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金属学报  1989, Vol. 25 Issue (4): 110-114    
  论文 本期目录 | 过刊浏览 |
电化学合金化Y-Cu体系的生成自由能
杨绮琴;刘冠昆;刘泽锦
中山大学;中山大学;中山大学
FREE ENERGIES OF FORMATION FOR ELECTROCHEMICALLY ALLOYED Y-Cu SYSTEM
YANG Qiqin;LIU Cuankun;LIU Zejin Zhongshan University; Guangzhou
引用本文:

杨绮琴;刘冠昆;刘泽锦. 电化学合金化Y-Cu体系的生成自由能[J]. 金属学报, 1989, 25(4): 110-114.
, , . FREE ENERGIES OF FORMATION FOR ELECTROCHEMICALLY ALLOYED Y-Cu SYSTEM[J]. Acta Metall Sin, 1989, 25(4): 110-114.

全文: PDF(401 KB)  
摘要: 本文研究了在NaCl-KCl-YCl_3熔体中,电化学合金化Y-Cu体系的热力学行为。用恒电位电解断电后的电极电位-时间曲线测定了形成YCu_6,YCu_4,YCu_2,YCu等金属间化合物反应的ΔG(973-1103K),结果表明测量方法简单可靠。
关键词 钇—铜合金生成自由能电化学合金化    
Abstract:The electrochemical alloying of Y-Cu system in molten NaCl-KCl-YCl_3 has been investigated. The free energy changes of the formation reactions ofthe intermetallic compounds, including YCu_6, YCu_4, YCu_2, YCu(973--1103K), weredetermined by means of electrode potential-time curves of the working electrodeafter potentiostatic electrolysis. The results indicate that the potential-time methodis simple and reliable.
Key wordsY-Cu system    free energy of formation    electrochemically alloying
收稿日期: 1989-04-18     
基金资助:国家自然科学基金
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