金属学报  1988, Vol. 24 Issue (2): 189-193

论文 本期目录 | 过刊浏览 |

用核磁共振方法研究氢在LaNi_5,LaNi_4Cu,LaNi_4Fe晶格中的运动

周达明;侯磊;金庆华;郭振亚;丁大同

南开大学物理系;南开大学;南开大学;南开大学;南开大学

AN NMR STUDY OF HYDROGEN MOTION IN LaNi_5, LaNi_4Cu AND LaNi_4Fe LATTICES

ZHOU Daming Department of physics;Nankai University;Tianjin;HOU Lei;JIN Qinghua;GUO Zhenya;DING Datong Nankai University; Tianjin

周达明;侯磊;金庆华;郭振亚;丁大同. 用核磁共振方法研究氢在LaNi_5,LaNi_4Cu,LaNi_4Fe晶格中的运动[J]. 金属学报, 1988, 24(2): 189-193.
, , , , . AN NMR STUDY OF HYDROGEN MOTION IN LaNi_5, LaNi_4Cu AND LaNi_4Fe LATTICES[J]. Acta Metall Sin, 1988, 24(2): 189-193.

摘要 参考文献 相关文章 Metrics 全文: PDF(415 KB)   摘要: 本文首先报道LaNi_5·H_6中~1H核磁共振连续波观测:高、低温下的线型、线宽的温度依赖,扩散激活能,自相关时间及基于一定模型假设计算自扩散系数.对LaNi_4Cu·H_x和LaNi_4Fe·H_x作了类似研究.通过对比得出结论:Cu,Fe部分置换Ni使氢在基质合金中稳定性增加. 关键词 ： La-Ni合金,  核磁共振,  氢扩散     Abstract：The continuous wave NMR (nuclear magnetic resonance) results of ~1Hin LaNi_5·H_6, LaNi_4Cu·H_x and LaNi_4Fe·H_x were reported. The line shape at bothhigher and lower temperatures, the activation energy of diffusion, the self correla-tion time and the diffusion coefficient calculated according to a model have beendiscussed. It was concluded that the partial substitution of Cu and Fe for Ni increasesthe stability of hydrogen in the host alloy. Key words： La-Ni alloys    nuclear magnetic resonance    hydrogen diffusion 收稿日期: 1988-02-18      基金资助:中国科学院科学基金 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 周达明 侯磊 金庆华 郭振亚 丁大同 44.8K 链接本文: https://www.ams.org.cn/CN/      或      https://www.ams.org.cn/CN/Y1988/V24/I2/189 1 Van Vucht J H N, Kuijpers F A, Bruning H C A M. Philips Res Rep, 1970; 25: 133 2 Van Mal H H. Buschow K H J, Miedema A R. J Less-Common Met, 1974; 35: 65 3 Halstead T K. J Solid State Chem, 1974; 11: 114 4 Barnes R S, Harper W C, Nelson S O, Thome D K. Torgeson D R. J Less-Common Met, 1976; 49:483 5 Karlicek R F Jr, Lowe I J. J Less-Common Met. 1980; 73: 219 6 Chang H, Lowe I J, Karlicek R F Jr. In: Kaufmann, Shenoy eds. Nuclear and Electron Resonance Spectroscopies Applied to Material Science, 1981: 7 Drain L E. Proc Phys Soc, 1962; 80: 1380 8 Bloembergen N, Purcell E M, Pound R V. Phys Rev. 1948; 73: 679 9 Weaver H T. J Cham Phys, 1972; 56: 3193 10 StalinsByk Coogan C K. Gutowsky H S. J Chem Phys, 1961; 34: 1191 11 Kubo R, Tomita K. J Phys Soc Jpn. 1954; 9: 888 12 侯磊.镧镍(铜、铁)氢合金的氢位及运动研究.硕士学位论文,南开大学物理系,1986年6月 13 Bowman R C Jr, Gruen D M. MendeIsohn M. H.. Solid State Commun, 1979; 32: 501 14 Bowman A L, Anderson J L, Nereson N G. In: Proc 10th Rare Earth Res Conf, Carefree, Arizona: 1972: 485 15 Percheron-Guegan A, Lartigue C, Achard J C, Germi P, Tasset F. J Less-Common Met, 1980; 74: 1 16 Yartys' V A. Burnasheva V V. Semenenko K N, Fadeeva N V. Solov'ev S P. J Hydrogen Energy, 1982; 7(12) : 957 17 Achard J C, Lart gue C, Percheron-Guegan A. J Less-Common Met. 1982; 88: 89 18 Richter D, Hempelmann R, Vinhas L A. J Less-Common Met, 1982; 88: 353 [1] 蒋文春; 巩建鸣; 唐建群; 陈虎; 涂善东 . 焊接残余应力对氢扩散影响的有限元模拟[J]. 金属学报, 2006, 42(11): 1221-1226 . [2] 刘实; 郑华; 贵全红; 马爱华; 于洪波; 王隆保 . 管状样品中高温氢扩散系数的测定[J]. 金属学报, 2004, 40(4): 393-398 . [3] 孟庆海;陈廉;刘迪;柯伟. 堆焊结构界面区附近的微观组织结构、氢扩散富集与开裂行为研究[J]. 金属学报, 1998, 34(6): 633-639. [4] 万晓景;程晓英;陈业新. Co_3Ti金属间化合物的环境氢脆及氢扩散[J]. 金属学报, 1998, 34(2): 141-145. [5] 徐坚;孙秀魁;陈文绣;李依依. Incoloy 903合金氢渗透与扩散的研究[J]. 金属学报, 1992, 28(11): 23-27. [6] 钱立和;曹名洲;万晓景. α-Fe中置换式合金元素的氢陷阱效应[J]. 金属学报, 1991, 27(1): 27-31. Viewed Full text Abstract Cited   Shared      Discussed