中; 周国治

上海大学材料科学与工程学院

A NOVEL TECHNOLOGY TO PRODUCE METAL TANTALUM DIRECTLY FROM Ta2O5

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School of Materials Science and Engineering; Shanghai University;

程红伟; 鲁雄刚; 李谦; 刘建民; 丁伟中; 周国治 . 固体透氧膜法制备金属Ta[J]. 金属学报, 2006, 42(5): 500-504 .
, , , , , . A NOVEL TECHNOLOGY TO PRODUCE METAL TANTALUM DIRECTLY FROM Ta2O5[J]. Acta Metall Sin, 2006, 42(5): 500-504 .

摘要 参考文献 相关文章 Metrics 全文: PDF(1193 KB)   摘要: 利用固体透氧膜(SOM)法进行了从Ta2O5中提取金属Ta的实验. 在1150℃, 外加直流电解电压3.2 V下,以55.5%MgF2-44.5%CaF2的熔盐体系为介质,阴极为经过预烧成型的Ta2O5, 阳极为氧化锆管内的碳饱和铜液. 测试结果显示: Ta2O5阴极中氧含量大大降低甚至消失, Ta2O5还原为金属Ta. 关键词 ： 金属Ta,  固体透氧膜,  电解法     Abstract：ABSTRACT In this paper, the method using Solid Oxygen-Ion Membrane (SOM) to produce tantalum from tantalum oxide was investigated. Experiment was carried out at 1150℃ and 3.2V of DC electrolysis potential in the flux system of 55.5wt.%CaF2- 44.5wt.%MgF2. Sintered Ta2O5 solid and liquid copper saturated with carbon loaded in zirconia tube were used as the cathode and the anode, respectively. The results of scanning electron microscopy (SEM) with an energy dispersive X-ray spectrometer (EDX) indicated that the amount of oxygen in tantalum oxide decreased obviously even approached to the zero level and tantalum was produced. Key words： Tantalum    SOM    electrolysis 收稿日期: 2005-08-30      ZTFLH:  TG146.4   服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 程红伟 鲁雄刚 李谦 刘建民 丁伟中 周国治 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y2006/V42/I5/500 [1] He J L. Chin J Rare Met, 2003; 27: 23 (何季麟．稀有金属,2003;27:23) [2] He J L. Eng Sci, 2003; 5(5): 40 (何季麟．中国工程科学,2003;5(5):40) [3] He J L, Zhang Z G, Xu Z T. Rare Met Mater Eng, 1998; 27: 9 (何季林,张宗国,徐忠亭．稀有金属材料与工程,1998;27: 9) [4] He J L. Eng Sci, 2001; 3(12): 85 (何季麟．中国工程科学,2001;3(12):85) [5] Lu X G, Zhou G Z, Ding W Z, Jang G C, Xu K D. J Iron Steel Res, 2003; 15(5): 69 (鲁雄刚,周国治,丁伟中,蒋国昌,徐匡迪．钢铁研究学报, 2003;15(5):69) [6] Pal U. JOM, 2001; 53(10): 25 [7] Pal U, Woolley D E,Kenney G B. JOM, 2001; 53(10): 32 [8] Woolley D E, Pal U. JOM, 2001; 53(10): 40 [9] Krishnan A, Lu X G, Pal U. Mater Metall Trans, 2005; 36B: 463 [10] Chen G Z, Fray D J, Farthing T W. Nature, 2000; 407: 361 [1] 何峰; 张正义 . 制备超细金属粉末的新型电解法[J]. 金属学报, 2000, 36(6): 659-661 . Viewed Full text Abstract Cited   Shared      Discussed