金属学报  1996, Vol. 32 Issue (2): 144-148

论文 本期目录 | 过刊浏览 |

Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4)的热力学稳定性

邢献然;乔芝郁;魏寿昆

北京科技大学

THERMODYNAMIC STABILITY OF COMPLEX OXIDE Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4)

XING Hianran; QIAO Zhiyu; WEI Shoukun(University of Science and Technology Beijing; Beijing 100083)(Manuscript received 1995-05-02; in revised form 1995-11-05)

邢献然;乔芝郁;魏寿昆. Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4)的热力学稳定性[J]. 金属学报, 1996, 32(2): 144-148.
, , . THERMODYNAMIC STABILITY OF COMPLEX OXIDE Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4)[J]. Acta Metall Sin, 1996, 32(2): 144-148.

摘要 参考文献 相关文章 Metrics 全文: PDF(352 KB)   摘要: 用测量固体电解质电池电动势（ＥＭＦ）的方法，测试了Ｓｍ－Ｂａ－Ｃｕ－Ｏ体系主要化合物的标准Ｇｉｂｂｓ生成自由能；结果发现，稀土复合氧化物Ｓｍ_（１＋ｘ）Ｂａ_（２－ｘ）Ｃｕ_３Ｏ_ｙ，随着固溶度ｘ增加，化合物稳定性下降ＤＴＡ实验支持这一结论。 关键词 ： 电池电动势（ＥＭＦ）,  热力学稳定性,  高温超导体     Abstract：An assembly for performing EMF measurements using a CaF2 single crystal as a solid state electrolyte has been constructed. From the EMF data, the standard Gibbs energies of formation of member oxides in the Sm-Ba-Cu-O system were calculated. It is found that the thermodynamic stability of the complex oxide Sm_(1+x)Ba_(2-x)Cu_3O_y(0≤x≤0.4）decreases with the increase in the solid solubility x.(Correspondent: XING Xianran, associate professor-Department of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083.) Key words： electromotive force (EMF)    thermodynamic stability    high temperature superconductor 收稿日期: 1996-02-18      基金资助:国家自然科学基金 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 邢献然 乔芝郁 魏寿昆 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1996/V32/I2/144 1RothRS．AdvCeramMater,1987;2:3032AsanoH,YokoyamaY．ModernPhysLettB,1988;2:5833JCPDSCard,6一399,19884QiaoZhiyu,XingXianran,YuanWenxia,WeiSoukun,ChenXiaolong,LiangJinkui,XieShishen.JAlloysCompounds,1993,202:775邢献然.北京科技大学博士论文,19936BarinI,KnackeO,KubachewskiO．Thermochemicalpropertiesofinorganicsubstancesandsupple-ment,Dusseldorf:Springer-Verleg,19777XingXianran,QiaoZhiyu,YuanWenxia,WeiSoukun,ChenXiaolong,RaoGuanghui,LiangJinkui．JMaterSciTech,1994;10:269 [1] 边为民 朱溢眉 周 廉. Bi系高温超导体中非公度调制结构相的空间群测定[J]. 金属学报, 2009, 45(6): 673-679. Viewed Full text Abstract Cited   Shared      Discussed