金属学报  1990, Vol. 26 Issue (1): 113-119

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渣钢持续接触时脱硫反应的动力学研究

蒋国昌;徐匡迪;邓健雄;郭占成;关玉龙

上海工业大学冶金及材料研究所;副教授;上海(200070);上海工业大学;上海工业大学;北京科技大学;北京科技大学

KINETIC STUDY OF DESULPHURIZATION ALONG METAL-SLAG INTERFACE

JIANG Guochang;XU Kuangdi;DENG Jianxiong Shanghai University of Technology GUO Zhancheng; GUAN Yulong University of Science and Technology Beijing Institute of Metallurgy and Materials;Shanghai University of Technology; Shanghai 200072

蒋国昌;徐匡迪;邓健雄;郭占成;关玉龙. 渣钢持续接触时脱硫反应的动力学研究[J]. 金属学报, 1990, 26(1): 113-119.
, , , , . KINETIC STUDY OF DESULPHURIZATION ALONG METAL-SLAG INTERFACE[J]. Acta Metall Sin, 1990, 26(1): 113-119.

摘要 参考文献 相关文章 Metrics 全文: PDF(481 KB)   摘要: 直接由电化学原理导出的电化学模型,以及给出的初始渣钢界面氧位计算方法,可用以定量描述％S～τ曲线。计算与实测吻合。脱硫过程中渣钢界面上硫的分配常数L_S~*和渣钢本体内硫的分配指数L′_S随界面氧位的下降而不断变化,其规律截然不同:L_S~*～τ曲线属抛物线类型,而L′_S～τ曲线属双曲线类型。与此相应,计算及实测都指出,驱动力参数随时间而变化的曲线呈现一驼峰。 关键词 ： 渣钢界面,  脱硫过程,  电化学模型     Abstract：An electrochemical model, directly deduced from the principle of elec-trochemistry, together with the calculational method for initial oxygen potentialalong the metal-slag interface may be available to quantitatively describe the plotof %S vs time. It was found that during desulphurization both the distribution con-stant of S along metal-slag interface, L_S~*, and distribation index inside the bulk,L'_S, vary with the descending of oxygen potential along metal-slag interface. Butthe plot of L_S~* vs time is quite different from L'_S vs time, being of parabola or hy-perhola type respectively. The variation of the driving force parameter vs time,obtained either calculated or experimental, plotted as a camel hump. Key words： desulphurization    metal-slag interface    electrochemical model 收稿日期: 1990-01-18      基金资助:国家自然科学基金 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 蒋国昌 徐匡迪 邓健雄 郭占成 关玉龙 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1990/V26/I1/113 1 Deng Jianxiong (邓健雄), Oeters F. Preprints of 7th Japan-Germany Seminar on Fundamenials of Iron and Steel Making, Duesseldorf, 1987 2 Wagner C. In: Elliot J F ed, The Physical Chemistry of Steelmaking, New York: John Wiley, 1958: 237--251 3 PluscMell S W, Dortmund B R, Schuermann E. Arch Eisenhuettenwes, 1981: 52 (3) : 85--89 4 Riboud P P, Olette M. Proc 7th Int on Vacuum Metallurgy, Vol. II, Tokyo: The Iron Steel Inst of Japan, 1982: 879--889 5 Adamson A W,顾惕人译,表面的物理化学,北京:科学出版社,1984:151 6 Bard A J,Faulkner L R.谷林瑛等译.电化学方法(原理及应用),北京:化学工业出版社,1986:195 7 田昭武.电化学研究方法,北京:科学出版社,1984:24 8 Nicholson A, Howarth D J, Turton J. Ironmaking Steelmaking, 1983; 10: 31--45k [1] 鲁雄刚; 李福燊; 李丽芬; 周国治 . 炉渣中氧离子迁移的电化学模型[J]. 金属学报, 1999, 35(7): 743-747 . Viewed Full text Abstract Cited   Shared      Discussed